2,772 research outputs found
Effective non-additive pair potential for lock-and-key interacting particles: the role of the limited valence
Theoretical studies of self-assembly processes and condensed phases in
colloidal systems are often based on effective inter-particle potentials. Here
we show that developing an effective potential for particles interacting with a
limited number of ``lock-and-key'' selective bonds (due to the specificity of
bio-molecular interactions) requires -- beside the non-sphericity of the
potential -- a (many body) constraint that prevent multiple bonding on the same
site. We show the importance of retaining both valence and bond-selectivity by
developing, as a case study, a simple effective potential describing the
interaction between colloidal particles coated by four single-strand DNA
chains.Comment: 4 pages, 5 figure
Critical behaviors of sheared frictionless granular materials near jamming transition
Critical behaviors of sheared dense and frictionless granular materials in
the vicinity of the jamming transition are numerically investigated. From the
extensive molecular dynamics simulation, we verify the validity of the scaling
theory near the jamming transition proposed by Otsuki and Hayakawa (Prog.
Theor. Phys., 121, 647 (2009)). We also clarify the critical behaviors of the
shear viscosity and the pair correlation function based on both a phenomenology
and the simulation.Comment: 13pages, 26 figure
Complete bandgaps in one-dimensional left-handed periodic structures
Artificially fabricated structures with periodically modulated parameters
such as photonic crystals offer novel ways of controlling the flow of light due
to the existence of a range of forbidden frequencies associated with a photonic
bandgap. It is believed that modulation of the refractive index in all three
spatial dimensions is required to open a complete bandgap and prevent the
propagation of electromagnetic waves in all directions. Here we reveal that, in
a sharp contrast to what was known before and contrary to the accepted physical
intuition, a one-dimensional periodic structure containing the layers of
transparent left-handed (or negative-index) metamaterial can trap light in
three-dimensional space due to the existence of a complete bandgap.Comment: 4 pages, 5 figure
Dynamic regimes of hydrodynamically coupled self-propelling particles
We analyze the collective dynamics of self-propelling particles (spps) which
move at small Reynolds numbers including the hydrodynamic coupling to the
suspending solvent through numerical simulations. The velocity distribution
functions show marked deviations from Gaussian behavior at short times, and the
mean-square displacement at long times shows a transition from diffusive to
ballistic motion for appropriate driving mechanism at low concentrations. We
discuss the structures the spps form at long times and how they correlate to
their dynamic behavior.Comment: 7 pages, 4 figure
Quantifying the Reversible Association of Thermosensitive Nanoparticles
Under many conditions, biomolecules and nanoparticles associate by means of
attractive bonds, due to hydrophobic attraction. Extracting the microscopic
association or dissociation rates from experimental data is complicated by the
dissociation events and by the sensitivity of the binding force to temperature
(T). Here we introduce a theoretical model that combined with light-scattering
experiments allows us to quantify these rates and the reversible binding energy
as a function of T. We apply this method to the reversible aggregation of
thermoresponsive polystyrene/poly(N-isopropylacrylamide) core-shell
nanoparticles, as a model system for biomolecules. We find that the binding
energy changes sharply with T, and relate this remarkable switchable behavior
to the hydrophobic-hydrophilic transition of the thermosensitive nanoparticles
Structure characterization of hard sphere packings in amorphous and crystalline states
The channel size distribution in hard sphere systems, based on the local
neighbor correlation of four particle positions, is investigated for all volume
fractions up to jamming. For each particle, all three particle combinations of
neighbors define channels, which are relevant for the concept of caging. The
analysis of the channel size distribution is shown to be very useful in
distinguishing between gaseous, liquid, partially and fully crystallized, and
glassy (random) jammed states. A common microstructural feature of four
coplanar particles is observed in crystalline and glassy jammed states,
suggesting the presence of "hidden" two-dimensional order in three-dimensional
random close packings.Comment: 5 pages, 5 figure
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Removal of NOx and NOy in biomass burning plumes in the boundary layer over northern Australia
Fractionation effects in phase equilibria of polydisperse hard sphere colloids
The equilibrium phase behaviour of hard spheres with size polydispersity is
studied theoretically. We solve numerically the exact phase equilibrium
equations that result from accurate free energy expressions for the fluid and
solid phases, while accounting fully for size fractionation between coexisting
phases. Fluids up to the largest polydispersities that we can study (around
14%) can phase separate by splitting off a solid with a much narrower size
distribution. This shows that experimentally observed terminal polydispersities
above which phase separation no longer occurs must be due to non-equilibrium
effects. We find no evidence of re-entrant melting; instead, sufficiently
compressed solids phase separate into two or more solid phases. Under
appropriate conditions, coexistence of multiple solids with a fluid phase is
also predicted. The solids have smaller polydispersities than the parent phase
as expected, while the reverse is true for the fluid phase, which contains
predominantly smaller particles but also residual amounts of the larger ones.
The properties of the coexisting phases are studied in detail; mean diameter,
polydispersity and volume fraction of the phases all reveal marked
fractionation. We also propose a method for constructing quantities that
optimally distinguish between the coexisting phases, using Principal Component
Analysis in the space of density distributions. We conclude by comparing our
predictions to perturbative theories for near-monodisperse systems and to Monte
Carlo simulations at imposed chemical potential distribution, and find
excellent agreement.Comment: 21 pages, 23 figures, 2 table
High-Dispersion Optical Spectra of Nearby Stars Younger Than The Sun
We present high-dispersion (R~16,000) optical (3900-8700 A) spectra of 390
stars obtained with the Palomar 60 inch telescope. The majority of stars
observed are part of the Spitzer Legacy Science Program "The Formation and
Evolution of Planetary Systems." Through detailed analysis we determine stellar
properties for this sample, including radial and rotational velocities, Li I
6708 and Ha equivalent widths, the chromospheric activity index R'_HK, and
temperature- and gravity-sensitive line ratios. Several spectroscopic binaries
are also identified. From our tabulations, we illustrate basic age- and
rotation-related correlations among measured indices. One novel result is that
Ca II chromospheric emission appears to saturate at vsini values above ~30
km/s, similar to the well established saturation of X-rays that originate in
the spatially separate coronal regions.Comment: 1 electronic table; published in the Astronomical Journa
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