1,077 research outputs found
Molecular Realism in Default Models for Information Theories of Hydrophobic Effects
This letter considers several physical arguments about contributions to
hydrophobic hydration of inert gases, constructs default models to test them
within information theories, and gives information theory predictions using
those default models with moment information drawn from simulation of liquid
water. Tested physical features include: packing or steric effects, the role of
attractive forces that lower the solvent pressure, and the roughly tetrahedral
coordination of water molecules in liquid water. Packing effects (hard sphere
default model) and packing effects plus attractive forces (Lennard-Jones
default model) are ineffective in improving the prediction of hydrophobic
hydration free energies of inert gases over the previously used Gibbs and flat
default models. However, a conceptually simple cluster Poisson model that
incorporates tetrahedral coordination structure in the default model is one of
the better performers for these predictions. These results provide a partial
rationalization of the remarkable performance of the flat default model with
two moments in previous applications. The cluster Poisson default model thus
will be the subject of further refinement.Comment: 5 pages including 3 figure
Dynamic rotor mode in antiferromagnetic nanoparticles
We present experimental, numerical, and theoretical evidence for a new mode
of antiferromagnetic dynamics in nanoparticles. Elastic neutron scattering
experiments on 8 nm particles of hematite display a loss of diffraction
intensity with temperature, the intensity vanishing around 150 K. However, the
signal from inelastic neutron scattering remains above that temperature,
indicating a magnetic system in constant motion. In addition, the precession
frequency of the inelastic magnetic signal shows an increase above 100 K.
Numerical Langevin simulations of spin dynamics reproduce all measured neutron
data and reveal that thermally activated spin canting gives rise to a new type
of coherent magnetic precession mode. This "rotor" mode can be seen as a
high-temperature version of superparamagnetism and is driven by exchange
interactions between the two magnetic sublattices. The frequency of the rotor
mode behaves in fair agreement with a simple analytical model, based on a high
temperature approximation of the generally accepted Hamiltonian of the system.
The extracted model parameters, as the magnetic interaction and the axial
anisotropy, are in excellent agreement with results from Mossbauer
spectroscopy
Immunocytochemical localisation of follicle stimulating hormone (FSH) in normal, benign and malignant human prostates.
Immunocytochemical localisation of follicle stimulating hormone (FSH) was carried out in normal, benign and malignant human prostates by indirect immunoperoxidase technique. Positive staining was observed in the epithelial cells of all the three categories, while the stromal cells showed a weakly positive reaction in a few specimens. The brown reaction product was dispersed in the cytoplasm of the epithelial cells. These observations demonstrate the presence of immunoreactive FSH-like peptide in human prostate. The significance of FSH in the aetiopathology of prostatic disorders is discussed
Universal trend of the information entropy of a fermion in a mean field
We calculate the information entropy of single-particle states in
position-space and momentum-space for a nucleon in a nucleus, a
particle in a hypernucleus and an electron in an atomic cluster. It
is seen that and obey the same approximate functional form as
functions of the number of particles, ({\rm or}
in all of the above many-body systems in position- and momentum- space
separately. The net information content is a slowly varying
function of of the same form as above. The entropy sum is
invariant to uniform scaling of coordinates and a characteristic of the
single-particle states of a specific system. The order of single-particle
states according to is the same as their classification according to
energy keeping the quantum number constant. The spin-orbit splitting is
reproduced correctly. It is also seen that enhances with
excitation of a fermion in a quantum-mechanical system. Finally, we establish a
relationship of with the energy of the corresponding single-particle
state i.e. . This relation holds for all the
systems under consideration.Comment: 9 pages, latex, 6 figure
Modeling healthcare authorization and claim submissions using the openEHR dual-model approach
<p>Abstract</p> <p>Background</p> <p>The TISS standard is a set of mandatory forms and electronic messages for healthcare authorization and claim submissions among healthcare plans and providers in Brazil. It is not based on formal models as the new generation of health informatics standards suggests. The objective of this paper is to model the TISS in terms of the openEHR archetype-based approach and integrate it into a patient-centered EHR architecture.</p> <p>Methods</p> <p>Three approaches were adopted to model TISS. In the first approach, a set of archetypes was designed using ENTRY subclasses. In the second one, a set of archetypes was designed using exclusively ADMIN_ENTRY and CLUSTERs as their root classes. In the third approach, the openEHR ADMIN_ENTRY is extended with classes designed for authorization and claim submissions, and an ISM_TRANSITION attribute is added to the COMPOSITION class. Another set of archetypes was designed based on this model. For all three approaches, templates were designed to represent the TISS forms.</p> <p>Results</p> <p>The archetypes based on the openEHR RM (Reference Model) can represent all TISS data structures. The extended model adds subclasses and an attribute to the COMPOSITION class to represent information on authorization and claim submissions. The archetypes based on all three approaches have similar structures, although rooted in different classes. The extended openEHR RM model is more semantically aligned with the concepts involved in a claim submission, but may disrupt interoperability with other systems and the current tools must be adapted to deal with it.</p> <p>Conclusions</p> <p>Modeling the TISS standard by means of the openEHR approach makes it aligned with ISO recommendations and provides a solid foundation on which the TISS can evolve. Although there are few administrative archetypes available, the openEHR RM is expressive enough to represent the TISS standard. This paper focuses on the TISS but its results may be extended to other billing processes. A complete communication architecture to simulate the exchange of TISS data between systems according to the openEHR approach still needs to be designed and implemented.</p
Magnetic anisotropy, first-order-like metamagnetic transitions and large negative magnetoresistance in the single crystal of GdPdSi
Electrical resistivity (), magnetoresistance (MR), magnetization,
thermopower and Hall effect measurements on the single crystal
GdPdSi, crystallizing in an AlB-derived hexagonal structure are
reported. The well-defined minimum in at a temperature above N\'eel
temperature (T= 21 K) and large negative MR below 3T, reported
earlier for the polycrystals, are reproducible even in single crystals. Such
features are generally uncharacteristic of Gd alloys. In addition, we also
found interesting features in other data, e.g., two-step first-order-like
metamagnetic transitions for the magnetic field along [0001] direction. The
alloy exhibits anisotropy in all these properties, though Gd is a S-state ion.Comment: RevTeX, 5 pages, 6 encapsulated postscript figures; scheduled to be
published in Phy. Rev. B (01 November 1999, B1
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