16 research outputs found

    Data for: Assessing the efficacy and ecology of biocontrol and biomanipulation for managing invasive pest fish

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    This is the data for the paper 'Assessing the efficacy and ecology of biocontrol and biomanipulation for managing invasive pest fish' in Journal of Applied Ecolog

    Total Synthesis of the Cytotoxic Anhydrophytosphingosine Pachastrissamine (Jaspine B)

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    A short, 8-step synthesis of the marine natural product pachastrissamine has been developed that relies on a diastereoselective aldol reaction between a suitably protected hydantoin and an optically enriched α-chloroaldehyde. This synthetic route provides new opportunities for exploring structure activity relationships within this family of natural products

    A Tandem Organocatalytic α‑Chlorination–Aldol Reaction That Proceeds with Dynamic Kinetic Resolution: A Powerful Tool for Carbohydrate Synthesis

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    A tandem, proline-catalyzed α-chlorination/aldol reaction is described that involves a dynamic kinetic resolution of α-chloroaldehyde intermediates. The resulting <i>syn-</i>chlorohydrins are produced with good to excellent diastereoselectivity in high enantiopurity and provide new opportunities for the synthesis of carbohydrates

    Additional file 2: of Cultivation of stable, reproducible microbial communities from different fecal donors using minibioreactor arrays (MBRAs)

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    Stabilization of MBRA communities. Plot of Average Bray-Curtis (BC) dissimilarities on days 8-21 across replicate reactors

    Total Synthesis of Amphirionin‑4

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    The first total synthesis of amphirionin-4 has been achieved using a combination of cross-coupling strategies to access the polyene side chain and a chlorohydrin-based approach to construct the tetrahydrofuranol core. The remote C9-stereocenter was introduced through a Nozaki–Hiyama–Kishi coupling that proceeded with remote stereoinduction

    A Short, Organocatalytic Formal Synthesis of (−)-Swainsonine and Related Alkaloids

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    A short synthesis of hydroxyalkyl dihydropyrroles has been developed that involves the coupling of propargylamines with α-chloroaldehydes, followed by Lindlar reduction and a one-pot epoxide formation/opening sequence. The application of this process to the synthesis of unnatural iminosugars and a formal synthesis of (−)-swainsonine is described

    The Kondrat’eva Reaction in Flow: Direct Access to Annulated Pyridines

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    A continuous flow <i>inverse-electron-demand</i> Kondrat’eva reaction has been developed that provides direct access to cycloalka[<i>c</i>]pyridines from unactivated oxazoles and cycloalkenes. Annulated pyridines obtained by this one-step process are valuable scaffolds for medicinal chemistry

    Britton et al. Functional Ecology

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    Data for experiment of Britton et al. 2017, 'Trophic consequences of introduced species: comparative impacts of increased inter-specific versus intra-specific competitive interactions
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