1,019 research outputs found

    Maxillary fungus ball: zinc-oxide endodontic materials as a risk factor

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    open7openNICOLAI, Piero; MENSI, Magda; Marsili, F.; Piccioni, M.; SALGARELLO, Stefano Alessandro; GILBERTI, Maria Enrica; Apostoli, P.Nicolai, Piero; Mensi, Magda; Marsili, F.; Piccioni, M.; Salgarello, Stefano Alessandro; Gilberti, Maria Enrica; Apostoli, P

    Distribution of Relaxation Times Based on Lasso Regression: A Tool for High-Resolution Analysis of IMPS Data in Photoelectrochemical Systems

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    Intensity-modulated photocurrent spectroscopy (IMPS) has been largely employed in semiconductor characterization for solar energy conversion devices to probe the operando behavior with widely available facilities. However, the implementation of IMPS data analysis to complex structures, whether based on the physical rate constant model (RCM) or the assumption-free distribution of relaxation times (DRT), is generally limited to a semi-quantitative description of the charge carrier kinetics of the system. In this study, a new algorithm for the analysis of IMPS data is developed, providing unprecedented time resolution to the investigation of μs to s charge carrier dynamics in semiconductor-based systems used in photoelectrochemistry and photovoltaics. The algorithm, based on the previously developed DRT analysis, is herein modified with a Lasso regression method and available to the reader free of charge. A validation of this new algorithm is performed on a α-Fe2O3 photoanode for photoelectrochemical water splitting, identified as a standard platform in the field, highlighting multiple potential-dependent charge transfer paths, otherwise hidden in the conventional IMPS data analysis

    A chaotic long-lived vortex at Venus southern pole

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    Polar vortices are common in the atmospheres of rapidly rotating planets [1-4]. On Earth and Mars they are tied to the surface and their existence follows the seasonal insolation cycle [1-3]. Venus is a slowly rotating planet but it is also known to have vortices at both poles at the edge of a superrotating atmosphere [5-8]. However, their nature and long-term properties have not been constrained so far impeding precise modeling. Here we report cloud motions at two altitude levels (about 42 km and 63 km above the surface) using infrared images from the VIRTIS instrument onboard Venus Express that show that the south polar vortex is a permanent but erratic and unpredictable feature. We find that the centers of rotation of the vortex at these levels rarely coincide and both wander erratically around the pole with speeds of up to 16 m s-1. The cloud morphology and vorticity patches are uncorrelated and change continuously developing transient areas of small vertical motions. Venus south polar vortex is a continuously evolving structure immersed in a baroclinic environment laying at altitude levels that have variable vertical and meridional wind shears, extending at least 20 km in height through a quasi-convective turbulent region
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