Analyses of moisture in polymers and composites

A suitable method for the direct measurement of moisture concentrations after humidity/thermal exposure on state of the art epoxy and polyimide resins and their graphite and glass fiber reinforcements was investigated. Methods for the determination of moisture concentration profiles, moisture diffusion modeling and moisture induced chemical changes were examined. Carefully fabricated, precharacterized epoxy and polyimide neat resins and their AS graphite and S glass reinforced composites were exposed to humid conditions using heavy water (D20), at ambient and elevated temperatures. These specimens were fixtured to theoretically limit the D20 permeation to a unidirectional penetration axis. The analytical techniques evaluated were: (1) laser pyrolysis gas chromatography mass spectrometry; (2) solids probe mass spectrometry; (3) laser pyrolysis conventional infrared spectroscopy; and (4) infrared imaging thermovision. The most reproducible and sensitive technique was solids probe mass spectrometry. The fabricated exposed specimens were analyzed for D20 profiling after humidity/thermal conditioning at three exposure time durations

Entrepreneurial Innovation

This paper constructs an equilibrium model of entrepreneurial innovation where individuals differ in their attitude toward uncertainty.Unlike previous models of innovation, the firm-formation process is endogenous.An entrepreneur, who owns residual profits, utilizes an uncertain technology and hires a worker who may only be partially isolated from uncertainty.While the available production technologies are exogenously specified, the technologies that operate in equilibrium are endogenous, depending on both the entrepreneur's prior beliefs about the profitability of the technology, as well as the worker's willingness to work with the uncertain technology.The general equilibrium setting allows us to explore the impact of innovation on the nature of the firm. The relationship between technological uncertainty and the nature of the firm is able to explain the commonly observed S-shaped diffusion profile.As uncertainty falls, firms evolve from being entrepreneurial to corporate, finally becoming bureaucratic.entrepreneurship;uncertainty;innovation

Galaxy pairs in the Sloan Digital Sky Survey - XII: The fuelling mechanism of low excitation radio-loud AGN

We investigate whether the fuelling of low excitation radio galaxies (LERGs) is linked to major galaxy interactions. Our study utilizes a sample of 10,800 spectroscopic galaxy pairs and 97 post-mergers selected from the Sloan Digital Sky Survey with matches to multi-wavelength datasets. The LERG fraction amongst interacting galaxies is a factor of 3.5 higher than that of a control sample matched in local galaxy density, redshift and stellar mass. However, the LERG excess in pairs does not depend on projected separation and remains elevated out to at least 500 kpc, suggesting that major mergers are not their main fuelling channel. In order to identify the primary fuelling mechanism of LERGs, we compile samples of control galaxies that are matched in various host galaxy and environmental properties. The LERG excess is reduced, but not completely removed, when halo mass or D4000 are included in the matching parameters. However, when BOTH M_halo and D4000 are matched, there is no LERG excess and the 1.4 GHz luminosities (which trace jet mechanical power) are consistent between the pairs and control. In contrast, the excess of optical and mid-IR selected AGN in galaxy pairs is unchanged when the additional matching parameters are implemented. Our results suggest that whilst major interactions may trigger optically and mid-IR selected AGN, the gas which fuels the LERGs has two secular origins: one associated with the large scale environment, such as accretion from the surrounding medium or minor mergers, plus an internal stellar mechanism, such as winds from evolved stars.Comment: Accepted for publication in MNRAS Letters; 5 page

Dimethyl 2,2'-di-nitro-biphenyl-4,4'-di-carboxyl-ate.

The title compound, C16H12N2O8, exhibits two near-planar aromatic ester groups with ar-yl-ester dihedral angles of 2.1 (2) and 4.2 (3)°. The dihedral angle between the aromatic rings is 58.0 (1)°. The two nitro groups are tilted slightly from the plane of the aromatic rings, making dihedral angles of 14.1 (1) and 8.2 (2)°. In the crystal, mol-ecules are connected by weak C-H⋯O inter-actions, forming a three-dimensional network

Cartilage on the Move: Cartilage Lineage Tracing During Tadpole Metamorphosis

The reorganization of cranial cartilages during tadpole metamorphosis is a set of complex processes. The fates of larval cartilage-forming cells (chondrocytes) and sources of adult chondrocytes are largely unknown. Individual larval cranial cartilages may either degenerate or remodel, while many adult cartilages appear to form de novo during metamorphosis. Determining the extent to which adult chondrocytes/cartilages are derived from larval chondrocytes during metamorphosis requires new techniques in chondrocyte lineage tracing. We have developed two transgenic systems to label cartilage cells throughout the body with fluorescent proteins. One system strongly labels early tadpole cartilages only. The other system inducibly labels forming cartilages at any developmental stage. We examined cartilages of the skull (viscero- and neurocranium), and identified larval cartilages that either resorb or remodel into adult cartilages. Our data show that the adult otic capsules, tecti anterius and posterius, hyale, and portions of Meckel\u27s cartilage are derived from larval chondrocytes. Our data also suggest that most adult cartilages form de novo, though we cannot rule out the potential for extreme larval chondrocyte proliferation or de- and re-differentiation, which could dilute our fluorescent protein signal. The transgenic lineage tracing strategies developed here are the first examples of inducible, skeleton-specific, lineage tracing in Xenopus

Motivation profiles in sport: A self-determination theory perspective

The present study examined the link between motivation profiles among adult sports participants and the outcomes of enjoyment, effort, positive and negative affect, attitude toward sport participation, intention to continue sport participation, satisfaction, and persistence in sport. Two samples of participants (n = 590 and n = 555) completed the Sport Motivation Scale and a range of self-report measures to assess the outcome variables. Exploratory cluster analyses applied to Sample 1 and confirmatory cluster analysis applied to Sample 2 identified two clusters of sport participants. The first comprised participants with high scores on both non self-determined and self-determined motives. The second comprised participants with high scores on self-determined motives but low scores on non self- determined motives. Participants in the first cluster scored higher on all outcome variables. The results are discussed with reference to a more in-depth understanding of the motivation dynamics of sport participation based on Self-Determination Theory

SONTRAC—a scintillating plastic fiber tracking detector for neutron and proton imaging spectroscopy

SONTRAC (SOlar Neutron TRACking imager and spectrometer) is a conceptual instrument intended to measure the energy and incident direction of 20–150 MeV neutrons produced in solar flares. The intense neutron background in a low-Earth orbit requires that imaging techniques be employed to maximize an instrument’s signal-to-noise ratio. The instrument is comprised of mutually perpendicular, alternating layers of parallel, scintillating, plastic fibers that are viewed by optoelectronic devices. Two stereoscopic views of recoil proton tracks are necessary to determine the incident neutron’s direction and energy. The instrument can also be used as a powerful energetic proton imager. Data from a fully functional 3-d prototype are presented. Early results indicate that the instrument’s neutron energy resolution is approximately 10% with the neutron incident direction determined to within a few degrees

Crystal structure of dimethyl 9H-carbazole-2,7-di-carb-oxy-late.

In the title compound, C16H13NO4, the carbazole ring system is almost planar with non-H atoms possessing a mean deviation from planarity of 0.037 Å. The two ester groups are orientated trans to one another and tilted slightly from the mean plane of the carbazole ring system, making dihedral angles of 8.12 (6) and 8.21 (5)°. In the crystal, mol-ecules are linked by pairs of N-H⋯O hydrogen bonds forming inversion dimers. The dimers are linked by parallel slipped π-π inter-actions, forming slabs propagating along the b-axis direction [inter-centroid distance = 3.6042 (8) Å, inter-planar distance = 3.3437 (5) Å, slippage = 1.345 Å]