Algal Assemblage Distribution as Related to Seasonal Fluctuations of Selected Metal Concentrations

Seasonal variations of phytoplankton assemblages have been observed in a mildly eutrophic lake in northwestern Arkansas for six years. The data indicated that certain metal concentrations also varied seasonally. Sodium, potassium, calcium and magnesium ion concentrations, and phytoplankton composition and abundances were examined spatially and temporally. Four major algal blooms characterized the lake: a spring, a summer and an autumnal cyanophycean assemblage and a winter diatom-chrysophyte dominated population. Each metal concentration was inversely proportional to the abundance of the cyanophytes. The presence of the winter assemblage was accompanied by decreases in sodium, calcium and magnesium and increased levels of potassium. First and second order linear regression models were developed for each assemblage

The Moral Vocabulary of Violence

What is at stake in labeling a particular incidence of large-scale violence “genocide”? Mahmood Mamdani rightly argues that “genocide” is an insufficient description of the conflict in Darfur. I would suggest that the problematic nature of that terminology goes back to its inception after World War II. Activists have inherited the concept of “genocide” from a particular historical moment. Now, “ genocide” carries unique moral weight in the discourse of international politics. When violence against civilians has been widely accepted as a necessary outcome of the preservation of peace, activists find it necessary to imagine a worse evil than the mere fact of indiscriminate killing. The notion of “genocidal intent” fills that role. But the U.N. Commission’s inability to find “genocidal intent” in the killing of civilians in Darfur demonstrates the limits of that very notion. “Genocide” is considered the worst crime against humanity, but too many massacres and incidents of civilian casualties are not included under its rubric

Human Rights and Personal Stories

Negar Azimi’s “Prisoners of Sex” is a welcome reminder that human rights discourse should always keep its subject, “humans,” firmly in view. The stories she tells of death, torture, hope, and survival bear witness to the challenges and dangers faced by gays and lesbians in Egypt

The Trouble with Rights

Do human rights imply enforcement powers? Do they require police or armies? How many soldiers would it take to secure universal human rights? What sort of weaponry would suffice

Fractoluminescence characterization of the energy dissipated during fast fracture of glass

Fractoluminescence experiments are performed on two kinds of silicate glasses. All the light spectra collected during dynamic fracture reveal a black body radiator behaviour, which is interpreted as a crack velocity-dependent temperature rise close to the crack tip. Crack velocities are estimated to be of the order of 1300 m.s$^{-1}$ and fracture process zones are shown to extend over a few nanometers.Comment: Accepted for publication in Europhysics Letters; 5 pages; 4 figure

The influence of chiral surface states on the London penetration depth in Sr2_2RuO4_4

The London penetration depth for the unconventional superconductor Sr$_2$RuO$_4$ is analyzed assuming an order parameter which breaks time reversal symmetry and parity simultaneously. Such a superconducting state possesses chiral quasiparticle states with subgap energies at the surface. We show that these subgap states can give a significant contribution to the low-temperature behavior of the London penetration depth yielding a $T^2$ power-law even though bulk quasiparticle spectrum is gapped. The presence of several electron bands gives rise to interband transition among the subgap surface states and influences the properties of the surface impedance. Furthermore, the surface states lead also to a non-linear Meissner effect.Comment: 4 pages, 1 figure, the definition of the Nambu field operator introduced, and some typos correcte

A Risk Analysis of Carbon Sequestration in Claypan Soil with Conservation Tillage Systems and Nitrogen Fertilizers for Grain Sorghum and Soybean

Replaced with revised version of paper 02/15/06.carbon sequestration, carbon credits, nitrogen, risk, tillage, Crop Production/Industries, Risk and Uncertainty, Q12,

Relationship between the molecular composition, visible light absorption, and health-related properties of smoldering woodsmoke aerosols

Organic aerosols generated from the smoldering combustion of wood critically impact air quality and health for billions of people worldwide; yet, the links between the chemical components and the optical or biological effects of woodsmoke aerosol (WSA) are still poorly understood. In this work, an untargeted analysis of the molecular composition of smoldering WSA, generated in a controlled environment from nine types of heartwood fuels (African mahogany, birch, cherry, maple, pine, poplar, red oak, redwood, and walnut), identified several hundred compounds using gas chromatography mass spectrometry (GCMS) and nano-electrospray high-resolution mass spectrometry (HRMS) with tandem multistage mass spectrometry (MSn). The effects of WSA on cell toxicity as well as gene expression dependent on the aryl hydrocarbon receptor (AhR) and estrogen receptor (ER) were characterized with cellular assays, and the visible mass absorption coefficients (MACvis) of WSA were measured with ultraviolet-visible spectroscopy. The WSAs studied in this work have significant levels of biological and toxicological activity, with exposure levels in both an outdoor and indoor environment similar to or greater than those of other toxicants. A correlation between the HRMS molecular composition and aerosol properties found that phenolic compounds from the oxidative decomposition of lignin are the main drivers of aerosol effects, while the cellulose decomposition products play a secondary role; e.g., levoglucosan is anticorrelated with multiple effects. Polycyclic aromatic hydrocarbons (PAHs) are not expected to form at the combustion temperature in this work, nor were they observed above the detection limit; thus, biological and optical properties of the smoldering WSA are not attributed to PAHs. Syringyl compounds tend to correlate with cell toxicity, while the more conjugated molecules (including several compounds assigned to dimers) have higher AhR activity and MACvis. The negative correlation between cell toxicity and AhR activity suggests that the toxicity of smoldering WSA to cells is not mediated by the AhR. Both mass-normalized biological outcomes have a statistically significant dependence on the degree of combustion of the wood. In addition, our observations support the fact that the visible light absorption of WSA is at least partially due to charge transfer effects in aerosols, as previously suggested. Finally, MACvis has no correlation with toxicity or receptor signaling, suggesting that key chromophores in this work are not biologically active on the endpoints tested