592 research outputs found

    Development of a creep data base management system for engineering materials

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    A fully menu driven creep data base management system has been developed for various high temperature materials using the client /server (C/S) architecture with Sybase system. 10 as backend and power builder 4.0 as an inter-face. The relational data base constitutes of various classes of materials, their heat treatment, prior history and the related creep properties at different test condit-ions, in addition to the source process route and chemical composition details.Top-down approach has been adopted in designing the entity-relationship (E-R) model. The creep data is organized into the third normal form, and the entire system is divided into manageable modules. Coding for the system is done using Transact-SQL for data defin- ition, manipulation and control operations, and power script language for application development. This article briefly outlines the formulation of data base design, and the implemented E-R model, in addition , to the prese-ntation of various screen formats used for data entry and retrieval modules

    Selective IR laser chemistry of CDF<SUB>3</SUB> in natural fluoroform

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    Selective decomposition of CDF3 at natural abundance level (&#8776;150ppm) in fluoroform has been achieved by infra-red multiple-photon excitation at moderate substrate pressure using 100 ns FWHM CO2 laser pulses. Effects of energy fluence, number of laser pulses, buffer gas pressure and substrate pressure on decomposition yield and bulk selectivity are reported and discussed

    Carbon-13 enrichment by IR laser chemistry of CHF<SUB>3</SUB>-Cl<SUB>2</SUB>

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    IR laser chemistry of CHF3 is investigated in both neat form and in the presence of Cl2 for carbon-13 enrichment. Infrared multiple-photon dissociation of CHF3 is an order of magnitude more efficient in the scavenged system compared to the neat case. The photolysis of CHF3/Cl2 mixture results in two products, viz., CF2Cl2 and C2F4Cl2 but with different enrichment factors. The parametric studies show that C2F4Cl2 arises due to MPD of CF2Cl2 in secondary photolysis

    Transient isomerisation and inverse electronic relaxation of infrared multiple-photon excited Pentafluoropyridine

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    Pentafluoropyridine (PFP) undergoes fast structural isomerisation to fulvenes when irradiated with 9R(16) CO2 laser line in the fluence range 0.5-1.5 J/cm2. The unstable fulvenes slowly decay back to PFP in ms time scale. No detectable permanent dissociation of PFP was observed in the above low fluence experiments. However, by using focused CO2 laser beam for the irradiation of PFP, an emission of light in the visible/near-UV was observed. The time evolution of the luminescence reveals three peaks at 390, 460 and 500 nm on a broad background emission of 300-680 nm. These bands are assigned to the fluorescence of PFP via inverse electronic relaxation (IER) and C2 Swan bands. On prolonged irradiation of PFP in focused condition a small extent of permanent dissociation was observed with the major products as C2F4, a sooty yellow deposit and another compound presumed to be Dewar PFP

    Laser isotope separation of <SUP>13</SUP>C: a comparative study

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    IR laser chemistry of (CF3Br/Cl2) mixture and neat CF2HCl are examined in the context of 13C enrichment. Decomposition extent, enrichment factor and energy absorbed are measured for both systems at their respective optimum conditions. A direct comparison is obtained by keeping extraneous factors such as laser, its pulse duration, cell, irradiation geometry etc. the same. The halogen scavenged CF3Br MPD requires lower fluence compared to neat CF2HCl irradiation. Overall throughput for a product with 60-65% 13C content in a single stage is the same for both systems requiring a similar amount of energy. However, at lower enrichment levels, CF2HCl MPD is better than (CF3Br/Cl2) photolysis in terms of both product yield and energy absorption

    Seaweed resources of the Tuticorin-Tiruchendur coast, Tamil Nadu, India

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    The southern coast of Tamil Nadu (Mandapam to Kanyakumari) supports luxuriant growth of economic seaweeds. The entire indigenous phycocoUoid industry of the country gets the raw material from this region and during the last two decades, due to indiscriminate harvesting, there has been over-exploitation of the resource. The present paper deals with survey conducted in the first sector from Tuticorin to Tiruchendur during December 1986—March 1987. In this study 58 species of marine algae were recorded of which 7 belong to Chlorophyta, 12 to Phaeophyta and 39 to Rhodophyta besides 3 species of seagrasses namely Cymodocea seiriilata, Halophila ovalis and //. ovata within 650 sq. km area surveyed. The total standing crop of the seaweeds was estimated at 9,100 tonnes (wt.). The estimates for the dominant species are Dictyota maxima 530 t, Sargassum tenerrium 640 t, D. bartayresiana 8601, Selieria rebusta 2,0901 and Hypnea valemiae 2,4301. The seaweed potential for commercial exploitation has been briefly discussed

    Temporal and spatial variations in TEC using simultaneous measurements from the Indian GPS network of receivers during the low solar activity period of 2004?2005

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    International audienceWith the recent increase in the satellite-based navigation applications, the ionospheric total electron content (TEC) and the L-band scintillation measurements have gained significant importance. In this paper we present the temporal and spatial variations in TEC derived from the simultaneous and continuous measurements made, for the first time, using the Indian GPS network of 18 receivers located from the equator to the northern crest of the equatorial ionization anomaly (EIA) region and beyond, covering a geomagnetic latitude range of 1° S to 24° N, using a 16-month period of data for the low sunspot activity (LSSA) years of March 2004 to June 2005. The diurnal variation in TEC at the EIA region shows its steep increase and reaches its maximum value between 13:00 and 16:00 LT, while at the equator the peak is broad and occurs around 16:00 LT. A short-lived day minimum occurs between 05:00 to 06:00 LT at all the stations from the equator to the EIA crest region. Beyond the crest region the day maximum values decrease with the increase in latitude, while the day minimum in TEC is flat during most of the nighttime hours, i.e. from 22:00 to 06:00 LT, a feature similar to that observed in the mid-latitudes. Further, the diurnal variation in TEC show a minimum to maximum variation of about 5 to 50 TEC units, respectively, at the equator and about 5 to 90 TEC units at the EIA crest region, which correspond to range delay variations of about 1 to 8 m at the equator to about 1 to 15 m at the crest region, at the GPS L1 frequency of 1.575 GHz. The day-to-day variability is also significant at all the stations, particularly during the daytime hours, with maximum variations at the EIA crest regions. Further, similar variations are also noticed in the corresponding equatorial electrojet (EEJ) strength, which is known to be one of the major contributors for the observed day-to-day variability in TEC. The seasonal variation in TEC maximizes during the equinox months followed by winter and is minimum during the summer months, a feature similar to that observed in the integrated equatorial electrojet (IEEJ) strength for the corresponding seasons. In the Indian sector, the EIA crest is found to occur in the latitude zone of 15° to 25° N geographic latitudes (5° to 15° N geomagnetic latitudes). The EIA also maximizes during equinoxes followed by winter and is not significant in the summer months in the LSSA period, 2004?2005. These studies also reveal that both the location of the EIA crest and its peak value in TEC are linearly related to the IEEJ strength and increase with the increase in IEEJ

    Characteristics of VHF radiowave scintillations over a solar cycle (1983?1993) at a low-latitude station: Waltair (17.7°N, 83.3°E)

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    International audienceThe characteristics of VHF radiowave scintillations at 244 MHz (FLEETSAT) during a complete solar cycle (1983?93) at a low-latitude station, Waltair (17.7°N, 83.3°E), are presented. The occurrence of night-time scintillations shows equinoctial maxima and summer minima in all the epochs of solar activity, and follows the solar activity. The daytime scintillation occurrence is negatively correlated with the solar activity and shows maximum occurrence during the summer months in a period of low solar activity. The occurrence of night-time scintillations is inhibited during disturbed days of high solar activity and enhanced during low solar activity

    Distribution of sea weeds off Kattapadu - Tiruchendur coast, Tamil nadu

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    The present paper deals with the distribution of seaweeds and seagrasses during the deep sea survey conducted in the first sector from Kattapadu to Tiruchendur in Tamil Nadu coast between December 1986 and March 1987 covering an area of 650 sq.km. In thiS survey. 58 species of marine algae \\ere recorded. of which 7 belong to Chlorophyta. 12 to Phaeophyta and 39 to Rhodophyta. Three species of seagrasses vi z. Cymodocea serrl/lata. Halophila ovails and H. ovala were also recorded at the depths ranging from 5.5 to 21.5 III Halim eda macroloba, D,ClyOIO barlayresiana, D. Maxima, Gracliaria corl/cala var. corlicala, G. edulis, Sarcodia indica, Sarconema filiform e, Soliena rob"sla, flypnea esperi and H. "alenliae were found to be dominant and widely distributed. Hydrological data were also collected from area surveyed. The atmospheric and bottom water temperature varied from 25.0 to 36.8'C and 26.0 to 31.8'C respectively. The pH ranged from 8.3 to 8.6 and the salinity from 26.39 to 33.430/00 . The dissolved oxygen ranged from 3A2 to 6.47 mill. The phosphate content varied from 0.05 to 0. 15 I'g atm/ l, silicate from 4.00 to 12.00 I'g atmll, nitrate from 0.25 to 1.00 I'g at mil and nitrite from 1.05 to 3.99 I'g atml l
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