Laboratory studies of photodissociation processes relevant to the formation of cometary radicals

The strength of the C2(d 3 Pi g yields a 3 Pi u) Swan band emission in the spectra of cometary comae identifies this species as a prominent constituent of the coma gas. It was previously suggested that the formation of cometary C2 proceeds via the secondary photolysis of the C2H radical. The detection of C2H in the interstellar medium and the recent analysis of the radial variation in C2(delta V=O) surface brightness of Comet Halley support the postulate that C2 is a third-generation molecule. Measurement of the C2 and C2H translational energy distributions produced from the multiphoton dissociation (MPD) of acetylene at 193 nm are identified . Time-resolved FTIR emission studies of the nascent C2H radical formed in the C2H2 yields C2H + H reaction verify that this species is produced both vibrationally and electronically excited. A survey of the internal energy distributions of the C2 fragments produced from the MPD of acetylene using a high intensity ArF laser is currently in progress in the laboratory. Recent experiments have focused on the measurement of rotational energy distribution for the C2(A 1 Pi u, a 3 Pi u) fragments. The C2(a 3 Pi u) detection capability is currently being improved by performing this experiment in a molecular beam, thus allowing for discrimination between initial emission and laser-induced fluorescence (LIF). Although the experiments performed to date provide considerable evidence in support of C2H yields C2 + H reaction, there is an important distinction to be made when comparing the laboratory conditions to those typically found in comets. The C2H radicals generated in the laboratory experiments are formed vibrationally and/or electronically excited. Any rotationally/vibrationally excited C2H present in cometary comae will quickly undergo radiative relaxation in the infrared to their lowest rotational and vibrational state. Experiments are currently under way to confirm the cometary formation of C2 via the VUV dissociation of cold C2H

Breathing oscillations of a trapped impurity in a Bose gas

Motivated by a recent experiment [J. Catani et al., arXiv:1106.0828v1 preprint, 2011], we study breathing oscillations in the width of a harmonically trapped impurity interacting with a separately trapped Bose gas. We provide an intuitive physical picture of such dynamics at zero temperature, using a time-dependent variational approach. In the Gross-Pitaevskii regime we obtain breathing oscillations whose amplitudes are suppressed by self trapping, due to interactions with the Bose gas. Introducing phonons in the Bose gas leads to the damping of breathing oscillations and non-Markovian dynamics of the width of the impurity, the degree of which can be engineered through controllable parameters. Our results reproduce the main features of the impurity dynamics observed by Catani et al. despite experimental thermal effects, and are supported by simulations of the system in the Gross-Pitaevskii regime. Moreover, we predict novel effects at lower temperatures due to self-trapping and the inhomogeneity of the trapped Bose gas.Comment: 7 pages, 3 figure

Bell Inequalities Classifying Bi-separable Three-qubit States

We present a set of Bell inequalities that gives rise to a finer classification of the entanglement for tripartite systems. These inequalities distinguish three possible bi-separable entanglements for three-qubit states. The three Bell operators we employed constitute an external sphere of the separable cube.Comment: 8 page

Low-lying S-wave and P-wave Dibaryons in a Nodal Structure Analysis

The dibaryon states as six-quark clusters of exotic QCD states are investigated in this paper. With the inherent nodal surface structure analysis, the wave functions of the six-quark clusters (in another word, the dibaryons) are classified. The contribution of the hidden color channels are discussed. The quantum numbers of the low-lying dibaryon states are obtained. The States $[\Omega\Omega]_{(0,0^{+})}$, $[\Omega\Omega]_{(0,2^{-})}$, $[\Xi^{*}\Omega]_{(1/2,0^{+})}$, $[\Sigma^{*}\Sigma^{*}]_{(0,4^{-})}$ and the hidden color channel states with the same quantum numbers are proposed to be the candidates of dibaryons, which may be observed in experiments.Comment: 29 pages, 2 figure

Improvements in prevalence trend fitting and incidence estimation in EPP 2013

OBJECTIVE: Describe modifications to the latest version of the Joint United Nations Programme on AIDS (UNAIDS) Estimation and Projection Package component of Spectrum (EPP 2013) to improve prevalence fitting and incidence trend estimation in national epidemics and global estimates of HIV burden. METHODS: Key changes made under the guidance of the UNAIDS Reference Group on Estimates, Modelling and Projections include: availability of a range of incidence calculation models and guidance for selecting a model; a shift to reporting the Bayesian median instead of the maximum likelihood estimate; procedures for comparison and validation against reported HIV and AIDS data; incorporation of national surveys as an integral part of the fitting and calibration procedure, allowing survey trends to inform the fit; improved antenatal clinic calibration procedures in countries without surveys; adjustment of national antiretroviral therapy reports used in the fitting to include only those aged 15–49 years; better estimates of mortality among people who inject drugs; and enhancements to speed fitting. RESULTS: The revised models in EPP 2013 allow closer fits to observed prevalence trend data and reflect improving understanding of HIV epidemics and associated data. CONCLUSION: Spectrum and EPP continue to adapt to make better use of the existing data sources, incorporate new sources of information in their fitting and validation procedures, and correct for quantifiable biases in inputs as they are identified and understood. These adaptations provide countries with better calibrated estimates of incidence and prevalence, which increase epidemic understanding and provide a solid base for program and policy planning

Automorphic Instanton Partition Functions on Calabi-Yau Threefolds

We survey recent results on quantum corrections to the hypermultiplet moduli space M in type IIA/B string theory on a compact Calabi-Yau threefold X, or, equivalently, the vector multiplet moduli space in type IIB/A on X x S^1. Our main focus lies on the problem of resumming the infinite series of D-brane and NS5-brane instantons, using the mathematical machinery of automorphic forms. We review the proposal that whenever the low-energy theory in D=3 exhibits an arithmetic "U-duality" symmetry G(Z) the total instanton partition function arises from a certain unitary automorphic representation of G, whose Fourier coefficients reproduce the BPS-degeneracies. For D=4, N=2 theories on R^3 x S^1 we argue that the relevant automorphic representation falls in the quaternionic discrete series of G, and that the partition function can be realized as a holomorphic section on the twistor space Z over M. We also offer some comments on the close relation with N=2 wall crossing formulae.Comment: 25 pages, contribution to the proceedings of the workshop "Algebra, Geometry and Mathematical Physics", Tjarno, Sweden, 25-30 October, 201

Rapid, efficient, and economical synthesis of PET tracers in a droplet microreactor: application to O-(2-[18F]fluoroethyl)-L-tyrosine ([18F]FET).

BackgroundConventional scale production of small batches of PET tracers (e.g. for preclinical imaging) is an inefficient use of resources. Using O-(2-[18F]fluoroethyl)-L-tyrosine ([18F]FET), we demonstrate that simple microvolume radiosynthesis techniques can improve the efficiency of production by consuming tiny amounts of precursor, and maintaining high molar activity of the tracers even with low starting activity.ProceduresThe synthesis was carried out in microvolume droplets manipulated on a disposable patterned silicon "chip" affixed to a heater. A droplet of [18F]fluoride containing TBAHCO3 was first deposited onto a chip and dried at 100 °C. Subsequently, a droplet containing 60 nmol of precursor was added to the chip and the fluorination reaction was performed at 90 °C for 5 min. Removal of protecting groups was accomplished with a droplet of HCl heated at 90 °C for 3 min. Finally, the crude product was collected in a methanol-water mixture, purified via analytical-scale radio-HPLC and formulated in saline. As a demonstration, using [18F]FET produced on the chip, we prepared aliquots with different molar activities to explore the impact on preclinical PET imaging of tumor-bearing mice.ResultsThe microdroplet synthesis exhibited an overall decay-corrected radiochemical yield of 55 ± 7% (n = 4) after purification and formulation. When automated, the synthesis could be completed in 35 min. Starting with < 370 MBq of activity, ~ 150 MBq of [18F]FET could be produced, sufficient for multiple in vivo experiments, with high molar activities (48-119 GBq/μmol). The demonstration imaging study revealed the uptake of [18F]FET in subcutaneous tumors, but no significant differences in tumor uptake as a result of molar activity differences (ranging 0.37-48 GBq/μmol) were observed.ConclusionsA microdroplet synthesis of [18F]FET was developed demonstrating low reagent consumption, high yield, and high molar activity. The approach can be expanded to tracers other than [18F]FET, and adapted to produce higher quantities of the tracer sufficient for clinical PET imaging

Provision of secondary frequency regulation by coordinated dispatch of industrial loads and thermal power plants

Demand responsive industrial loads with high thermal inertia have potential to provide ancillary service for frequency regulation in the power market. To capture the benefit, this study proposes a new hierarchical framework to coordinate the demand responsive industrial loads with thermal power plants in an industrial park for secondary frequency control. In the proposed framework, demand responsive loads and generating resources are coordinated for optimal dispatch in two-time scales: (1) the regulation reserve of the industrial park is optimally scheduled in a day-ahead manner. The stochastic regulation signal is replaced by the specific extremely trajectories. Furthermore, the extremely trajectories are achieved by the day-ahead predicted regulation mileage. The resulting benefit is to transform the stochastic reserve scheduling problem into a deterministic optimization; (2) a model predictive control strategy is proposed to dispatch the industry park in real time with an objective to maximize the revenue. The proposed technology is tested using a real-world industrial electrolysis power system based upon Pennsylvania, Jersey, and Maryland (PJM) power market. Various scenarios are simulated to study the performance of the proposed approach to enable industry parks to provide ancillary service into the power market. The simulation results indicate that an industrial park with a capacity of 500 MW can provide up to 40 MW ancillary service for participation in the secondary frequency regulation. The proposed strategy is demonstrated to be capable of maintaining the economic and secure operation of the industrial park while satisfying performance requirements from the real world regulation market

Three Dimensional Simulation of Jet Formation in Collapsing Condensates

We numerically study the behavior of collapsing and exploding condensates using the parameters of the experiments by E.A. Donley et al. [Nature, 412, 295, (2001)]. Our studies are based on a full three-dimensional numerical solution of the Gross-Pitaevskii equation (GPE) including three body loss. We determine the three body loss rate from the number of remnant condensate atoms and collapse times and obtain only one possible value which fits with the experimental results. We then study the formation of jet atoms by interrupting the collapse and find very good agreement with the experiment. Furthermore we investigate the sensitivity of the jets to the initial conditions. According to our analysis the dynamics of the burst atoms is not described by the GPE with three body loss incorporated.Comment: 9 pages, 10 figure