28 research outputs found
The Degree of Charge Transfer in Ground and Charge-Separated States Revealed by Ultrafast Visible Pump/Mid-IR Probe Spectroscopy
Acentric 2-D Ensembles of D-br-A Electron-Transfer Chromophores via Vectorial Orientation within Amphiphilic n
What Kind of Self-Awareness Follows Growth: Facets of Reflection at Different Levels of Ego Development
State-Selective Electron Transfer in an Unsymmetric AcceptorâZn(II)porphyrinâAcceptor Triad: Toward a Controlled Directionality of Electron Transfer from the Porphyrin S 2
Amphiphilic Four-Helix Bundle Peptides Designed for Light-Induced Electron Transfer Across a Soft Interface
Diametric Stereocontrol in Dynamic Catalytic Reduction of Racemic Acyl Phosphonates: Divergence from α-Keto Ester Congeners
An unexpected dichotomy was observed in the Ru-catalyzed asymmetric transfer hydrogenation of acyl phosphonates: reduction proceeded from the opposite face relative to that observed in the analogous reduction of α-keto esters. The first highly selective catalytic hydrogenation of acyl phosphonates was utilized in the dynamic kinetic resolution of α-aryl acyl phosphonates providing ÎČ-stereogenic α-hydroxy phosphonic acid derivatives