Extractability and mobility of mercury from agricultural soils surrounding industrial and mining contaminated areas

This study focussed on a comparison of the extractability of mercury in soils with two different contamination sources (a chlor-alkali plant and mining activities) and on the evaluation of the influence of specific soil properties on the behaviour of the contaminant. The method applied here did not target the identification of individual species, but instead provided information concerning the mobility of mercury species in soil. Mercury fractions were classified as mobile, semi-mobile and non-mobile. The fractionation study revealed that in all samples mercury was mainly present in the semi-mobile phase (between 63 and 97%). The highest mercury mobility (2.7 mg kg-1) was found in soils from the industrial area. Mining soils exhibited higher percentage of non-mobile mercury, up to 35%, due to their elevated sulfur content. Results of factor analysis indicate that the presence of mercury in the mobile phase could be related to manganese and aluminum soil contents. A positive relation between mercury in the semi-mobile fraction and the aluminium content was also observed. By contrary, organic matter and sulfur contents contributed to mercury retention in the soil matrix reducing the mobility of the metal. Despite known limitations of sequential extraction procedures, the methodology applied in this study for the fractionation of mercury in contaminated soil samples provided relevant information on mercury's relative mobility

On the impact of a tax shock in Portugal

In 1999, Cavaco Silva, the Portuguese Prime Minister from 1985 to 1995, proposed a comprehensive tax reform package, which is to this day the basic reference in the tax policy debate in Portugal. A tax shock would consist of 4pp cuts in the corporate income tax and in the firms’ social security contribution rates, and a 5pp reduction in the highest personal income tax rate. These cuts would be financed by combating tax evasion, curbing wasteful public expenditure and, if necessary, by increasing the VAT rate by up to 2pp. Using a dynamic general equilibrium model to evaluate the effects of this tax shock, we find that the long- term GDP gains would be between 0.72% and 2.91% while the effects on lifetime private welfare would range between –0.99% and 0.9%. The efficiency of this tax reform package depends critically on the way the tax cuts are financed to ensure deficit neutrality. Because investment is subject to adjustment costs, to alleviate the long-run trade-off between GDP and welfare, tax policy changes must induce a significant increase in net labor income.info:eu-repo/semantics/publishedVersio

Consensual sexual nonmonogamy, extradyadic sex, and relationship satisfaction

In sexually monogamous relationships (SMR), sociosexuality, or the predisposition to engage in extradyadic casual sex, is negatively associated with relationship outcomes. However, mutually consenting to sexually non-MR (SNMR) does not hinder relationship outcomes. Recent research has extended these findings to the phenomenon of online extradyadic sexual behavior. The aim of this study was to examine whether this sexual agreement moderates the association between sociosexuality and relationship satisfaction in a sample of romantically involved heterosexuals registered on a dating Web site directed at other romantically involved heterosexuals—Second Love.info:eu-repo/semantics/publishedVersio

'We agree and now everything goes my way': consensual sexual nonmonogamy, extradyadic sex, and relationship satisfaction

In sexually monogamous relationships (SMR), sociosexuality, or the predisposition to engage in extradyadic casual sex, is negatively associated with relationship outcomes. However, mutually consenting to sexually nonMR (SNMR) does not hinder relationship outcomes. Recent research has extended these findings to the phenomenon of online extradyadic sexual behavior. The aim of this study was to examine whether this sexual agreement moderates the association between sociosexuality and relationship satisfaction in a sample of romantically involved heterosexuals registered on a dating Web site directed at other romantically involved heterosexuals-Second Love. A sample of 329 Portuguese heterosexuals (66% men) aged 18-68 (M = 41.47, SD = 10.19) completed a web survey. A bootstrapped moderation analysis showed the expected negative association between sociosexuality and satisfaction, b=-0.18, p = 0.013. However, this was moderated by sexual agreement, b = 1.12, p < 0.001. While individuals in SMR showed the negative association, b(women) =-0.46, p < 0.001, b(men) = -0.67, p < 0.001, for those in SNMR the association between unrestricted sociosexuality and satisfaction was positive, b(women) = 0.63, p = 0.002, b(men) = 0.46, p = 0.006. Gender did not moderate these results. The current study suggests that dating Web sites for romantically involved heterosexuals are not necessarily negative for relationship outcomes as long as there is a consensual agreement for sexual nonmonogamy. This adds to the growing body of literature examining online sexual behavior and sexual infidelity.info:eu-repo/semantics/acceptedVersio

Sociosexuality, commitment, sexual infidelity, and perceptions of infidelity: data from the second love web site

This study explored the association between sociosexuality (behavior, attitudes, and desire) and commitment to understand sexual infidelity in current relationships. We also explored how these variables were associated with attitudes toward infidelity. Participants were romantically involved heterosexuals (N = 252; 51 women, 201 men; Mage = 41.13, SD = 9.82) registered on a dating Web site directed at romantically involved individuals. Results showed that sociosexuality, alongside commitment, was associated with sexual infidelity. Individuals who had (versus had not) previously engaged in infidelity reported more unrestricted sociosexuality, while reporting less commitment. For individuals reporting prior sexual infidelity, unrestricted sociosexual desire and lesser commitment were associated with more permissive perceptions of infidelity. For individuals reporting no prior sexual infidelity, greater commitment was always associated with more strict perceptions of infidelity. No gender differences emerged in the analyses. Also, no differences were found according to individual motivations (i.e., looking to know other people versus seeking casual sex) or relational motivations (i.e., individual registration versus registration as a couple) underlying individuals’ registration on the Web site. These results are an important addition to the literature on infidelity by analyzing a specific sample motivated to engage in infidelity. Implications for future research are discussed.info:eu-repo/semantics/acceptedVersio

Integration of Flight Simulator 2002 with an epidemic multicast protocol

Multi-player games are increasingly popular in the Internet. This growing interest results in the need to support a high number of participants, which raises the issue of scalability, namely in what regards the ability to offer good performance in such a large-scale setting. This paper addresses the issue of designing middleware solutions to support large-scale multi-player applications. In particular, we are interested in studying the feasibility of using epidemic multicast protocols for information dissemination in multi-player games based on a peer-to-peer architecture. We have integrated a comercial multiplayer game, the Microsoft Flight Simulator 2002, with an epidemic multicast protocol appropriate to this kind of applications, the NEEM. The paper describes how this integration was achieved and presents evaluation results of the resulting prototype

IT/IST/IPLeiria Response to the Call for Evidence on JPEG Pleno Point Cloud Coding

This document proposes two scalable point cloud (PC) geometry codecs, submitted to the JPEG Call for Evidence on Point Cloud Coding (PCC).N/

BioRePortAP, an electronic clinical record coupled with a database : an example of its use in a single

Aims: To evaluate the efficacy and safety of the treatment of psoriatic arthritis (PsA) patients with tumor necrosis factor (TNF) antagonists in the Rheumatology Department of Hospital de Santa Maria using the BioRePortAP. Methods: The Portuguese Society of Rheumatology (SPR) developed an electronic medical chart coupled with a database for the follow up of PsA patients, the BioRePortAP, which was launched in May 2009. This evaluation was based on all the PsA patients that were on active treatment with TNF antagonists in September 2009 and were registered in the BioRePortAP. All the previous data on these patients were introduced in BioRePortAP using the prospective paper based follow up protocol that this Department was using since 1999. Only patients with more than 9 months of treatment were analyzed. Results: Forty-two patients with PsA, actively treated with anti-TNF agents in September 2009, for at least 9 months, were analyzed in BioRePortAP. Twenty-three patients were male (55%) and nineteen were female (45%). The average age of these patients was 49.8±10.9 years old, the average disease duration was of 10.7±5.6 years and the mean duration of biological therapy was of 37.8±27.8 months. For the 81% of patients with peripheral joint disease there was a mean reduction of more than 80% in the swollen and tender joint counts, and almost 50% in the health assessment questionnaire (HAQ) value. In the 19% of the patients with axial involvement the reduction of BASDAI and BASFI was not statistically significative. On top of that, PASI score suffered a reduction of 64%. Fourteen patients (33.3%) had to switch their TNF antagonist treatment. 58.8% of the switches were due to adverse effects and 41.2% due to therapy failure. Regarding the 56 adverse reactions registered, only one was a severe reaction. The remaining adverse reactions were not severe and 67% of them were due to infections. Discussion: The results of this first report of the use of the BioRePortAP in clinical practice confirm the efficacy and safety of TNF antagonist treatment in PsA. The results shown here elucidate the potential applications of BioRePortAP as a tool for efficacy and safety assessment of PsA patients treated with biotechnological drugs

Renal Dysfunction Phenotypes in Patients Undergoing Obesity Surgery

Obesity surgery candidates are at an increased risk of kidney injury, but pre-operative evaluation usually neglects kidney function assessment. This study aimed to identify renal dysfunction in candidates for bariatric surgery. To reduce the sources of bias, subjects with diabetes, prediabetes under metformin treatment, neoplastic or inflammatory diseases were excluded. Patients' (n = 192) average body mass index was 41.7 +/- 5.4 kg/m(2). Among these, 51% (n = 94) had creatinine clearance over 140 mL/min, 22.4% (n = 43) had proteinuria over 150 mg/day and 14.6% (n = 28) albuminuria over 30 mg/day. A creatinine clearance higher than 140 mL/min was associated with higher levels of proteinuria and albuminuria. Univariate analysis identified sex, glycated hemoglobin, uric acid, HDL and VLDL cholesterol as being associated with albuminuria, but not with proteinuria. On multivariate analysis, glycated hemoglobin and creatinine clearance as continuous variables were significantly associated with albuminuria. In summary, in our patient population prediabetes, lipid abnormalities and hyperuricemia were associated with albuminuria, but not with proteinuria, suggesting different disease mechanisms might be implicated. Data suggest that in obesity-associated kidney disease, tubulointerstitial injury precedes glomerulopathy. A significant proportion of obesity surgery candidates present clinically relevant albuminuria and proteinuria along with renal hyperfiltration, suggesting that routine pre-operative assessment of these parameters should be considered