Dynamic characterization of cellulose nanofibrils in sheared and extended semi-dilute dispersions

New materials made through controlled assembly of dispersed cellulose nanofibrils (CNF) has the potential to develop into biobased competitors to some of the highest performing materials today. The performance of these new cellulose materials depends on how easily CNF alignment can be controlled with hydrodynamic forces, which are always in competition with a different process driving the system towards isotropy, called rotary diffusion. In this work, we present a flow-stop experiment using polarized optical microscopy (POM) to study the rotary diffusion of CNF dispersions in process relevant flows and concentrations. This is combined with small angle X-ray scattering (SAXS) experiments to analyze the true orientation distribution function (ODF) of the flowing fibrils. It is found that the rotary diffusion process of CNF occurs at multiple time scales, where the fastest scale seems to be dependent on the deformation history of the dispersion before the stop. At the same time, the hypothesis that rotary diffusion is dependent on the initial ODF does not hold as the same distribution can result in different diffusion time scales. The rotary diffusion is found to be faster in flows dominated by shear compared to pure extensional flows. Furthermore, the experimental setup can be used to quickly characterize the dynamic properties of flowing CNF and thus aid in determining the quality of the dispersion and its usability in material processes.Comment: 45 pages, 13 figure

Effect of Stiffness on the Dynamics of Entangled Nanofiber Networks at Low Concentrations

Biopolymer network dynamics play a significant role in both biological and materials science. This study focuses on the dynamics of cellulose nanofibers as a model system given their relevance to biology and nanotechnology applications. Using large-scale coarse-grained simulations with a lattice Boltzmann fluid coupling, we investigated the reptation behavior of individual nanofibers within entangled networks. Our analysis yields essential insights, proposing a scaling law for rotational diffusion, quantifying effective tube diameter, and revealing release mechanisms during reptation, spanning from rigid to semiflexible nanofibers. Additionally, we examine the onset of entanglement in relation to the nanofiber flexibility within the network. Microrheology analysis is conducted to assess macroscopic viscoelastic behavior. Importantly, our results align closely with previous experiments, validating the proposed scaling laws, effective tube diameters, and onset of entanglement. The findings provide an improved fundamental understanding of biopolymer network dynamics and guide the design of processes for advanced biobased materials

Non-Hermitian Hamiltonians in field theory

This thesis is centred around the role of non-Hermitian Hamiltonians in Physics both at the quantum and classical levels. In our investigations of two-level models we demonstrate [1] the phenomenon of fast transitions developed in the PT -symmetric quantum brachistochrone problem may in fact be attributed to the non-Hermiticity of evolution operator used, rather than to its invariance under PT operation. Transition probabilities are calculated for Hamiltonians which explicitly violate PT -symmetry. When it comes to Hilbert spaces of infinite dimension, starting with non-Hermitian Hamiltonians expressed as linear and quadratic combinations of the generators of the su(1; 1) Lie algebra, we construct [2] Hermitian partners in the same similarity class. Alongside, metrics with respect to which the original Hamiltonians are Hermitian are also constructed, allowing to assign meaning to a large class of non-Hermitian Hamiltonians possessing real spectra. The finding of exact results to establish the physical acceptability of other non-Hermitian models may be pursued by other means, especially if the system of interest cannot be expressed in terms of Lie algebraic elements. We also employ [3] a representation of the canonical commutation relations for position and momentum operators in terms of real-valued functions and a noncommutative product rule of differential form. Besides exact solutions, we also compute in a perturbative fashion metrics and isospectral partners for systems of physical interest. Classically, our efforts were concentrated on integrable models presenting PT - symmetry. Because the latter can also establish the reality of energies in classical systems described by Hamiltonian functions, we search for new families of nonlinear differential equations for which the presence of hidden symmetries allows one to assemble exact solutions. We use [4] the Painleve test to check whether deformations of integrable systems preserve integrability. Moreover we compare [5] integrable deformed models, which are thus likely to possess soliton solutions, to a broader class of systems presenting compacton solutions. Finally we study [6] the pole structure of certain real valued nonlinear integrable systems and establish that they behave as interacting particles whose motion can be extended to the complex plane in a PT -symmetric way.EThOS - Electronic Theses Online ServiceGBUnited Kingdo

Layer-by-Layer Spray-Coating of Cellulose Nanofibrils and Silver Nanoparticles for Hydrophilic Interfaces

Silver nanoparticles (AgNPs) and AgNP-based composite materials have attracted growing interest due to their structure-dependent optical, electrical, catalytic, and stimuli-responsive properties. For practical applications, polymeric materials are often combined with AgNPs to provide flexibility and offer a scaffold for homogenous distribution of the AgNPs. However, the control over the assembly process of AgNPs on polymeric substrates remains a big challenge. Herein, we report the fabrication of AgNP/cellulose nanofibril (CNF) thin films via layer-by-layer (LBL) spray-coating. The morphology and self-assembly of AgNPs with increasing number of spray cycles are characterized by atomic force microscopy (AFM), grazing-incidence small-angle X-ray scattering (GISAXS), and grazing-incidence wide-angle X-ray scattering (GIWAXS). We deduce that an individual AgNP (radius = 15 ± 3 nm) is composed of multiple nanocrystallites (diameter = 2.4 ± 0.9 nm). Our results suggest that AgNPs are assembled into large agglomerates on SiO2 substrates during spray-coating, which is disadvantageous for AgNP functionalization. However, the incorporation of CNF substrates contributes to a more uniform distribution of AgNP agglomerates and individual AgNPs by its network structure and by absorbing the partially dissolved AgNP agglomerates. Furthermore, we demonstrate that the spray-coating of the AgNP/CNF mixture results in similar topography and agglomeration patterns of AgNPs compared to depositing AgNPs onto a precoated CNF thin film. Contact-angle measurements and UV/vis spectroscopy suggest that the deposition of AgNPs onto or within CNFs could increase the hydrophilicity of AgNP-containing surfaces and the localized surface plasmon resonance (LSPR) intensity of AgNP compared to AgNPs sprayed on SiO2 substrates, suggesting their potential applications in antifouling coatings or label-free biosensors. Thereby, our approach provides a platform for a facile and scalable production of AgNP/CNF films with a low agglomeration rate by two different methods as follows: (1) multistep layer-by-layer (LBL) spray-coating and (2) direct spray-coating of the AgNP/CNF mixture. We also demonstrate the ability of CNFs as a flexible framework for directing the uniform assembly of AgNPs with tailorable wettability and plasmonic properties

Measuring the quantum state of photoelectrons

A photoelectron, emitted due to the absorption of light quanta as described by the photoelectric effect, is often characterized experimentally by a classical quantity, its momentum. However, since the photoelectron is a quantum object, its rigorous characterization requires the reconstruction of the complete quantum state, the photoelectron's density matrix. Here, we use quantum state tomography to fully characterize photoelectrons emitted from helium and argon atoms upon absorption of ultrashort, extreme ultraviolet light pulses. While in helium we measure a pure photoelectronic state, in argon, spin-orbit interaction induces entanglement between the ion and the photoelectron, leading to a reduced purity of the photoelectron state. Our work shows how state tomography gives new insights into the fundamental quantum aspects of light-induced electronic processes in matter, bridging the fields of photoelectron spectroscopy and quantum information, and offering new spectroscopic possibilities for quantum technology

Electron Identification with a Prototype of the Transition Radiation Tracker for the ATLAS experiment

A prototype of the Transition Radiation Tracker (TRT) for the ATLAS detector at the LHC has been built and tested. The TRT is an array of straw tubes which integrate tracking and electron identification by transition radiation into one device. Results of experimental measurements and of comparisons with Monte Carlo simulations are presented for the electron identification performance as a function of various detector parameters. Under optimal operating conditions, a rejection against pions of a factor 100 was achieved with 90\% electron efficiency

Variation in Structure and Process of Care in Traumatic Brain Injury: Provider Profiles of European Neurotrauma Centers Participating in the CENTER-TBI Study.

INTRODUCTION: The strength of evidence underpinning care and treatment recommendations in traumatic brain injury (TBI) is low. Comparative effectiveness research (CER) has been proposed as a framework to provide evidence for optimal care for TBI patients. The first step in CER is to map the existing variation. The aim of current study is to quantify variation in general structural and process characteristics among centers participating in the Collaborative European NeuroTrauma Effectiveness Research in Traumatic Brain Injury (CENTER-TBI) study. METHODS: We designed a set of 11 provider profiling questionnaires with 321 questions about various aspects of TBI care, chosen based on literature and expert opinion. After pilot testing, questionnaires were disseminated to 71 centers from 20 countries participating in the CENTER-TBI study. Reliability of questionnaires was estimated by calculating a concordance rate among 5% duplicate questions. RESULTS: All 71 centers completed the questionnaires. Median concordance rate among duplicate questions was 0.85. The majority of centers were academic hospitals (n = 65, 92%), designated as a level I trauma center (n = 48, 68%) and situated in an urban location (n = 70, 99%). The availability of facilities for neuro-trauma care varied across centers; e.g. 40 (57%) had a dedicated neuro-intensive care unit (ICU), 36 (51%) had an in-hospital rehabilitation unit and the organization of the ICU was closed in 64% (n = 45) of the centers. In addition, we found wide variation in processes of care, such as the ICU admission policy and intracranial pressure monitoring policy among centers. CONCLUSION: Even among high-volume, specialized neurotrauma centers there is substantial variation in structures and processes of TBI care. This variation provides an opportunity to study effectiveness of specific aspects of TBI care and to identify best practices with CER approaches