Estimating gender differences in access to jobs: females trapped at the bottom of the ladder

In this paper, we propose a job assignment model allowing for a gender difference in access to jobs. Males and females compete for the same job positions. They are primarily interested in the best-paid jobs. A structural relationship of the model can be used to empirically recover the probability ratio of females and males getting a given job position. As this ratio is allowed to vary with the rank of jobs in the wage distribution of positions, barriers in females' access to high-paid jobs can be detected and quantiffed. We estimate the gender relative probability of getting any given job position for full-time executives aged 40-45 in the private sector. This is done using an exhaustive French administrative dataset on wage bills. Our results show that the access to any job position is lower for females than for males. Also, females' access decreases with the rank of job positions in the wage distribution, which is consistent with females being faced with more barriers to high-paid jobs than to low-paid jobs. At the bottom of the wage distribution, the probability of females getting a job is 12% lower than the probability of males. The difference in probability is far larger at the top of the wage distribution and climbs to 50%.gender ; discrimination ; wages ; quantiles ; job assignment model ; glass ceiling

Modelling the kinetics of transesterification reaction of sunflower oil with ethanol in microreactors

Transesterification reaction of vegetable oil with ethanol leads to ethyl esters, used to date for applications principally in food and cosmetic industry. To open the application field to biofuels (to substitute current fuels resulting from fossil resources), the process efficiency has to be developed to be economically profitable. In this work, the sunflower oil ethanolysis was performed in a micro-scaled continuous device, inducing better control for heat and mass transfer in comparison with batch processes. Moreover, this device ensures kinetic data acquisition at the first seconds of the reaction, which was not feasible in a conventional batch process. These data were used to model occurring phenomena and to determine kinetic constants and mass transfer coefficients. A single set of these parameters is able to represent the evolution of the reaction media composition function of time for five ethanol to oil molar ratios (6.0, 9.0, 16.2, 22.7 and 45.4). The model was validated in reaction and diffusion mode. Finally, it was subsequently used to simulate reactions with other operational conditions and to propose other process implementation

Enhanced light emission from Carbon Nanotubes integrated in silicon micro-resonator

Single-wall carbon nanotube are considered a fascinating nanomaterial for photonic applications and are especially promising for efficient light emitter in the telecommunication wavelength range. Furthermore, their hybrid integration with silicon photonic structures makes them an ideal platform to explore the carbon nanotube instrinsic properties. Here we report on the strong photoluminescence enhancement from carbon nanotubes integrated in silicon ring resonator circuit under two pumping configurations: surface-illuminated pumping at 735 nm and collinear pumping at 1.26 {\mu}m. Extremely efficient rejection of the non-resonant photoluminescence was obtained. In the collinear approach, an emission efficiency enhancement by a factor of 26 has been demonstrated in comparison with classical pumping scheme. This demonstration pave the way for the development of integrated light source in silicon based on carbon nanotubes

On-line monitoring of the transesterification reaction carried out in microreactors using near infrared spectroscopy

Biodiesel can be produced from vegetable oils, animal fats, and waste cooking oils by transesterification with ethanol (also called ethanolysis) in order to substitute fossil fuels. In this work, the batch ethanolysis of high oleic sunflower oil was transferred into a continuous microstructured device, which induces a better control of heat and mass transfers. Various parameters were studied, notably the initial ethanol to oil molar ratio. An innovative method using NIR spectroscopy was also developed to on-line monitor the transesterification reaction of high oleic sunflower oil with ethanol in microreactors (circular PFA tube 1/1600 OD, 0.0200 ID). The reactions were monitored directly in the microreactors through sequential scans of the reaction medium by the means of an adequate probe. The asset of the method is that no sample collection or preparation is necessary. Partial Least Squares regression was used to develop calibration and prediction models between NIR spectral data and analytical data obtained by a reference method (gas chromatography with flame ionization detection, GC–FID). This method is fast, safe, reliable, nondestructive and inexpensive contrary to conventional procedures, such as gas chromatography and high performance liquid chromatography generally used to determine the composition of crude transesterification medium

On-line monitoring of the transesterification reaction between triglycerides and ethanol using near infrared spectroscopy combined with gas chromatography

Many analytical procedures have been developed to determine the composition of reaction mixtures during transesterification of vegetable oils with alcohols. However, despite their accuracy, these methods are time consuming and cannot be easily used for on-line monitoring. In this work, a fast analytical method was developed to on-line monitor the transesterification reaction of high oleic sunflower oil with ethanol using Near InfraRed spectroscopy and a multivariate approach. The reactions were monitored through sequential scans of the reaction medium with a probe in a one-liter batch reactor without collecting and preparing samples. To calibrate the NIR analytical method, gas chromatography-flame ionization detection was used as a reference method. The method was validated by studying the kinetics of the EtONa-catalyzed transesterification reaction. Activation energy (51.0 kJ/mol) was also determined by considering a pseudo second order kinetics model

Aerosol deposition and origin in French mountains estimated with soil inventories of 210Pb and artificial radionuclides

Radionuclide inventories were measured in soils from different French mountainous areas: Chaîne des Puys (Massif Central), Eastern Corsica, Jura, Montagne Noire, Savoie, Vosges and Rhine Valley. 210Pb soil inventories were used to estimate long-term (>75 yr) deposition of submicron aerosols. Whereas 210Pb total deposition is explained partly by wet deposition, as demonstrated by increase of 210Pb inventory with annual rainfall; a part of 210Pb in the soils of higher altitude is caused by orographic depositions. Using measurements of radionuclides coming from nuclear aerial weapon tests (137Cs and Pu isotopes), we were able to estimate the origin of aerosols deposited in high-altitude sites and to confirm the importance of occult deposition and feeder–seeder mechanism. Using a simple mass balance model, we estimate that occult deposition and feeder–seeder mechanisms account to more than 50% of total deposition of 210Pb and associated submicron aerosols in French altitude sites

Compensation de déformations en tomographie dynamique 3D conique

19 pagesIn dynamic tomography, the measured object or organs are no-longer supposed to be static in the scanner during the acquisition but are supposed to move or to be deformed. Our approach is the analytic deformation compensation during the reconstruction. Our work concentrates on 3D cone beam tomography. We introduce a new large class of deformations preserving the 3D cone beam geometry. We show that deformations from this class can be analytically compensated. We present numerical experiments on phantoms showing the compensation of these deformations in 3D cone beam tomography