On the Kinetics of Body versus End Evaporation and Addition of Supramolecular Polymers

Although pathway-specific kinetic theories are fundamentally important to describe and understand reversible polymerisation kinetics, they come in principle at a cost of having a large number of system-specific parameters. Here, we construct a dynamical Landau theory to describe the kinetics of activated linear supramolecular self-assembly, which drastically reduces the number of parameters and still describes most of the interesting and generic behavior of the system in hand. This phenomenological approach hinges on the fact that if nucleated, the polymerisation transition resembles a phase transition. We are able to describe hysteresis, overshooting, undershooting and the existence of a lag time before polymerisation takes off, and pinpoint the conditions required for observing these types of phenomenon in the assembly and disassembly kinetics. We argue that the phenomenological kinetic parameter in our theory is a pathway controller, i.e., it controls the relative weights of the molecular pathways through which self-assembly takes place

Simulations Show that Vortex Flows could Heat the Chromosphere in Solar Plage

The relationship between vortex flows at different spatial scales and their contribution to the energy balance in the chromosphere is not yet fully understood. We perform three-dimensional (3D) radiation-magnetohydrodynamic (MHD) simulations of a unipolar solar plage region at a spatial resolution of 10 km using the MURaM code. We use the swirling-strength criterion that mainly detects the smallest vortices present in the simulation data. We additionally degrade our simulation data to smooth-out the smaller vortices, so that also the vortices at larger spatial scales can be detected. Vortex flows at various spatial scales are found in our simulation data for different effective spatial resolutions. We conclude that the observed large vortices are likely clusters of much smaller ones that are not yet resolved by observations. We show that the vertical Poynting flux decreases rapidly with reduced effective spatial resolutions and is predominantly carried by the horizontal plasma motions rather than vertical flows. Since the small-scale horizontal motions or the smaller vortices carry most of the energy, the energy transported by vortices deduced from low resolution data is grossly underestimated. In full resolution simulation data, the Poynting flux contribution due to vortices is more than adequate to compensate for the radiative losses in plage, indicating their importance for chromospheric heating.Comment: 8 pages, 5 figures, accepted in ApJ

Programmable optical waveform reshaping on a picosecond timescale

We experimentally demonstrate temporal reshaping of optical waveforms in the telecom wavelength band using the principle of quantum frequency conversion. The reshaped optical pulses do not undergo any wavelength translation. The interaction takes place in a nonlinear $\chi^{(2)}$ waveguide using an appropriately designed pump pulse programmed via an optical waveform generator. We show reshaping of a single-peak pulse into a double-peak pulse and vice versa. We also show that exponentially decaying pulses can be reshaped into near Gaussian shape, and vice versa, which is a useful functionality for quantum communications.Comment: Manuscript updated after comments from reviewers. Journal reference and DOI also adde

Wells and ill-fare: impacts of well failures on cultivators in hard rock areas of Madhya Pradesh

WellsDrillingCostsGroundwater depletionWater tableGroundwater irrigationOwnershipEconomic impactSocial impactCrop managementFood security

Rare case of huge rectal and uterovaginal prol

A case of combined genital prolapse and rectal prolapse in a 60-year-old multipara is reported. The treatment of mixed prolapse remains surgical and should be treated the genital prolapse by vaginal hysterectomy with pelvic floor repair and the rectal prolapse by means of the Delorme operation. The mortality and morbidity rates are zero if this operation is used and the relapse rate is only 8 to 11% for the rectal prolapse. It would appear that the two approaches are rarely associated by the authors and would seem to be interesting to reconsider this question by indicating mixed treatment of the two prolapses whenever possible