Gravitational backreaction in cosmological spacetimes

We develop a new formalism for the treatment of gravitational backreaction in the cosmological setting. The approach is inspired by projective techniques in non-equilibrium statistical mechanics. We employ group-averaging with respect to the action of the isotropy group of homogeneous and isotropic spacetimes (rather than spatial averaging), in order to define effective FRW variables for a generic spacetime. Using the Hamiltonian formalism for gravitating perfect fluids, we obtain a set of equations for the evolution of the effective variables; these equations incorporate the effects of backreaction by the inhomogeneities. Specializing to dust-filled spacetimes, we find regimes that lead to a closed set of backreaction equations, which we solve for small inhomogeneities. We then study the case of large inhomogeneities in relation to the proposal that backreaction can lead to accelerated expansion. In particular, we identify regions of the gravitational state space that correspond to effective cosmic acceleration. Necessary conditions are (i) a strong expansion of the congruences corresponding to comoving observers, and (ii) a large negative value of a dissipation variable that appears in the effective equations (i.e, an effective "anti-dissipation").Comment: 36 pages, latex. Extended discussion on results and on relation to Lemaitre-Tolman-Bondi models. Version to appear in PR

Improved Calculation of Vibrational Mode Lifetimes in Anharmonic Solids - Part I: Theory

We propose here a formal foundation for practical calculations of vibrational mode lifetimes in solids. The approach is based on a recursion method analysis of the Liouvillian. From this we derive the lifetime of a vibrational mode in terms of moments of the power spectrum of the Liouvillian as projected onto the relevant subspace of phase space. In practical terms, the moments are evaluated as ensemble averages of well-defined operators, meaning that the entire calculation is to be done with Monte Carlo. These insights should lead to significantly shorter calculations compared to current methods. A companion piece presents numerical results.Comment: 18 pages, 3 figure

Reaction rate calculation with time-dependent invariant manifolds

The identification of trajectories that contribute to the reaction rate is the crucial dynamical ingredient in any classical chemical reactivity calculation. This problem often requires a full scale numerical simulation of the dynamics, in particular if the reactive system is exposed to the influence of a heat bath. As an efficient alternative, we propose here to compute invariant surfaces in the phase space of the reactive system that separate reactive from nonreactive trajectories. The location of these invariant manifolds depends both on time and on the realization of the driving force exerted by the bath. These manifolds allow the identification of reactive trajectories simply from their initial conditions, without the need of any further simulation. In this paper, we show how these invariant manifolds can be calculated, and used in a formally exact reaction rate calculation based on perturbation theory for any multidimensional potential coupled to a noisy environment

Quantum versus classical counting in nonMarkovian master equations

We discuss the description of full counting statistics in quantum transport with a nonMarkovian master equation. We focus on differences arising from whether charge is considered as a classical or a quantum degree of freedom. These differences manifest themselves in the inhomogeneous term of the master equation which describes initial correlations. We describe the influence on current and in particular, the finite-frequency shotnoise. We illustrate these ideas by studying transport through a quantum dot and give results that include both sequential and cotunneling processes. Importantly, the noise spectra derived from the classical description are essentially frequency-independent and all quantum noise effects are absent. These effects are fully recovered when charge is considered as a quantum degree of freedom.Comment: 12 pages; 3 figure

Information-theoretical meaning of quantum dynamical entropy

The theory of noncommutative dynamical entropy and quantum symbolic dynamics for quantum dynamical systems is analised from the point of view of quantum information theory. Using a general quantum dynamical system as a communication channel one can define different classical capacities depending on the character of resources applied for encoding and decoding procedures and on the type of information sources. It is shown that for Bernoulli sources the entanglement-assisted classical capacity, which is the largest one, is bounded from above by the quantum dynamical entropy defined in terms of operational partitions of unity. Stronger results are proved for the particular class of quantum dynamical systems -- quantum Bernoulli shifts. Different classical capacities are exactly computed and the entanglement-assisted one is equal to the dynamical entropy in this case.Comment: 6 page

Interference effects in the counting statistics of electron transfers through a double quantum dot

We investigate the effect of quantum interferences and Coulomb interaction on the counting statistics of electrons crossing a double quantum dot in a parallel geometry using a generating function technique based on a quantum master equation approach. The skewness and the average residence time of electrons in the dots are shown to be the quantities most sensitive to interferences and Coulomb coupling. The joint probabilities of consecutive electron transfer processes show characteristic temporal oscillations due to interference. The steady-state fluctuation theorem which predicts a universal connection between the number of forward and backward transfer events is shown to hold even in the presence of Coulomb coupling and interference.Comment: 11 pages, 12 figure

Accelerated Sampling of Boltzmann distributions

The sampling of Boltzmann distributions by stochastic Markov processes, can be strongly limited by the crossing time of high (free) energy barriers. As a result, the system may stay trapped in metastable states, and the relaxation time to the equilibrium Boltzmann distribution may be very large compared to the available computational time. In this paper, we show how, by a simple modification of the Hamiltonian, one can dramatically decrease the relaxation time of the system, while retaining the same equilibrium distribution. The method is illustrated on the case of the one-dimensional double-well potential

A homogenization theorem for Langevin systems with an application to Hamiltonian dynamics

This paper studies homogenization of stochastic differential systems. The standard example of this phenomenon is the small mass limit of Hamiltonian systems. We consider this case first from the heuristic point of view, stressing the role of detailed balance and presenting the heuristics based on a multiscale expansion. This is used to propose a physical interpretation of recent results by the authors, as well as to motivate a new theorem proven here. Its main content is a sufficient condition, expressed in terms of solvability of an associated partial differential equation ("the cell problem"), under which the homogenization limit of an SDE is calculated explicitly. The general theorem is applied to a class of systems, satisfying a generalized detailed balance condition with a position-dependent temperature.Comment: 32 page

Spin Waves in Quantum Antiferromagnets

Using a self-consistent mean-field theory for the $S=1/2$ Heisenberg antiferromagnet Kr\"uger and Schuck recently derived an analytic expression for the dispersion. It is exact in one dimension ($d=1$) and agrees well with numerical results in $d=2$. With an expansion in powers of the inverse coordination number $1/Z$ ($Z=2d$) we investigate if this expression can be {\em exact} for all $d$. The projection method of Mori-Zwanzig is used for the {\em dynamical} spin susceptibility. We find that the expression of Kr\"uger and Schuck deviates in order $1/Z^2$ from our rigorous result. Our method is generalised to arbitrary spin $S$ and to models with easy-axis anisotropy \D. It can be systematically improved to higher orders in $1/Z$. We clarify its relation to the $1/S$ expansion.Comment: 8 pages, uuencoded compressed PS-file, accepted as Euro. Phys. Lette

Confinement and Viscoelastic effects on Chain Closure Dynamics

Chemical reactions inside cells are typically subject to the effects both of the cell's confining surfaces and of the viscoelastic behavior of its contents. In this paper, we show how the outcome of one particular reaction of relevance to cellular biochemistry - the diffusion-limited cyclization of long chain polymers - is influenced by such confinement and crowding effects. More specifically, starting from the Rouse model of polymer dynamics, and invoking the Wilemski-Fixman approximation, we determine the scaling relationship between the mean closure time t_{c} of a flexible chain (no excluded volume or hydrodynamic interactions) and the length N of its contour under the following separate conditions: (a) confinement of the chain to a sphere of radius D, and (b) modulation of its dynamics by colored Gaussian noise. Among other results, we find that in case (a) when D is much smaller than the size of the chain, t_{c}\simND^{2}, and that in case (b), t_{c}\simN^{2/(2-2H)}, H being a number between 1/2 and 1 that characterizes the decay of the noise correlations. H is not known \`a priori, but values of about 0.7 have been used in the successful characterization of protein conformational dynamics. At this value of H (selected for purposes of illustration), t_{c}\simN^3.4, the high scaling exponent reflecting the slow relaxation of the chain in a viscoelastic medium