95 research outputs found

    Complex potentials: bound states, quantum dynamics and wave operators

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    Schr\"odinger operator on half-line with complex potential and the corresponding evolution are studied within perturbation theoretic approach. The total number of eigenvalues and spectral singularities is effectively evaluated. Wave operators are constructed and a criterion is established for the similarity of perturbed and free propagators.Comment: 9 page

    Spectral multiplicity for powers of weakly mixing automorphisms

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    We study the behavior of maximal multiplicities mm(Rn)mm (R^n) for the powers of a weakly mixing automorphism RR. For some special infinite set AA we show the existence of a weakly mixing rank-one automorphism RR such that mm(Rn)=nmm (R^n)=n and mm(Rn+1)=1mm(R^{n+1}) =1 for all n∈An\in A. Moreover, the cardinality cardm(Rn)cardm(R^n) of the set of spectral multiplicities for RnR^n is not bounded. We have cardm(Rn+1)=1cardm(R^{n+1})=1 and cardm(Rn)=2m(n)cardm(R^n)=2^{m(n)}, m(n)β†’βˆžm(n)\to\infty, n∈An\in A. We also construct another weakly mixing automorphism RR with the following properties: mm(Rn)=nmm(R^{n}) =n for n=1,2,3,...,2009,2010n=1,2,3,..., 2009, 2010 but mm(T2011)=1mm(T^{2011}) =1, all powers (Rn)(R^{n}) have homogeneous spectrum, and the set of limit points of the sequence {mm(Rn)n:n∈N}\{\frac{mm (R^n)}{n} : n\in \N \} is infinite

    HIERARCHICAL ONTOLOGY OF THE BASIC CONCEPTS OF HARDWARE, INFORMATION AND MANAGEMENT SUPPORT FOR THE CONDITION OF A CARDIAC SURGICAL SUTURE

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    The proposed topic includes the development of classification systems and structuring of the basic concepts associated with cardiac surgical sutures to ensure the expected process of information management and quality care for patients with cardiovascular diseases

    MHD alpha^2-dynamo, Squire equation and PT-symmetric interpolation between square well and harmonic oscillator

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    It is shown that the alpha^2-dynamo of Magnetohydrodynamics, the hydrodynamic Squire equation as well as an interpolation model of PT-symmetric Quantum Mechanics are closely related as spectral problems in Krein spaces. For the alpha^2-dynamo and the PT-symmetric model the strong similarities are demonstrated with the help of a 2x2 operator matrix representation, whereas the Squire equation is re-interpreted as a rescaled and Wick-rotated PT-symmetric problem. Based on recent results on the Squire equation the spectrum of the PT-symmetric interpolation model is analyzed in detail and the Herbst limit is described as spectral singularity.Comment: 21 pages, LaTeX2e, 10 figures, minor improvements, references added, to appear in J. Math. Phy

    Π‘ΠΈΠ½Ρ‚Π΅Π· Π°Π·ΠΎΠΌΠ΅Ρ‚ΠΈΠ½ΠΎΠ² Π½Π° основС ΠΏΡ€ΠΎΠΈΠ·Π²ΠΎΠ΄Π½Ρ‹Ρ… 4-Π°ΠΌΠΈΠ½ΠΎΠ±Π΅Π½Π·ΠΎΠ»ΡΡƒΠ»ΡŒΡ„Π°ΠΌΠΈΠ΄Π°

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    Synthesis of (Β£)-azomethines, derivatives of 4-aminobenzenesulfonamide (Streptocidum), by condensation of substituted vanillin-like benzaldehydes with streptocidum in methanol, has been described.ΠŸΡ€Π΅Π΄ΡΡ‚Π°Π²Π»Π΅Π½ синтСз Ρ„ΡƒΠ½ΠΊΡ†ΠΈΠΎΠ½Π°Π»ΡŒΠ½ΠΎ Π·Π°ΠΌΠ΅Ρ‰Π΅Π½Π½Ρ‹Ρ… ароматичСских (Π•)-Π°Π·ΠΎΠΌΠ΅Ρ‚ΠΈΠ½ΠΎΠ² - ΠΏΡ€ΠΎΠΈΠ·Π²ΠΎΠ΄Π½Ρ‹Ρ… 4-Π°ΠΌΠΈΠ½ΠΎΠ±Π΅Π½Π·ΠΎΠ»-ΡΡƒΠ»ΡŒΡ„Π°ΠΌΠΈΠ΄Π° (стрСптоцида), ΠΏΠΎΠ»ΡƒΡ‡Π΅Π½Π½Ρ‹Ρ… кондСнсациСй Π·Π°ΠΌΠ΅Ρ‰Π΅Π½Π½Ρ‹Ρ… бСнзальдСгидов Π²Π°Π½ΠΈΠ»ΠΈΠ½ΠΎΠ²ΠΎΠ³ΠΎ ряда ΠΈ стрСптоцида Π² срСдС ΠΌΠ΅Ρ‚Π°Π½ΠΎΠ»Π° с Π²Ρ‹Ρ…ΠΎΠ΄ΠΎΠΌ 70-82%

    Group measure space decomposition of II_1 factors and W*-superrigidity

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    We prove a "unique crossed product decomposition" result for group measure space II_1 factors arising from arbitrary free ergodic probability measure preserving (p.m.p.) actions of groups \Gamma in a fairly large family G, which contains all free products of a Kazhdan group and a non-trivial group, as well as certain amalgamated free products over an amenable subgroup. We deduce that if T_n denotes the group of upper triangular matrices in PSL(n,Z), then any free, mixing p.m.p. action of the amalgamated free product of PSL(n,Z) with itself over T_n, is W*-superrigid, i.e. any isomorphism between L^\infty(X) \rtimes \Gamma and an arbitrary group measure space factor L^\infty(Y) \rtimes \Lambda, comes from a conjugacy of the actions. We also prove that for many groups \Gamma in the family G, the Bernoulli actions of \Gamma are W*-superrigid.Comment: Final version. Some extra details have been added to improve the expositio

    Π‘Π˜ΠΠ’Π•Π— (E,E)-ΠΠ—ΠžΠœΠ•Π’Π˜ΠΠžΠšΠ‘Π˜ΠœΠžΠ’ НА ΠžΠ‘ΠΠžΠ’Π• ОКБИМА 4-ΠΠœΠ˜ΠΠžΠΠ¦Π•Π’ΠžΠ€Π•ΠΠžΠΠ

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    4-Aminoacetophenone oxime is convenient and accessible reagent for chemical modification of substituted aromatic aldehydes to produce ligands for complexation with transition metals. By the reaction of 4-aminoacetophenone oxime with aldehydes vanillyl series by boiling in absolute methanol in the presence of catalytic amounts of glacial acetic acid, (E,E)-azomethyneoximes with 70–85 % yields were synthesized. By the reaction of 4-aminoacetophenone oxime with 9-phenanthrene carboxaldehyde, ferrocene carboxaldehyde, 5-phenylisoxazole-3-carboxaldehyde and 5-(p-tolyl)isoxazole- 3-carboxaldehyde, corresponding (E,E)-azomethineoximes with 77–84 % yield were obtained. By acylation of the (E)-1-{4-(E)-benzo[d][1,3]dioxol-5-ylmethyleneaminophenyl}ethan-1-one oxime in a solution of dry diethyl ester in the presence of triethylamine, corresponding ester was synthesized with 84 % yield. By quantum chemical calculations using DFT method using level B3LYP1 / MIDI using the theory GAMESS software package and a MIDI basic set, we defined the most thermodynamically stable isomers of the synthesized compounds. In the process of calculations a full optimization of all geometric parameters to achieve a minimum total energy (E,E)-, (E,Z)-, (Z,E)- and (Z,Z)-azomethineoximes was carried out.Оксим 4-Π°ΠΌΠΈΠ½ΠΎΠ°Ρ†Π΅Ρ‚ΠΎΡ„Π΅Π½ΠΎΠ½Π° являСтся ΡƒΠ΄ΠΎΠ±Π½Ρ‹ΠΌ ΠΈ доступным Ρ€Π΅Π°Π³Π΅Π½Ρ‚ΠΎΠΌ для химичСской ΠΌΠΎΠ΄ΠΈΡ„ΠΈΠΊΠ°Ρ†ΠΈΠΈ Π·Π°ΠΌΠ΅Ρ‰Π΅Π½Π½Ρ‹Ρ… ароматичСских альдСгидов с Ρ†Π΅Π»ΡŒΡŽ получСния Π»ΠΈΠ³Π°Π½Π΄ΠΎΠ² для комплСксообразования с ΠΏΠ΅Ρ€Π΅Ρ…ΠΎΠ΄Π½Ρ‹ΠΌΠΈ ΠΌΠ΅Ρ‚Π°Π»Π»Π°ΠΌΠΈ. ВзаимодСйствиСм оксима 4-Π°ΠΌΠΈΠ½ΠΎΠ°Ρ†Π΅Ρ‚ΠΎΡ„Π΅Π½ΠΎΠ½Π° с альдСгидами Π²Π°Π½ΠΈΠ»ΠΈΠ½ΠΎΠ²ΠΎΠ³ΠΎ ряда, Π² срСдС кипящСго Π°Π±ΡΠΎΠ»ΡŽΡ‚Π½ΠΎΠ³ΠΎ ΠΌΠ΅Ρ‚Π°Π½ΠΎΠ»Π° Π² присутствии каталитичСских количСств лСдяной уксусной кислоты Π±Ρ‹Π»ΠΈ синтСзированы (E,E)-Π°Π·ΠΎΠΌΠ΅Ρ‚ΠΈΠ½Ρ‹ с Π²Ρ‹Ρ…ΠΎΠ΄Π°ΠΌΠΈ 70–85 %. ВзаимодСйствиСм 4-Π°ΠΌΠΈΠ½ΠΎΠ°Ρ†Π΅Ρ‚ΠΎΡ„Π΅Π½ΠΎΠ½Π° с 9-Ρ„Π΅Π½Π°Π½Ρ‚Ρ€Π΅Π½ΠΊΠ°Ρ€Π±Π°Π»ΡŒΠ΄Π΅Π³ΠΈΠ΄ΠΎΠΌ, Ρ„Π΅Ρ€Ρ€ΠΎΡ†Π΅Π½ΠΊΠ°Ρ€Π±Π°Π»ΡŒΠ΄Π΅Π³ΠΈΠ΄ΠΎΠΌ, 5-фСнилизоксазол-3-ΠΊΠ°Ρ€Π±Π°Π»ΡŒΠ΄Π΅Π³ΠΈΠ΄ΠΎΠΌ ΠΈ 5-(ΠΏ-Ρ‚ΠΎΠ»ΠΈΠ»)изоксазол-3-ΠΊΠ°Ρ€Π±Π°Π»ΡŒΠ΄Π΅Π³ΠΈΠ΄ΠΎΠΌ Π±Ρ‹Π»ΠΈ ΠΏΠΎΠ»ΡƒΡ‡Π΅Π½Ρ‹ ΡΠΎΠΎΡ‚Π²Π΅Ρ‚ΡΡ‚Π²ΡƒΡŽΡ‰ΠΈΠ΅ (E,E)-азомСтиноксимы c Π²Ρ‹Ρ…ΠΎΠ΄ΠΎΠΌ 77–84 %. АцилированиСм оксима (E)-1-{4-(E)-Π±Π΅Π½Π·ΠΎ[d][1,3]диоксол-5-ΠΈΠ»ΠΌΠ΅Ρ‚ΠΈΠ»Π΅Π½Π°ΠΌΠΈΠ½ΠΎΡ„Π΅Π½ΠΈΠ»}этан-1-ΠΎΠ½Π° Ρ…Π»ΠΎΡ€Π°Π½Π³ΠΈΠ΄Ρ€ΠΈΠ΄ΠΎΠΌ 4,5-Π΄ΠΈΡ…Π»ΠΎΡ€ΠΈΠ·ΠΎΡ‚ΠΈΠ°Π·ΠΎΠ»-3-ΠΊΠ°Ρ€Π±ΠΎΠ½ΠΎΠ²ΠΎΠΉ кислоты Π² растворС сухого диэтилового эфира Π² присутствии триэтиламина Π±Ρ‹Π» синтСзирован ΡΠΎΠΎΡ‚Π²Π΅Ρ‚ΡΡ‚Π²ΡƒΡŽΡ‰ΠΈΠΉ слоТный эфир с Π²Ρ‹- Ρ…ΠΎΠ΄ΠΎΠΌ 84 %. ΠŸΡƒΡ‚Π΅ΠΌ ΠΊΠ²Π°Π½Ρ‚ΠΎΠ²ΠΎ-химичСских расчСтов с использованиСм ΠΌΠ΅Ρ‚ΠΎΠ΄Π° DFT с ΠΏΡ€ΠΈΠΌΠ΅Π½Π΅Π½ΠΈΠ΅ΠΌ уровня Ρ‚Π΅ΠΎΡ€ΠΈΠΈ B3LYP1/MIDI, ΠΏΡ€ΠΎΠ³Ρ€Π°ΠΌΠΌΠ½ΠΎΠ³ΠΎ ΠΏΠ°ΠΊΠ΅Ρ‚Π° GAMESS ΠΈ базисного Π½Π°Π±ΠΎΡ€Π° MIDI установлСны Π½Π°ΠΈΠ±ΠΎΠ»Π΅Π΅ тСрмодинамичСски устойчивыС ΠΈΠ·ΠΎΠΌΠ΅Ρ€Ρ‹ ряда синтСзированных соСдинСний. ΠŸΡ€ΠΈ расчСтах ΠΏΡ€ΠΎΠ²ΠΎΠ΄ΠΈΠ»ΠΈ ΠΎΠΏΡ‚ΠΈΠΌΠΈΠ·Π°Ρ†ΠΈΡŽ всСх гСомСтричСских ΠΏΠ°Ρ€Π°ΠΌΠ΅Ρ‚Ρ€ΠΎΠ² Π΄ΠΎ достиТСния ΠΌΠΈΠ½ΠΈΠΌΡƒΠΌΠΎΠ² ΠΏΠΎΠ»Π½Ρ‹Ρ… элСктронных энСргий (E,E)-, (E,Z)-(Z,E)- ΠΈ (Z,Z)-азомСтиноксимов
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