4 research outputs found
Production of Xylanase from Arthrobacter sp. MTCC 6915 Using Saw Dust As Substrate under Solid State Fermentation
Saw dust was used as substrate for xylanase production from Arthrobacter sp. MTCC 6915. The study of period of incubation, temperature, pH, carbon, and nitrogen sources for xylanase production was optimized. Xylanase production was found to be optimum at an incubation period of 96 hrs (117.0 U/mL), temperature 30°C (105.0 U/mL), and pH 9.0 (102.9 U/mL). The results showed that the xylanase production was found to be higher in the presence of carboxymethylcellulose (176.4 U/mL) and dextrose (126.0 U/mL). It was also observed that peptone (170.1 U/mL) and beef extract (161.7 U/mL) supported maximum xylanase production.The enzyme was characterized and found to be fairly active at pH 9 (764.4 U/mL) and temperature 60°C (819 U/mL). Even in the present study, a major difference in the production temperature (30°C) and optimal temperature (60°C) of the enzyme activity was observed. However, the pH of the production media and the enzyme activity were found to be the same (pH 9)
Fabrication of Nano-Ag Encapsulated on ZnO/Fe<sub>2</sub>V<sub>4</sub>O<sub>13</sub> Hybrid-Heterojunction for Photodecomposition of Methyl Orange
Novel silver encapsulated nanocomposite zinc oxide/iron tetra-poly-vanadate (Ag-ZnO/Fe2V4O13) was synthesized with various wt% of silver (1.0–2.5 wt% of Ag) by cost-effective photo-deposition method under the irradiation of ultraviolet-A (UV-A) light. The nanostructure of the Ag-ZnO/Fe2V4O13 was explored by various characterization techniques. The surface functionalities were confirmed by Fourier transform infrared spectra and the crystalline nature of the material was revealed by X-ray diffraction patterns. Furthermore, the surface morphology and the optical properties of the composites were analyzed by scanning electron microscopy, energy dispersive X-ray–elemental color mapping (ECM), high-resolution transmission electron microscopy (HRTEM), ultraviolet–visible diffuse reflectance spectroscopy and photoluminescence. The crystallite size of Ag-ZnO/Fe2V4O13 was 28.5 nm which was consistent with HRTEM analysis. The photocatalytic activity was tested against aqueous methyl orange degradation under UV-A light irradiation. In all five runs, the stability of the catalyst was confirmed by reusability measurements and almost 98% of degradation was achieved. A suitable degradation pathway was proposed based on intermediates obtained during the degradation analyzed by gas chromatography–mass spectrometry. Trapping experiments confirmed that the superoxide radical anion (O2•−) was considered as the most active species for this degradation process. Complete mineralization was confirmed by the measurements of chemical oxygen demand
Highly Efficient Solar-Light-Active Ag-Decorated g-C3N4 Composite Photocatalysts for the Degradation of Methyl Orange Dye
Licensee MDPI, Basel, Switzerland.
This article is an open access article
distributed under the terms and
conditions of the Creative Commons
Attribution (CC BY) license (https://
creativecommons.org/licenses/by/
4.0/).In this study, we utilized calcination and simple impregnation methods to successfully
fabricate bare g-C3N4
(GCN) and x% Ag/g-C3N4
(x% AgGCN) composite photocatalysts with various
weight percentages (x = 1, 3, 5, and 7 wt.%). The synthesized bare and composite photocatalysts were
analyzed to illustrate their phase formation, functional group, morphology, and optical properties
utilizing XRD, FT-IR, UV-Vis DRS, PL, FE-SEM, and the EDS. The photodegradation rate of MO
under solar light irradiation was measured, and the 5% AgGCN composite photocatalyst showed
higher photocatalytic activity (99%), which is very high compared to other bare and composite
photocatalysts. The MO dye degradation rate constant with the 5% AgGCN photocatalyst exhibits
14.83 times better photocatalytic activity compared to the bare GCN catalyst. This photocatalyst
showed good efficiency in the degradation of MO dye and demonstrated cycling stability even in the
5th successive photocatalytic reaction cycle. The higher photocatalytic activity of the 5% AgGCN
composite catalyst for the degradation of MO dye is due to the interaction of Ag with GCN and the
localized surface plasmon resonance (SPR) effect of Ag. The scavenger study results indicate that
O2
•− radicals play a major role in MO dye degradation. A possible charge-transfer mechanism is
proposed to explain the solar-light-driven photocatalyst of GCN