Exact solution of the Percus-Yevick integral equation for fluid mixtures of hard hyperspheres

Structural and thermodynamic properties of multicomponent hard-sphere fluids at odd dimensions have recently been derived in the framework of the rational function approximation (RFA) [Rohrmann and Santos, Phys. Rev. E \textbf{83}, 011201 (2011)]. It is demonstrated here that the RFA technique yields the exact solution of the Percus-Yevick (PY) closure to the Ornstein-Zernike (OZ) equation for binary mixtures at arbitrary odd dimensions. The proof relies mainly on the Fourier transforms $\hat{c}_{ij}(k)$ of the direct correlation functions defined by the OZ relation. From the analysis of the poles of $\hat{c}_{ij}(k)$ we show that the direct correlation functions evaluated by the RFA method vanish outside the hard core, as required by the PY theory.Comment: 6 page

Chemical-potential route for multicomponent fluids

The chemical potentials of multicomponent fluids are derived in terms of the pair correlation functions for arbitrary number of components, interaction potentials, and dimensionality. The formally exact result is particularized to hard-sphere mixtures with zero or positive nonadditivity. As a simple application, the chemical potentials of three-dimensional additive hard-sphere mixtures are derived from the Percus-Yevick theory and the associated equation of state is obtained. This Percus-Yevick chemical-route equation of state is shown to be more accurate than the virial equation of state. An interpolation between the chemical-potential and compressibility routes exhibits a better performance than the well-known Boubl\'ik-Mansoori-Carnahan-Starling-Leland equation of state.Comment: 9 pages, 1 figure; v2: minor change

Equation of state of sticky-hard-sphere fluids in the chemical-potential route

The coupling-parameter method, whereby an extra particle is progressively coupled to the rest of the particles, is applied to the sticky-hard-sphere fluid to obtain its equation of state in the so-called chemical-potential route ($\mu$ route). As a consistency test, the results for one-dimensional sticky particles are shown to be exact. Results corresponding to the three-dimensional case (Baxter's model) are derived within the Percus-Yevick approximation by using different prescriptions for the dependence of the interaction potential of the extra particle on the coupling parameter. The critical point and the coexistence curve of the gas-liquid phase transition are obtained in the $\mu$ route and compared with predictions from other thermodynamics routes and from computer simulations. The results show that the $\mu$ route yields a general better description than the virial, energy, compressibility, and zero-separation routes.Comment: 13 pages, 7 figures; v2: Results from the zero-separation route have been adde

Equation of state for five-dimensional hyperspheres from the chemical-potential route

We use the Percus-Yevick approach in the chemical-potential route to evaluate the equation of state of hard hyperspheres in five dimensions. The evaluation requires the derivation of an analytical expression for the contact value of the pair distribution function between particles of the bulk fluid and a solute particle with arbitrary size. The equation of state is compared with those obtained from the conventional virial and compressibility thermodynamic routes and the associated virial coefficients are computed. The pressure calculated from all routes is exact up to third density order, but it deviates with respect to simulation data as density increases, the compressibility and the chemical-potential routes exhibiting smaller deviations than the virial route. Accurate linear interpolations between the compressibility route and either the chemical-potential route or the virial one are constructed.Comment: 9 pages, 6 figures; v2: Change in one referenc

Rayleigh scattering from hydrogen atoms including resonances and high photon energies

The non-relativistic cross section from Rayleigh scattering by hydrogen atoms in the ground state is calculated over a wide range of photon energies ($< 0.8$ keV). Evaluations are performed in terms of the real and imaginary components of the atomic polarizability. The sum over intermediate states that characterizes this second-order radiative process is performed using exact analytic expressions for oscillator strengths of bound and continuum states. Damping terms associated with the finite lifetimes of excited states and their splitting into two fine-structure levels ($p_{1/2}$ and $p_{3/2}$) are taken into account in resonance cross sections. Fitting formulas required for cross-section evaluation are presented for incident photon energy i) redward of the first resonance (Lyman-$\alpha_{1/2}$), ii) in the spectral region corresponding to resonances (for an arbitrary number of them), and iii) above the ionization threshold.Comment: 8 pages, 7 figures. Accepted for publication in Astronomy & Astrophysic

Multicomponent fluids of hard hyperspheres in odd dimensions

Mixtures of hard hyperspheres in odd space dimensionalities are studied with an analytical approximation method. This technique is based on the so-called Rational Function Approximation and provides a procedure for evaluating equations of state, structure factors, radial distribution functions, and direct correlations functions of additive mixtures of hard hyperspheres with any number of components and in arbitrary odd-dimension space. The method gives the exact solution of the Ornstein--Zernike equation coupled with the Percus--Yevick closure, thus extending to arbitrary odd dimension the solution for hard-sphere mixtures [J. L. Lebowitz, Phys.\ Rev.\ \textbf{133}, 895 (1964)]. Explicit evaluations for binary mixtures in five dimensions are performed. The results are compared with computer simulations and a good agreement is found.Comment: 16 pages, 8 figures; v2: slight change of notatio

Virial series for fluids of hard hyperspheres in odd dimensions

A recently derived method [R. D. Rohrmann and A. Santos, Phys. Rev. E. {\bf 76}, 051202 (2007)] to obtain the exact solution of the Percus-Yevick equation for a fluid of hard spheres in (odd) $d$ dimensions is used to investigate the convergence properties of the resulting virial series. This is done both for the virial and compressibility routes, in which the virial coefficients $B_j$ are expressed in terms of the solution of a set of $(d-1)/2$ coupled algebraic equations which become nonlinear for $d \geq 5$. Results have been derived up to $d=13$. A confirmation of the alternating character of the series for $d\geq 5$, due to the existence of a branch point on the negative real axis, is found and the radius of convergence is explicitly determined for each dimension. The resulting scaled density per dimension $2 \eta^{1/d}$, where $\eta$ is the packing fraction, is wholly consistent with the limiting value of 1 for $d \to \infty$. Finally, the values for $B_j$ predicted by the virial and compressibility routes in the Percus-Yevick approximation are compared with the known exact values [N. Clisby and B. M. McCoy, J. Stat. Phys. {\bf 122}, 15 (2006)]Comment: 9 pages, 6 figure

Structure of hard-hypersphere fluids in odd dimensions

The structural properties of single component fluids of hard hyperspheres in odd space dimensionalities $d$ are studied with an analytical approximation method that generalizes the Rational Function Approximation earlier introduced in the study of hard-sphere fluids [S. B. Yuste and A. Santos, Phys. Rev. A {\bf 43}, 5418 (1991)]. The theory makes use of the exact form of the radial distribution function to first order in density and extends it to finite density by assuming a rational form for a function defined in Laplace space, the coefficients being determined by simple physical requirements. Fourier transform in terms of reverse Bessel polynomials constitute the mathematical framework of this approximation, from which an analytical expression for the static structure factor is obtained. In its most elementary form, the method recovers the solution of the Percus-Yevick closure to the Ornstein-Zernike equation for hyperspheres at odd dimension. The present formalism allows one to go beyond by yielding solutions with thermodynamic consistency between the virial and compressibility routes to any desired equation of state. Excellent agreement with available computer simulation data at $d=5$ and $d=7$ is obtained. As a byproduct of this study, an exact and explicit polynomial expression for the intersection volume of two identical hyperspheres in arbitrary odd dimensions is given.Comment: 18 pages, 7 figures; v2: new references added plus minor changes; to be published in PR

Atmospheric models of He-peculiar stars: synthetic He I line profiles and absolute visual magnitudes

We analyze the influence of magnetic pressure effects on the atmospheric structure of B peculiar type stars, as well as, on the emergent He I line profiles and absolute visual magnitudes. We consider a photosphere in local thermodynamic and hydrostatic equilibrium. The hydrostatic equilibrium equation is modified to include the Lorentz force. Atomic occupational numbers are computed in LTE considering non-ideal effects in the gas equation of state. We depict the influence of a magnetic field on local He I line profiles and discuss the effects of the helium abundance in magnetic B-type stars. The Lorentz force might explain local variations up to 7 % in the equivalent width of helium lines, while local enhancements of He chemical abundances would produce larger changes. To analyze the line variations in real stars we computed the net contribution of a bipolar magnetic field over the stellar disk. The resulting disk-averaged magnetic field predicts variations with the rotation phase up to 2–3 % in the line EWs for a dipolar magnetic field of 1000 G.Facultad de Ciencias Astronómicas y GeofísicasInstituto de Astrofísica de La Plat