Electron Beam Induced Current Studies of Defect Induced Conductivity Inversion

Defect induced inversion of conductivity type was studied both at the surface and at a network of interfacially confined misfit dislocations in heteroepitaxial Si(Ge) on Si structures. The inversion was achieved by controlled contamination with Au and Ni metallic impurities introduced by diffusion from backside evaporated layers. A theoretical explanation of the defect electrical activity and the inversion effect is presented, along with temperature dependent beam induced current observations

Probing Spin-Vibronic Dynamics Using Femtosecond X-ray Spectroscopy

Ultrafast pump-probe spectroscopy within the X-ray regime is now possible owing to the devel- opment of X-ray Free Electrons Lasers (X-FELs) and are opening new opportunities for direct probing the correlated evolution of the nuclei, the electronic and spin degrees of freedom on the femtosecond timescale. In this contribution we use excited state wavepacket dynamics of the photoexcited decay of a new Fe(II) complex, [Fe(bmip)2]2+ (bmip=2,6-bis(3-methyl-imidazole- 1-ylidine)pyridine), to simulate the experimental observables associated with femtosecond Fe K- edge X-ray absorption near-edge structure (XANES) and X-ray emission (XES) spectra. We show how the evolution of the nuclear wavepacket is translated into the experimental observable and the sensitivity of these approaches for following excited state dynamics

The effectiveness and stability of impurity/defect interactions and their impact on minority carrier lifetime. Annual subcontract report, 1 August 1990--31 July 1991

This report covers the investigation and understanding of electrical activity of ``clean`` and metallic impurity decorated defects. A heterostructure containing a controlled number of deliberately introduced misfit dislocations is used as a model system to simulate a variety of defect/impurity interactions in photovoltaic materials. In addition, a noncontact laser/microwave deep-level transient spectroscopy technique is applied to characterize the minority carrier lifetime and determine the energy levels of defects. 59 refs

Very long baseline interferometry observations of the high-redshift blazar candidate J0141-5427

Active galactic nuclei (AGN) have been observed as far as redshift z~7. They are crucial in investigating the early Universe as well as the growth of supermassive black holes at their centres. Radio-loud AGN with their jets seen at a small viewing angle are called blazars and show relativistic boosting of their emission. Thus, their apparently brighter jets are easier to detect in the high-redshift Universe. DES J014132.4-542749.9 is a radio-luminous but X-ray weak blazar candidate at z = 5. We conducted high-resolution radio interferometric observations of this source with the Australian Long Baseline Array at 1.7 and 8.5 GHz. A single, compact radio emitting feature was detected at both frequencies with a flat radio spectrum. We derived the milliarcsecond-level accurate position of the object. The frequency dependence of its brightness temperature is similar to that of blazar sources observed at lower redshifts. Based on our observations, we can confirm its blazar nature. We compared its radio properties with those of two other similarly X-ray-weak and radio-bright AGN, and found that they show very different relativistic boosting characteristics.Comment: 8 pages, 4 figures, accepted for publication in PAS

Three little radio galaxies in the early Universe

Volonteri et al. (2011) found that the number of radio-loud quasars above redshift 4 calculated from the luminosity function (based upon Swift/BAT observations) is much smaller than the number estimated from the known high-redshift beamed sources, blazars, assuming that for every beamed source with a Lorentz factor of $\Gamma$, statistically $2 \Gamma^2$ non-beamed sources should exist. To explain the missing misaligned (non-beamed) population of high-redshift sources, they proposed various explanations, involving heavy optical obscuration and significantly different Lorentz factors at early cosmological epochs. Our EVN observations targeting high-redshift ($z>4$) blazar candidates revealed 3 sources not showing relativistic beaming, but rather kpc-scale double structures. These three sources have significant radio emission resolved out with the EVN, while they are compact on $\sim 5-10$ arcsec scale. Our dual-frequency ($1.5$ and $5$ GHz) e-MERLIN observations of these three sources revealed a rich morphology, bending jets, and hot spots with possible sites of interaction between the jets and the surrounding medium at intermediate scales.Comment: 6 pages, 3 figures, 1 table, accepted for the Proceedings of the 14th European VLBI Network Symposium & Users Meetin

Quantification of thermal ring flexibilities of aromatic and heteroaromatic compounds

The consequences of thermal fluctuations occurring at room temperatures on the aromatic character of a broad group of compounds were analyzed in three distinct ways. First of all, the ring deformations were modeled along normal coordinates coming from quantum thermo-chemistry computations. The amplitudes of vibrations were estimated according to absorbed energies at room temperature. Alternatively, in-plane and out-of-plane ring deformations were modeled via scanning procedure with partial relaxation of the molecular geometry. The influence of ring deformations on π–electron delocalization was expressed in terms of HOMA values. Besides, the ring deformability was defined as the averaged change of bond angles or dihedral angles constituting the ring that was associated with 1.5 kcal mol-1 increase of the system energy. The molecules structures adopted during vibrations at room temperature can lead to significant heterogeneity of structural index of aromaticity. The broad span of HOMA values was obtained for analyzed five- or six-membered aromatic and heteroaromatic rings. However, the averaged values obtained for such fluctuations almost perfectly match HOMA values of molecule in the ground state. It has been demonstrated that the ring deformability imposed by bond angle changes is much smaller than for dihedral angles with the same rise of system energy. Interestingly in the case of out-of-plane vibrations modeled by scanning procedure there is observed linear correlation between ring deformability and HOMA values. Proposed method for inclusion of thermal vibrations in the framework of π–electron delocalization provides natural shift of the way of thinking about aromaticity from a static quantity to a dynamic and heterogeneous one due to inclusion of a more realistic object of analysis – thermally deformed structures. From this perspective the thermal fluctuations are supposed to be non-negligible contributions to aromaticity phenomenon

High Genetic Diversity among Community-Associated Staphylococcus aureus in Europe: Results from a Multicenter Study

Background: Several studies have addressed the epidemiology of community-associated Staphylococcus aureus (CA-SA) in Europe; nonetheless, a comprehensive perspective remains unclear. In this study, we aimed to describe the population structure of CA-SA and to shed light on the origin of methicillin-resistant S. aureus (MRSA) in this continent. Methods and Findings: A total of 568 colonization and infection isolates, comprising both MRSA and methicillin-susceptible S. aureus (MSSA), were recovered in 16 European countries, from community and community-onset infections. The genetic background of isolates was characterized by molecular typing techniques (spa typing, pulsed-field gel electrophoresis and multilocus sequence typing) and the presence of PVL and ACME was tested by PCR. MRSA were further characterized by SCCmec typing. We found that 59 % of all isolates were associated with community-associated clones. Most MRSA were related with USA300 (ST8-IVa and variants) (40%), followed by the European clone (ST80-IVc and derivatives) (28%) and the Taiwan clone (ST59-IVa and related clonal types) (15%). A total of 83 % of MRSA carried Panton-Valentine leukocidin (PVL) and 14 % carried the arginine catabolic mobile element (ACME). Surprisingly, we found a high genetic diversity among MRSA clonal types (ST-SCCmec), Simpson’s index of diversity = 0.852 (0.788–0.916). Specifically, about half of the isolates carried novel associations between genetic background and SCCmec. Analysis by BURP showed that some CA-MSSA and CA-MRS

A Novel Gene, fudoh, in the SCCmec Region Suppresses the Colony Spreading Ability and Virulence of Staphylococcus aureus

Staphylococcus aureus colonies can spread on soft agar plates. We compared colony spreading of clinically isolated methicillin-sensitive S. aureus (MSSA) and methicillin-resistant S. aureus (MRSA). All MSSA strains showed colony spreading, but most MRSA strains (73%) carrying SCCmec type-II showed little colony spreading. Deletion of the entire SCCmec type-II region from these MRSA strains restored colony spreading. Introduction of a novel gene, fudoh, carried by SCCmec type-II into Newman strain suppressed colony spreading. MRSA strains with high spreading ability (27%) had no fudoh or a point-mutated fudoh that did not suppress colony spreading. The fudoh-transformed Newman strain had decreased exotoxin production and attenuated virulence in mice. Most community-acquired MRSA strains carried SCCmec type-IV, which does not include fudoh, and showed high colony spreading ability. These findings suggest that fudoh in the SCCmec type-II region suppresses colony spreading and exotoxin production, and is involved in S. aureus pathogenesis

CHILES. VII. Deep Imaging for the CHILES Project, an SKA Prototype

This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse, distribution, and reproduction in any medium, provided the original work is properly cited.Radio astronomy is undergoing a renaissance, as the next generation of instruments provides a massive leap forward in collecting area and therefore raw sensitivity. However, to achieve this theoretical level of sensitivity in the science data products, we need to address the much more pernicious systematic effects, which are the true limitation. These become all the more significant when we consider that much of the time used by survey instruments, such as the Square Kilometre Array (SKA), will be dedicated to deep surveys. CHILES is a deep H i survey of the COSMOS field, with 1000 hr of Very Large Array time. We present our approach for creating the image cubes from the first epoch, with discussions of the methods and quantification of the data quality from 946 to 1420 MHz—a redshift range of 0.5−0. We lay out the problems we had to solve and describe how we tackled them. These are important because CHILES is the first deep wide-band multiepoch H i survey and has relevance for ongoing and future surveys. We focus on the accumulated systematic errors in the imaging, as the goal is to deliver a high-fidelity image that is only limited by the random thermal errors. To understand and correct these systematic effects, we ideally manage them in the domain in which they arise, and that is predominately the visibility domain. CHILES is a perfect test bed for many of the issues we can expect for deep imaging with the SKA or ngVLA, and we discuss the lessons we have learned. © 2022. The Author(s). Published by the American Astronomical Society.he CHILES survey was partially supported by a collaborative research grant from the National Science Foundation under grant Nos. AST—1412843, 1412578, 1413102, 1413099, and 1412503. This research was supported by the Australian Research Council Centre of Excellence for All Sky Astrophysics in three Dimensions (ASTRO-3D), through project No. CE170100013, and by grants from Amazon Web Services, the AstroCompute project. The National Radio Astronomy Observatory is a facility of the National Science Foundation operated under cooperative agreement with Associated Universities Inc. Source flux densities in Table 2 were taken from the NASA/IPAC Extragalactic Database (NED), which is funded by the National Aeronautics and Space Administration and operated by the California Institute of Technology. J.M.v.d.H. acknowledges support from the European Research Council under the European Unions Seventh Framework Programme (FP/2007-2013)/ERC grant agreement No. 291531 (HIStoryNU). D.J.P., N.L., and E.S. acknowledge partial support from NSF grants No. AST 1412578 and AST-1149491 and from the WVU Eberly College Dean's office. K. R. acknowledges support from the Bundesministerium für Bildung und Forschung (BMBF) award 05A20WM4. K.M.H. acknowledges funding from the State Agency for Research of the Spanish Ministry of Science, Innovation and Universities through the "Center of Excellence Severo Ochoa" awarded to the Instituto de Astrofísica de Andalucía (SEV-2017-0709); from grant RTI2018-096228-B-C31 (Ministry of Science, Innovation and Universities/State Agency for Research/European Regional Development Funds, European Union); and from the coordination of the participation in SKA-SPAIN, funded by the Ministry of Science and innovation (MICIN).Peer reviewe