2,944 research outputs found

    Green synthesis of Fe3O4 nanoparticles embedded in a porous carbon matrix and its use as anode material for Li-ion batteries

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    A scalable and simple process was developed for the preparation of Fe3O4 nanoparticles embedded in carbon using nontoxic and affordable materials. The resulting composite showed a high reversible capacity of 702 mA h g(-1) as anode material in a Li-ion battery after 50 cycles.Latorre Sánchez, M.; Primo Arnau, AM.; García Gómez, H. (2012). Green synthesis of Fe3O4 nanoparticles embedded in a porous carbon matrix and its use as anode material for Li-ion batteries. Journal of Materials Chemistry. 22(40):21373-21375. doi:10.1039/c2jm34978gS21373213752240Aricò, A. S., Bruce, P., Scrosati, B., Tarascon, J.-M., & van Schalkwijk, W. (2005). Nanostructured materials for advanced energy conversion and storage devices. Nature Materials, 4(5), 366-377. doi:10.1038/nmat1368Kang, K. (2006). Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries. Science, 311(5763), 977-980. doi:10.1126/science.1122152Armand, M., & Tarascon, J.-M. (2008). Building better batteries. Nature, 451(7179), 652-657. doi:10.1038/451652aTirado, J. L. (2003). Inorganic materials for the negative electrode of lithium-ion batteries: state-of-the-art and future prospects. Materials Science and Engineering: R: Reports, 40(3), 103-136. doi:10.1016/s0927-796x(02)00125-0Etacheri, V., Marom, R., Elazari, R., Salitra, G., & Aurbach, D. (2011). Challenges in the development of advanced Li-ion batteries: a review. Energy & Environmental Science, 4(9), 3243. doi:10.1039/c1ee01598bPoizot, P., Laruelle, S., Grugeon, S., Dupont, L., & Tarascon, J.-M. (2000). Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries. Nature, 407(6803), 496-499. doi:10.1038/35035045Yu, Y., Chen, C.-H., Shui, J.-L., & Xie, S. (2005). Nickel-Foam-Supported Reticular CoO-Li2O Composite Anode Materials for Lithium Ion Batteries. Angewandte Chemie International Edition, 44(43), 7085-7089. doi:10.1002/anie.200501905Liu, D., Garcia, B. B., Zhang, Q., Guo, Q., Zhang, Y., Sepehri, S., & Cao, G. (2009). Mesoporous Hydrous Manganese Dioxide Nanowall Arrays with Large Lithium Ion Energy Storage Capacities. Advanced Functional Materials, 19(7), 1015-1023. doi:10.1002/adfm.200801515Cabana, J., Monconduit, L., Larcher, D., & Palacín, M. R. (2010). Beyond Intercalation-Based Li-Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions. Advanced Materials, 22(35), E170-E192. doi:10.1002/adma.201000717Taberna, P. L., Mitra, S., Poizot, P., Simon, P., & Tarascon, J.-M. (2006). High rate capabilities Fe3O4-based Cu nano-architectured electrodes for lithium-ion battery applications. Nature Materials, 5(7), 567-573. doi:10.1038/nmat1672Ban, C., Wu, Z., Gillaspie, D. T., Chen, L., Yan, Y., Blackburn, J. L., & Dillon, A. C. (2010). Nanostructured Fe3O4/SWNT Electrode: Binder-Free and High-Rate Li-Ion Anode. Advanced Materials, 22(20), E145-E149. doi:10.1002/adma.200904285Zhou, G., Wang, D.-W., Li, F., Zhang, L., Li, N., Wu, Z.-S., … Cheng, H.-M. (2010). Graphene-Wrapped Fe3O4Anode Material with Improved Reversible Capacity and Cyclic Stability for Lithium Ion Batteries. Chemistry of Materials, 22(18), 5306-5313. doi:10.1021/cm101532xZhu, T., Chen, J. S., & Lou, X. W. (David). (2011). Glucose-Assisted One-Pot Synthesis of FeOOH Nanorods and Their Transformation to Fe3O4@Carbon Nanorods for Application in Lithium Ion Batteries. The Journal of Physical Chemistry C, 115(19), 9814-9820. doi:10.1021/jp2013754Liu, H., Wang, G., Wang, J., & Wexler, D. (2008). Magnetite/carbon core-shell nanorods as anode materials for lithium-ion batteries. Electrochemistry Communications, 10(12), 1879-1882. doi:10.1016/j.elecom.2008.09.036He, Y., Huang, L., Cai, J.-S., Zheng, X.-M., & Sun, S.-G. (2010). Structure and electrochemical performance of nanostructured Fe3O4/carbon nanotube composites as anodes for lithium ion batteries. Electrochimica Acta, 55(3), 1140-1144. doi:10.1016/j.electacta.2009.10.014Yang, Z., Shen, J., & Archer, L. A. (2011). An in situ method of creating metal oxide–carbon composites and their application as anode materials for lithium-ion batteries. Journal of Materials Chemistry, 21(30), 11092. doi:10.1039/c1jm10902bZhang, W.-M., Wu, X.-L., Hu, J.-S., Guo, Y.-G., & Wan, L.-J. (2008). Carbon Coated Fe3O4Nanospindles as a Superior Anode Material for Lithium-Ion Batteries. Advanced Functional Materials, 18(24), 3941-3946. doi:10.1002/adfm.200801386Piao, Y., Kim, H. S., Sung, Y.-E., & Hyeon, T. (2010). Facile scalable synthesis of magnetitenanocrystals embedded in carbon matrix as superior anode materials for lithium-ion batteries. Chem. Commun., 46(1), 118-120. doi:10.1039/b920037aZhang, M., Lei, D., Yin, X., Chen, L., Li, Q., Wang, Y., & Wang, T. (2010). Magnetite/graphene composites: microwave irradiation synthesis and enhanced cycling and rate performances for lithium ion batteries. Journal of Materials Chemistry, 20(26), 5538. doi:10.1039/c0jm00638fYoon, T., Chae, C., Sun, Y.-K., Zhao, X., Kung, H. H., & Lee, J. K. (2011). Bottom-up in situ formation of Fe3O4 nanocrystals in a porous carbon foam for lithium-ion battery anodes. Journal of Materials Chemistry, 21(43), 17325. doi:10.1039/c1jm13450gBehera, S. K. (2011). Enhanced rate performance and cyclic stability of Fe3O4–graphene nanocomposites for Li ion battery anodes. Chemical Communications, 47(37), 10371. doi:10.1039/c1cc13218kFundueanu, G., Nastruzzi, C., Carpov, A., Desbrieres, J., & Rinaudo, M. (1999). Physico-chemical characterization of Ca-alginate microparticles produced with different methods. Biomaterials, 20(15), 1427-1435. doi:10.1016/s0142-9612(99)00050-2Davis, T. A., Volesky, B., & Mucci, A. (2003). A review of the biochemistry of heavy metal biosorption by brown algae. Water Research, 37(18), 4311-4330. doi:10.1016/s0043-1354(03)00293-8YAKUPARINODOTCA, M. (2004). Biosorption of Hg2+, Cd2+, and Zn2+ by Ca-alginate and immobilized wood-rotting fungus Funalia trogii. Journal of Hazardous Materials, 109(1-3), 191-199. doi:10.1016/j.jhazmat.2004.03.017Gibaud, A., Xue, J. S., & Dahn, J. R. (1996). A small angle X-ray scattering study of carbons made from pyrolyzed sugar. Carbon, 34(4), 499-503. doi:10.1016/0008-6223(95)00207-3Raymundo-Piñero, E., Leroux, F., & Béguin, F. (2006). A High-Performance Carbon for Supercapacitors Obtained by Carbonization of a Seaweed Biopolymer. Advanced Materials, 18(14), 1877-1882. doi:10.1002/adma.200501905Chen, J. S., Zhang, Y., & Lou, X. W. (David). (2011). One-Pot Synthesis of Uniform Fe3O4 Nanospheres with Carbon Matrix Support for Improved Lithium Storage Capabilities. ACS Applied Materials & Interfaces, 3(9), 3276-3279. doi:10.1021/am201079zBonhomme, F., Lassègues, J. C., & Servant, L. (2001). Raman Spectroelectrochemistry of a Carbon Supercapacitor. Journal of The Electrochemical Society, 148(11), E450. doi:10.1149/1.1409546Sadezky, A., Muckenhuber, H., Grothe, H., Niessner, R., & Pöschl, U. (2005). Raman microspectroscopy of soot and related carbonaceous materials: Spectral analysis and structural information. Carbon, 43(8), 1731-1742. doi:10.1016/j.carbon.2005.02.018Verma, P., Maire, P., & Novák, P. (2010). A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries. Electrochimica Acta, 55(22), 6332-6341. doi:10.1016/j.electacta.2010.05.07

    Módulo documentación máquinas recreativas SAP

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    El negocio de las máquinas recreativas está regulado por cada una de las Administraciones Públicas de cada Comunidad Autónoma. Por ello, es obligatorio la generación de documentación que acompaña a cada una de las máquinas que están siendo explotadas. Este proyecto describe el desarrollo de un módulo, dentro del ERP SAP R/3, para la generación de esta documentación a partir de las necesidades expresadas por el Departamento de Documentación, Trámites y Gestiones de CIRSA.El negoci de les màquines recreatives està regulat per cadascuna de les Administracions Públiques de cada Comunitat Autònoma. És per això, què és obligatori la generació de la documentació que acompanya a cadascuna de les màquinas que estàn sent explotades. Aquest projecte descriu el desenvolupament d'un mòdul, dins del ERP SAP R/3, per a la generació d'aquesta documentació a partir de les necessitats expressades pel Departament de Documentació, Tràmits i Gestions de CIRSA.The business of the recreative machines is regulated by each of the Public Administrations of every Autonomous Community. For it, there is obligatory the generation of documentation that accompanies on each of the machines that are being exploited. This project describes the development of a module, inside the ERP SAP R/3, for the generation of this documentation from the needs expressed by the Department of Documentation, Steps and CIRSA's Negotiations.Nota: Aquest document conté originàriament altre material i/o programari només consultable a la Biblioteca de Ciència i Tecnologia

    Analysis of additively manufactured notched PLA plates using failure assessment diagrams

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    This paper provides a methodology for the estimation of the load-bearing capacity of additively manufactured (AM) PLA plates containing different types of notches (U-notches, V-notches and holes). The methodology is based on the use of Failure Assessment Diagrams (FADs), which are the main fracture-plastic collapse assessment tool provided by structural integrity assessment procedures, such as BS7910 and API 579-1/ASME FFS-1. When analyzing notch-type defects, the FAD methodology requires the application of a notch correction which, in this work, is based on the Theory of Critical Distances (TCD) and the Creager-Paris stress distribution ahead of the crack-tip. The results show that the FAD methodology can be efficaciously applied in this AM polymer, providing safe conservative estimations of critical loads in U-notched and V-notched plates, and accurate slightly unsafe estimations in plates with central hole. The cracking behavior in the different tested plates is a complex procedure generated by a combination of filament failures and debonding processes.This publication is part of the project “Comportamiento en fractura y efecto entalla en compuestos de matriz termopl´astica obtenidos por fabricaci´on aditiva, PID2021-122324NB-I00” funded by MCIN/ AEI /10.13039/501100011033/FEDER “Una manera de hacer Europa”

    Using the point method to estimate failure loads in 3D printed graphene-reinforced PLA notched plates

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    This work estimates failure loads in Fused Filament Fabrication (FFF) printed graphene-reinforced PLA (polylactic acid) plates containing different types of stress risers. With this aim, firstly, several notched plates are tested and conducted to fracture. Then, linear elastic Finite Element (FE) analyses are completed to define the corresponding stress profiles and, finally, the Point Method (PM) is applied to establish the failure criterion. This approach asserts that fracture conditions are achieved when the stress level equates the inherent strength (σ0) at a distance from the notch tip equal to L/2, so both parameters (related to each other through the material fracture toughness, Kmat) have been defined beforehand. The estimations of fracture loads obtained following this approach agree with the experimental results. Thus, the present work demonstrates the accuracy of the PM to estimate failure loads in this 3D printed material.This publication is part of the project “Comportamiento en fractura y efecto entalla en compuestos de matriz termoplástica obtenidos por fabricación aditiva, PID2021-122324NB-I00” funded by MCIN/AEI/10.13039/501100011033/FEDER “Una manera de hacer Europa”

    Analysis of additively manufactured PLA containing notches using Failure Assessment Diagrams

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    ABSTRACT: This paper provides a methodology for the estimation of the load-bearing capacity of additively manufactured (AM) PLA specimens that may be applied to both cracked and notched conditions. The methodology is based on the use of Failure Assessment Diagrams (FADs), which are, in practice, the main fracture-plastic collapse assessment tool provided by structural integrity assessment procedures. When dealing with notch-type defects, the methodology requires, additionally, the application of a notch correction that it is based on the Theory of Critical Distances (TCD) and the Creager-Paris stress distribution ahead of the cracktip. The results show that the FAD methodology (alone, in cracked conditions, or in combination with the TCD in notched conditions) can be successfully applied in this AM polymer.This publication is part of the project “Comportamiento en fractura de materiales compuestos nano-reforzados con defectos tipo entalla, PGC2018-095400-B-I00” funded by MCIN/ AEI /10.13039/501100011033/ FEDER "Una manera de hacer Europa

    Master curve evaluation of ANP-5 steel using mini-CT specimens

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    The nuclear industry demands analyses that make possible the long-term operation of nuclear power plants (i.e., beyond 40 years). In this sense, one of the main challenges to overcome is the restricted amount of material available to extend the surveillance programs. To mitigate this issue, mini-CT specimens have been proposed for the evaluation of the fracture properties of reactor pressure vessel (RPV) materials, and particularly, the corresponding Master Curve. These specimens can be taken from the broken halves of previously tested Charpy specimens. In this work, mini-CT specimens have been employed to evaluate the reference temperature of the RPV ANP-5 steel in non-irradiated conditions. The results were compared with those obtained by means of conventional fracture tests.This project has received funding from the Euratom research and training programme 2020-2024, under grant agreement No. 900014. The significant contribution of the FRACTESUS project members is also acknowledged

    FRACture mechanics TEsting of irradiated RPV steels by means of SUb-sized Specimens: FRACTESUS PROJECT

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    This work presents the overall structure of the FRACTESUS project and the progress carried out so far. The project is part of the EURATOM work programme 2019-2020, topic NFRP-04: Innovation for Generation II and III reactors. The project developments will contribute to the long-term safe operation of nuclear power plants, addressing the goals of the European Union in terms of sustainable and green energy, where the decarbonisation of the energy system is a priority. FRACTESUS intends to demonstrate the reliability of measuring the fracture toughness of reactor pressure vessel steels by means of sub-sized specimens (e.g., 0.16 CT or mini CT specimens). This will allow, among others, to notably increase the number of specimens available in the surveillance programs of the nuclear power plants.This project has received funding from the Euratom research and training programme 2020-2024, under grant agreement No. 900014. The significant contribution of the FRACTESUS project members is also acknowledge

    Differentiation of autoimmune pancreatitis from pancreas cancer: utility of anti-amylase and anti-carbonic anhydrase II autoantibodies.

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    Purpose: To investigate the utility of different combinations of serum anti-carbonic anhydrase II antibodies (CA II Abs), anti-α amylase antibodies (AMY-α Abs) and IgG4 levels for the diagnosis of autoimmune pancreatitis (AIP). Methods: We recruited 93 patients with clinical suspicion for AIP and 94 patients as control groups between June 2003 and October 2009. Serum antibodies were measured using homemade enzyme linked immunosorbent assay and IgG4 levels were determined by nephelometry. Results: Both CA-II Abs and AMY-α Abs had the highest sensitivity (83%) although AMY-α Abs (89%) were more specific than CA-II Abs (75%). The presence of increased IgG4 levels was the most specific serological marker (94%), but it had the lowest sensitivity (58%). The combination of the three serological markers altogether had the highest specificity (99%) and positive predictive value (PPV) (86%), but they had a rather low sensitivity (50%). When we combined CA-II Abs and AMY-α Abs without IgG4 levels, we got the highest sensitivity (75%) and negative predictive value (98%) but the specificity and the PPV decreased to 93 and 50%, respectively. Importantly, AMY-α Abs were not detected in pancreas cancer. Conclusions: The presence of serum CA-II and AMY-α Abs with increased IgG4 is useful in the differential diagnosis of AIP from pancreatic cancer

    Los determinantes de la salud en Aragón: un estudio de necesidades de las personas con fibrosis quística

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    Para eliminar las situaciones de desigualdad que existen entre los diferentes colectivos de nuestra sociedad, es necesario conocer las peculiaridades de los mismos. El presente trabajo ofrece una aproximación diagnóstica de un grupo concreto de población: las personas con fibrosis quística. Desde la perspectiva que ofrecen los determinantes de la salud, se ha pretendido realizar un estudio de necesidades del mencionado conjunto de personas. De tal modo que facilite la labor tanto de la administración pública, como entidades privadas y asociaciones de usuarios para gestionar con mayor eficacia los recursos públicos y disminuir el efecto de las inequidades en salud

    Long-Term Effectiveness of a Smartphone App and a Smart Band on Arterial Stiffness and Central Hemodynamic Parameters in a Population with Overweight and Obesity (Evident 3 Study): Randomised Controlled Trial

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    Background: mHealth technologies could help to improve cardiovascular health; however, their effect on arterial stiffness and hemodynamic parameters has not been explored to date. Objective: To evaluate the effect of a mHealth intervention, at 3 and 12 months, on arterial stiffness and central hemodynamic parameters in a sedentary population with overweight and obesity. Methods: Randomised controlled clinical trial (Evident 3 study). 253 subjects were included: 127 in the intervention group (IG) and 126 in the control group (CG). The IG subjects were briefed on the use of the Evident 3 app and a smart band (Mi Band 2, Xiaomi) for 3 months to promote healthy lifestyles. All measurements were recorded in the baseline visit and at 3 and 12 months. The carotid-femoral pulse wave velocity (cfPWV) and the central hemodynamic parameters were measured using a SphigmoCor System® device, whereas the brachial-ankle pulse wave velocity (baPWV) and the Cardio Ankle Vascular Index (CAVI) were measured using a VaSera VS-2000® device. Results: Of the 253 subjects who attended the initial visit, 237 (93.7%) completed the visit at 3 months of the intervention, and 217 (85.3%) completed the visit at 12 months of the intervention. At 12 months, IG showed a decrease in peripheral augmentation index (PAIx) (−3.60; 95% CI −7.22 to −0.00) and ejection duration (ED) (−0.82; 95% CI −1.36 to −0.27), and an increase in subendocardial viability ratio (SEVR) (5.31; 95% CI 1.18 to 9.44). In CG, cfPWV decreased at 3 months (−0.28 m/s; 95% CI −0.54 to −0.02) and at 12 months (−0.30 m/s, 95% CI −0.54 to −0.05), central diastolic pressure (cDBP) decreased at 12 months (−1.64 mm/Hg; 95% CI −3.19 to −0.10). When comparing the groups we found no differences between any variables analyzed. Conclusions: In sedentary adults with overweight or obesity, the multicomponent intervention (Smartphone app and an activity-tracking band) for 3 months did not modify arterial stiffness or the central hemodynamic parameters, with respect to the control group. However, at 12 months, CG presented a decrease of cfPWV and cDBP, whereas IG showed a decrease of PAIx and ED and an increase of SEVR
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