Minimum permissible leakage resistance established for instrumentation systems

Mathematical formulas are used to determine if, and to what extent, an instrumentation system that has been exposed to the elements should be dried out to restore minimum permissible leakage resistance to ground. Formulas are also derived and used for an intermediate number of systems that are exposed to moisture penetration

Light scattering of large rough particles application to cometary grains

While the electromagnetic field scattered by a spherical particle is classically obtained by the Helmholtz equation, the general case of an arbitrary particle may be investigated in the general framework of the interaction of a wave with a scattering potential. A wave function then satisfies the Schroedinger equation. The general solution of the Schroedinger equation is given. The main disadvantage of this approach are its restriction to large particles and its scalar nature preventing the calculation of the polarization. However, Perrin and Lamy have shown how to avoid the second limitation and retrieve a vectorial description. They proved that in the case of large spheres when the ad hoc assumptions are satisfied, the expression of the scattering amplitude may be approximated by an expansion series in partial waves, i.e., on a discrete basis. The analogy may be generalized, and the ratio of the two components for a rough particle obtained by taking the ratio of the reflectivities for the two directions of polarization. These reflectivities involve the simple and double reflections calculated following the method developed by Wolff for rough surfaces. The theory is further detailed

Optical properties of irregular interstellar grains

In order to study the interaction of light with interstellar grains, the authors represent an irregular particle by a network of interacting dipoles whose polarizability is determined in a first approach by the Clausius-Mossoti relationship. Typically, 10,000 dipoles are considered. In the case of spherical particles, the results from Mie theory are fully recovered. The main interest of this method is to study with good accuracy the implications of surface roughness and/or inhomogeneities on optical properties in the infrared spectral range, particularly of the silicate emission features

Monitoring of a Deep Basement in London

A deep basement in London Clay has been monitored throughout the entire duration of its excavation and construction, covering a period to date of over two and a half years. Measurements have provided a complete record of all aspects of the soil and structural behaviour. The high quality and regularity of the data, have enabled integration of diverse measurements which serve to identify important events in the history of the structure. The paper describes briefly the excavation and construction procedure, the measurements made. together with the installation methods employed. A selection of data covering a broad range of measurements is presented to illustrate some typical aspects of the interaction of the structure and the soil

Image effects in transport at metal-molecule interfaces

We present a method for incorporating image-charge effects into the description of charge transport through molecular devices. A simple model allows us to calculate the adjustment of the transport levels, due to the polarization of the electrodes as charge is added to and removed from the molecule. For this, we use the charge distributions of the molecule between two metal electrodes in several charge states, rather than in gas phase, as obtained from a density-functional theory-based transport code. This enables us to efficiently model level shifts and gap renormalization caused by image-charge effects, which are essential for understanding molecular transport experiments. We apply the method to benzene di-amine molecules and compare our results with the standard approach based on gas phase charges. Finally, we give a detailed account of the application of our approach to porphyrin-derivative devices recently studied experimentally by Perrin et al. [Nat. Nanotechnol. 8, 282 (2013)], which demonstrates the importance of accounting for image-charge effects when modeling transport through molecular junctions

The Excitation of Extended Red Emission: New Constraints on its Carrier From HST Observations of NGC 7023

The carrier of the dust-associated photoluminescence process causing the extended red emission (ERE) in many dusty interstellar environments remains unidentified. Several competing models are more or less able to match the observed broad, unstructured ERE band. We now constrain the character of the ERE carrier further by determining the wavelengths of the radiation that initiates the ERE. Using the imaging capabilities of the Hubble Space Telescope, we have resolved the width of narrow ERE filaments appearing on the surfaces of externally illuminated molecular clouds in the bright reflection nebula NGC 7023 and compared them with the depth of penetration of radiation of known wavelengths into the same cloud surfaces. We identify photons with wavelengths shortward of 118 nm as the source of ERE initiation, not to be confused with ERE excitation, however. There are strong indications from the well-studied ERE in the Red Rectangle nebula and in the high-|b| Galactic cirrus that the photon flux with wavelengths shortward of 118 nm is too small to actually excite the observed ERE, even with 100% quantum efficiency. We conclude, therefore, that ERE excitation results from a two-step process. While none of the previously proposed ERE models can match these new constraints, we note that under interstellar conditions most polycyclic aromatic hydrocarbon (PAH) molecules are ionized to the di-cation stage by photons with E > 10.5 eV and that the electronic energy level structure of PAH di-cations is consistent with fluorescence in the wavelength band of the ERE. Therefore, PAH di-cations deserve further study as potential carriers of the ERE. (abridged)Comment: Accepted for Publication in the Ap