Stimuli-Responsive Reversible Assembly of 2D and 3D Metallosupramolecular Architectures

The discovery of interconvertible platinum coordination modes, which reveals and masks cis coordinating groups upon addition of acid and base, respectively, has been exploited to facilitate stimuli-responsive assembly and disassembly of both two- and three-dimensional metallosupramolecular architectures. Treatment of a binclear platinum complex with acid along with ditopic and tritopic donor ligands generated a molecular square and a trigonal prism, respectively, in good to high yield. These complexes were unambiguously identified using electrospray mass spectrometry, H-1 NMR spectroscopy, and X-ray crystallography. Both assemblies can be disassembled into their constituent parts simply by treatment with base, and the prism can be cycled between the assembled and disassembled states by the alternate addition of acid and base.</p

Lattice Spaces: Form optimisation throgh customization of non developable 3d wood surfaces

This paper discusses a collaborative project by RDAI architects, Bollinger+Grohmann and the timber construction company Holzbau Amann. The project is located in a former swimming pool in Paris and it is part of the new interior of a flagship store of the French fashion label Hermes. In late 2009, Rena Duma Architects, asked Bollinger+Grohmann to collaborate as structural engineers on a challenging design proposal within a very short timeframe. Three wooden lattice structures, the so-called'bull'and one monumental staircase with a similar design approach characterize the interior of the new flagship store. The lattice structures are dividing the basement into different retail spaces. They vary in height (8-9 m) and diameter (8-12 m) and have a free-form shaped wicker basket appearance. Wood was the chosen material for these structures to strengthen the idea of the wickerbaskets and to create an interior space with a sustainable and innovative material