7,637 research outputs found
Noise and thermal stability of vibrating micro-gyrometers preamplifiers
The preamplifier is a critical component of gyrometer's electronics. Indeed
the resolution of the sensor is limited by its signal to noise ratio, and the
gyrometer's thermal stability is limited by its gain drift. In this paper, five
different kinds of preamplifiers are presented and compared. Finally, the
design of an integrated preamplifier is shown in order to increase the gain
stability while reducing its noise and size.Comment: Submitted on behalf of EDA Publishing Association
(http://irevues.inist.fr/EDA-Publishing
An accurate equation of state for the one component plasma in the low coupling regime
An accurate equation of state of the one component plasma is obtained in the
low coupling regime . The accuracy results from a smooth
combination of the well-known hypernetted chain integral equation, Monte Carlo
simulations and asymptotic analytical expressions of the excess internal energy
. In particular, special attention has been brought to describe and take
advantage of finite size effects on Monte Carlo results to get the
thermodynamic limit of . This combined approach reproduces very accurately
the different plasma correlation regimes encountered in this range of values of
. This paper extends to low 's an earlier Monte Carlo
simulation study devoted to strongly coupled systems for ({J.-M. Caillol}, {J. Chem. Phys.} \textbf{111}, 6538 (1999)). Analytical
fits of in the range are provided with a
precision that we claim to be not smaller than . HNC equation and
exact asymptotic expressions are shown to give reliable results for
only in narrow intervals, i.e. and respectively
Production of human recombinant proapolipoprotein A-I in Escherichia coli: purification and biochemical characterization
A human liver cDNA library was used to isolate a clone coding for apolipoprotein A-I (Apo A-I). The clone
carries the sequence for the prepeptide (18 amino acids), the propeptide (6 amino acids), and the mature protein
(243 amino acids). A coding cassette for the proapo A-I molecule was reconstructed by fusing synthetic
sequences, chosen to optimize expression and specifying the amino-terminal methionine and amino acids -6
to +14, to a large fragment of the cDNA coding for amino acids 15-243. The module was expressed in
pOTS-Nco, an Escherichia coli expression vector carrying the regulatable X P^ promoter, leading to the production
of proapolipoprotein A-I at up to 10% of total soluble proteins. The recombinant polypeptide was
purified and characterized in terms of apparent molecular mass, isoelectric point, and by both chemical and
enzymatic peptide mapping. In addition, it was assayed in vitro for the stimulation of the enzyme lecithin:
cholesterol acyltransferase. The data show for the first time that proapo A-I can be produced efficiently in
E. coli as a stable and undegraded protein having physical and functional properties indistinguishable from
those of the natural product
Quantum free energy differences from non-equilibrium path integrals: I. Methods and numerical application
The imaginary-time path integral representation of the canonical partition
function of a quantum system and non-equilibrium work fluctuation relations are
combined to yield methods for computing free energy differences in quantum
systems using non-equilibrium processes. The path integral representation is
isomorphic to the configurational partition function of a classical field
theory, to which a natural but fictitious Hamiltonian dynamics is associated.
It is shown that if this system is prepared in an equilibrium state, after
which a control parameter in the fictitious Hamiltonian is changed in a finite
time, then formally the Jarzynski non-equilibrium work relation and the Crooks
fluctuation relation are shown to hold, where work is defined as the change in
the energy as given by the fictitious Hamiltonian. Since the energy diverges
for the classical field theory in canonical equilibrium, two regularization
methods are introduced which limit the number of degrees of freedom to be
finite. The numerical applicability of the methods is demonstrated for a
quartic double-well potential with varying asymmetry. A general parameter-free
smoothing procedure for the work distribution functions is useful in this
context.Comment: 20 pages, 4 figures. Added clarifying remarks and fixed typo
Geometrical Frustration and Static Correlations in Hard-Sphere Glass Formers
We analytically and numerically characterize the structure of hard-sphere
fluids in order to review various geometrical frustration scenarios of the
glass transition. We find generalized polytetrahedral order to be correlated
with increasing fluid packing fraction, but to become increasingly irrelevant
with increasing dimension. We also find the growth in structural correlations
to be modest in the dynamical regime accessible to computer simulations.Comment: 21 pages; part of the "Special Topic Issue on the Glass Transition
Modification of Charge Trapping at Particle/Particle Interfaces by Electrochemical Hydrogen Doping of Nanocrystalline TiO2
Particle/particle interfaces play a crucial role in the functionality and performance of nanocrystalline materials such as mesoporous metal oxide electrodes. Defects at these interfaces are known to impede charge separation via slow-down of transport and increase of charge recombination, but can be passivated via electrochemical doping (i.e., incorporation of electron/proton pairs), leading to transient but large enhancement of photoelectrode performance. Although this process is technologically very relevant, it is still poorly understood. Here we report on the electrochemical characterization and the theoretical modeling of electron traps in nanocrystalline rutile TiO2 films. Significant changes in the electrochemical response of porous films consisting of a random network of TiO2 particles are observed upon the electrochemical accumulation of electron/proton pairs. The reversible shift of a capacitive peak in the voltammetric profile of the electrode is assigned to an energetic modification of trap states at particle/particle interfaces. This hypothesis is supported by first-principles theoretical calculations on a TiO2 grain boundary, providing a simple model for particle/particle interfaces. In particular, it is shown how protons readily segregate to the grain boundary (being up to 0.6 eV more stable than in the TiO2 bulk), modifying its structure and electron-trapping properties. The presence of hydrogen at the grain boundary increases the average depth of traps while at the same time reducing their number compared to the undoped situation. This provides an explanation for the transient enhancement of the photoelectrocatalytic activity toward methanol photooxidation which is observed following electrochemical hydrogen doping of rutile TiO2 nanoparticle electrodes
Dynamic response of railway tracks in tunnel
International audiencePeriodically supported beams subjected to a moving load are often used for modelling the railway dynamics and analytical solutions have been developed for such modelling [3, 4]. More complex models can be constructed by including supports with damping or non-linear stiffness elements. This study deals with the dynamical modelling of non-ballasted railways, especially railways in tunnels. The model is developed as a dynamical system of multi-degree of freedom. Under the periodic assumption on the reaction force of the supports, the equation of motion for a periodically supported beam subjected to a moving load has been written. Then the Fourier transform has been used to solve this equation in case of damped supports. Analytical solutions have been established for the motion of the wheel and rail and also for the reaction force of the supports. The analytical solutions have been compared with in situ experimental measurements. The comparison shows that the theoretical results agree well with the measured results if damped supports are included in the model
Vector theories in cosmology
This article provides a general study of the Hamiltonian stability and the
hyperbolicity of vector field models involving both a general function of the
Faraday tensor and its dual, , as well as a Proca potential
for the vector field, . In particular it is demonstrated that theories
involving only do not satisfy the hyperbolicity conditions. It is then
shown that in this class of models, the cosmological dynamics always dilutes
the vector field. In the case of a nonminimal coupling to gravity, it is
established that theories involving or are generically
pathologic. To finish, we exhibit a model where the vector field is not diluted
during the cosmological evolution, because of a nonminimal vector
field-curvature coupling which maintains second-order field equations. The
relevance of such models for cosmology is discussed.Comment: 17 pages, no figur
First principles modelling of magnesium titanium hydrides
Mixing Mg with Ti leads to a hydride Mg(x)Ti(1-x)H2 with markedly improved
(de)hydrogenation properties for x < 0.8, as compared to MgH2. Optically, thin
films of Mg(x)Ti(1-x)H2 have a black appearance, which is remarkable for a
hydride material. In this paper we study the structure and stability of
Mg(x)Ti(1-x)H2, x= 0-1 by first-principles calculations at the level of density
functional theory. We give evidence for a fluorite to rutile phase transition
at a critical composition x(c)= 0.8-0.9, which correlates with the
experimentally observed sharp decrease in (de)hydrogenation rates at this
composition. The densities of states of Mg(x)Ti(1-x)H2 have a peak at the Fermi
level, composed of Ti d states. Disorder in the positions of the Ti atoms
easily destroys the metallic plasma, however, which suppresses the optical
reflection. Interband transitions result in a featureless optical absorption
over a large energy range, causing the black appearance of Mg(x)Ti(1-x)H2.Comment: 22 pages, 9 figures, 4 table
Spin-Valve Effect of the Spin Accumulation Resistance in a Double Ferromagnet - Superconductor Junction
We have measured the transport properties of Ferromagnet - Superconductor
nanostructures, where two superconducting aluminum (Al) electrodes are
connected through two ferromagnetic iron (Fe) ellipsoids in parallel. We find
that, below the superconducting critical temperature of Al, the resistance
depends on the relative alignment of the ferromagnets' magnetization. This
spin-valve effect is analyzed in terms of spin accumulation in the
superconducting electrode submitted to inverse proximity effect
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