Laer-induced Breakdown Spectroscopy Instrument for Element Analysis of Planetary Surfaces

One of the most fundamental pieces of information about any planetary body is the elemental and mineralogical composition of its surface materials. We are developing an instrument to obtain such data at ranges of up to several hundreds of meters using the technique of Laser-Induced Breakdown Spectroscopy (LIBS). We envision our instrument being used from a spacecraft in close rendezvous with small bodies such as comets and asteroids, or deployed on surface-rover vehicles on large bodies such as Mars and the Moon. The elemental analysis is based on atomic emission spectroscopy of a laser-induced plasma or spark. A pulsed, diode pumped Nd:YAG laser of several hundred millijoules optical energy is used to vaporize and electronically excite the constituent elements of a rock surface remotely located from the laser. Light emitted from the excited plasma is collected and introduced to the entrance slit of a small grating spectrometer. The spectrally dispersed spark light is detected with either a linear photo diode array or area CCD array. When the latter detector is used, the optical and spectrometer components of the LIBS instrument can also be used in a passive imaging mode to collect and integrate reflected sunlight from the same rock surface. Absorption spectral analysis of this reflected light gives mineralogical information that provides a remote geochemical characterization of the rock surface. We performed laboratory calibrations in air and in vacuum on standard rock powders to quantify the LIBS analysis. We performed preliminary field tests using commercially available components to demonstrate remote LIBS analysis of terrestrial rock surfaces at ranges of over 25 m, and we have demonstrated compatibility with a six-wheeled Russian robotic rover vehicle. Based on these results, we believe that all major and most minor elements expected on planetary surfaces can be measured with absolute accuracy of 10-15 percent and much higher relative accuracy. We have performed preliminary systems analysis of a LIBS instrument to evaluate probable mass and power requirements; results of this analysis are summarized

Theory of stripe domains in magnetic shape memory alloys

The evolution of multivariant patterns in thin plates of magnetic shape memory materials with an applied magnetic field was studied theoretically. A geometrical domain-model is considered composed of straight stripe-like martensite variants with constant internal magnetization (high anisotropy limit) and magnetic domain wall orientation fixed by the twin boundaries. Through integral transforms of the demagnetization energy, the micromagnetic energy is cast into a form convenient for direct numerical evaluation and analytical calculations. The equilibrium geometrical parameters of multivariant patterns with straight and oblique twin boundaries have been derived as functions of the applied field and the material parameters of a plate. It is shown that the oblique multivariant states exist only in plates with thicknesses L larger than a certain critical value L_0. In samples with L < L_0 a magnetic-field-driven transformation occurs directly between single variant states.Comment: Materials for E-MRS Fall Meeting, Warsaw 2007. Corrected figure