Palladium, platinum, and gold distribution in serpentinite seamounts in the Mariana and Izu-Bonin forearcs: evidence from Leg 125 fluids and serpentinites

Palladium, platinum, and gold were analyzed for 20 interstitial water samples from Leg 125. No Pd or Pt was detected in fluids from serpentinite muds from Conical Seamount in the Mariana forearc, indicating that low-temperature seawater-peridotite interaction does not mobilize these elements into the serpentinizing fluids to levels above 0.10 parts per billion (ppb) in solution. However, Au may be mobilized in high pH solutions. In contrast, fluids from vitric-rich clays on the flanks of the Torishima Seamount in the Izu-Bonin forearc have Pd values of between 4.0 and 11.8 nmol/L, Pt values between 2.3 and 5.0 nmol/L and Au values between 126.9 and 1116.9 pmol/L. The precious metals are mobilized, and possibly adsorbed onto clay mineral surfaces, during diagenesis and burial of the volcanic-rich clays. Desorption during squeezing of the sediments may produce the enhanced precious metal concentrations in the analyzed fluids. The metals are mobilized in the fluids probably as neutral hydroxide, bisulfide, and ammonia complexes. Pt/Pd ratios are between 0.42 and 2.33, which is much lower than many of the potential sources for Pt and Pd but is consistent with the greater solubility of Pd compared with Pt in most natural low-temperature fluids

Palladium, platinum, and gold distribution in serpentinite seamounts in the Mariana and Izu-Bonin forearcs: evidence from Leg 125 fluids and serpentinites

Palladium, platinum, and gold were analyzed for 20 interstitial water samples from Leg 125. No Pd or Pt was detected in fluids from serpentinite muds from Conical Seamount in the Mariana forearc, indicating that low-temperature seawater-peridotite interaction does not mobilize these elements into the serpentinizing fluids to levels above 0.10 parts per billion (ppb) in solution. However, Au may be mobilized in high pH solutions. In contrast, fluids from vitric-rich clays on the flanks of the Torishima Seamount in the Izu-Bonin forearc have Pd values of between 4.0 and 11.8 nmol/L, Pt values between 2.3 and 5.0 nmol/L and Au values between 126.9 and 1116.9 pmol/L. The precious metals are mobilized, and possibly adsorbed onto clay mineral surfaces, during diagenesis and burial of the volcanic-rich clays. Desorption during squeezing of the sediments may produce the enhanced precious metal concentrations in the analyzed fluids. The metals are mobilized in the fluids probably as neutral hydroxide, bisulfide, and ammonia complexes. Pt/Pd ratios are between 0.42 and 2.33, which is much lower than many of the potential sources for Pt and Pd but is consistent with the greater solubility of Pd compared with Pt in most natural low-temperature fluids

Integrals of Motion for Critical Dense Polymers and Symplectic Fermions

We consider critical dense polymers ${\cal L}(1,2)$. We obtain for this model the eigenvalues of the local integrals of motion of the underlying Conformal Field Theory by means of Thermodynamic Bethe Ansatz. We give a detailed description of the relation between this model and Symplectic Fermions including the indecomposable structure of the transfer matrix. Integrals of motion are defined directly on the lattice in terms of the Temperley Lieb Algebra and their eigenvalues are obtained and expressed as an infinite sum of the eigenvalues of the continuum integrals of motion. An elegant decomposition of the transfer matrix in terms of a finite number of lattice integrals of motion is obtained thus providing a reason for their introduction.Comment: 53 pages, version accepted for publishing on JSTA

Trace element geochemistry of peridotites from the Izu-Bonin-Mariana Forearc, Leg 125

Trace element analyses (first-series transition elements, Ti, Rb, Sr, Zr, Y, Nb, and REE) were carried out on whole rocks and minerals from 10 peridotite samples from both Conical Seamount in the Mariana forearc and Torishima Forearc Seamount in the Izu-Bonin forearc using a combination of XRF, ID-MS, ICP-MS, and ion microprobe. The concentrations of incompatible trace elements are generally low, reflecting the highly residual nature of the peridotites and their low clinopyroxene content (n ratios in the range of 0.05-0.25; several samples show possible small positive Eu anomalies. LREE enrichment is common to both seamounts, although the peridotites from Conical Seamount have higher (La/Ce)n ratios on extended chondrite-normalized plots, in which both REEs and other trace elements are organized according to their incompatibility with respect to a harzburgitic mantle. Comparison with abyssal peridotite patterns suggests that the LREEs, Rb, Nb, Sr, Sm, and Eu are all enriched in the Leg 125 peridotites, but Ti and the HREEs exhibit no obvious enrichment. The peridotites also give positive anomalies for Zr and Sr relative to their neighboring REEs. Covariation diagrams based on clinopyroxene data show that Ti and the HREEs plot on an extension of an abyssal peridotite trend to more residual compositions. However, the LREEs, Rb, Sr, Sm, and Eu are displaced off this trend toward higher values, suggesting that these elements were introduced during an enrichment event. The axis of dispersion on these plots further suggests that enrichment took place during or after melting and thus was not a characteristic of the lithosphere before subduction. Compared with boninites sampled from the Izu-Bonin-Mariana forearc, the peridotites are significantly more enriched in LREEs. Modeling of the melting process indicates that if they represent the most depleted residues of the melting events that generated forearc boninites they must have experienced subsolidus enrichment in these elements, as well as in Rb, Sr, Zr, Nb, Sm, and Eu. The lack of any correlation with the degree of serpentinization suggests that low-temperature fluids were not the prime cause of enrichment. The enrichment in the high-field-strength elements also suggests that at least some of this enrichment may have involved melts rather than aqueous fluids. Moreover, the presence of the hydrous minerals magnesio-hornblende and tremolite and the common resorption of orthopyroxene indicate that this high-temperature peridotite-fluid interaction may have taken place in a water-rich environment in the forearc following the melting event that produced the boninites. The peridotites from Leg 125 may therefore contain a record of an important flux of elements into the mantle wedge during the initial formation of forearc lithosphere. Ophiolitic peridotites with these characteristics have not yet been reported, perhaps because the precise equivalents to the serpentinite seamounts have not been analyzed

Off-Critical Logarithmic Minimal Models

We consider the integrable minimal models ${\cal M}(m,m';t)$, corresponding to the $\varphi_{1,3}$ perturbation off-criticality, in the {\it logarithmic limit\,} $m, m'\to\infty$, $m/m'\to p/p'$ where $p, p'$ are coprime and the limit is taken through coprime values of $m,m'$. We view these off-critical minimal models ${\cal M}(m,m';t)$ as the continuum scaling limit of the Forrester-Baxter Restricted Solid-On-Solid (RSOS) models on the square lattice. Applying Corner Transfer Matrices to the Forrester-Baxter RSOS models in Regime III, we argue that taking first the thermodynamic limit and second the {\it logarithmic limit\,} yields off-critical logarithmic minimal models ${\cal LM}(p,p';t)$ corresponding to the $\varphi_{1,3}$ perturbation of the critical logarithmic minimal models ${\cal LM}(p,p')$. Specifically, in accord with the Kyoto correspondence principle, we show that the logarithmic limit of the one-dimensional configurational sums yields finitized quasi-rational characters of the Kac representations of the critical logarithmic minimal models ${\cal LM}(p,p')$. We also calculate the logarithmic limit of certain off-critical observables ${\cal O}_{r,s}$ related to One Point Functions and show that the associated critical exponents $\beta_{r,s}=(2-\alpha)\,\Delta_{r,s}^{p,p'}$ produce all conformal dimensions $\Delta_{r,s}^{p,p'}<{(p'-p)(9p-p')\over 4pp'}$ in the infinitely extended Kac table. The corresponding Kac labels $(r,s)$ satisfy $(p s-p' r)^2< 8p(p'-p)$. The exponent $2-\alpha ={p'\over 2(p'-p)}$ is obtained from the logarithmic limit of the free energy giving the conformal dimension $\Delta_t={1-\alpha\over 2-\alpha}={2p-p'\over p'}=\Delta_{1,3}^{p,p'}$ for the perturbing field $t$. As befits a non-unitary theory, some observables ${\cal O}_{r,s}$ diverge at criticality.Comment: 18 pages, 5 figures; version 3 contains amplifications and minor typographical correction

Heating of the Intracluster Gas in the Triangulum Australis Cluster

ASCA and ROSAT X-ray data are used to obtain two-dimensional maps of the gas temperature, pressure and specific entropy in the Triangulum Australis cluster of galaxies. We find that this hot (T_e=10.3+-0.8 keV) system probably has a temperature peak (T_e>12 keV) at the cluster core, which approximately corresponds to the adiabatic relation. An underdense gas sector, found in the ROSAT cluster image eastward of the core, has a higher temperature than average at that radius. At this higher temperature, the gas pressure in this region is equal to that of the rest of the cluster at the same radius, but the specific entropy of this gas is significantly higher (although the temperature difference itself is only marginally significant). We speculate that the existence of this region of underdense high-entropy gas, as well as the adiabatic central temperature peak, indicate recent or ongoing heating of the intergalactic medium in this cluster. The most probable source of such heating is a subcluster merger, for which the hydrodynamic simulations predict a qualitatively similar temperature structure. We point out that entropy maps can provide a physically meaningful way of diagnosing merging clusters and comparing the predictions of merger simulations to the data.Comment: Text revised to give more technical details and clarify discussion. Accepted for ApJ Letters. Latex, 5 pages incl. figures, macros include

W-Extended Fusion Algebra of Critical Percolation

Two-dimensional critical percolation is the member LM(2,3) of the infinite series of Yang-Baxter integrable logarithmic minimal models LM(p,p'). We consider the continuum scaling limit of this lattice model as a `rational' logarithmic conformal field theory with extended W=W_{2,3} symmetry and use a lattice approach on a strip to study the fundamental fusion rules in this extended picture. We find that the representation content of the ensuing closed fusion algebra contains 26 W-indecomposable representations with 8 rank-1 representations, 14 rank-2 representations and 4 rank-3 representations. We identify these representations with suitable limits of Yang-Baxter integrable boundary conditions on the lattice and obtain their associated W-extended characters. The latter decompose as finite non-negative sums of W-irreducible characters of which 13 are required. Implementation of fusion on the lattice allows us to read off the fusion rules governing the fusion algebra of the 26 representations and to construct an explicit Cayley table. The closure of these representations among themselves under fusion is remarkable confirmation of the proposed extended symmetry.Comment: 30 page

Boundary operators in the O(n) and RSOS matrix models

We study the new boundary condition of the O(n) model proposed by Jacobsen and Saleur using the matrix model. The spectrum of boundary operators and their conformal weights are obtained by solving the loop equations. Using the diagrammatic expansion of the matrix model as well as the loop equations, we make an explicit correspondence between the new boundary condition of the O(n) model and the "alternating height" boundary conditions in RSOS model.Comment: 29 pages, 4 figures; version to appear in JHE

Solvable Critical Dense Polymers

A lattice model of critical dense polymers is solved exactly for finite strips. The model is the first member of the principal series of the recently introduced logarithmic minimal models. The key to the solution is a functional equation in the form of an inversion identity satisfied by the commuting double-row transfer matrices. This is established directly in the planar Temperley-Lieb algebra and holds independently of the space of link states on which the transfer matrices act. Different sectors are obtained by acting on link states with s-1 defects where s=1,2,3,... is an extended Kac label. The bulk and boundary free energies and finite-size corrections are obtained from the Euler-Maclaurin formula. The eigenvalues of the transfer matrix are classified by the physical combinatorics of the patterns of zeros in the complex spectral-parameter plane. This yields a selection rule for the physically relevant solutions to the inversion identity and explicit finitized characters for the associated quasi-rational representations. In particular, in the scaling limit, we confirm the central charge c=-2 and conformal weights Delta_s=((2-s)^2-1)/8 for s=1,2,3,.... We also discuss a diagrammatic implementation of fusion and show with examples how indecomposable representations arise. We examine the structure of these representations and present a conjecture for the general fusion rules within our framework.Comment: 35 pages, v2: comments and references adde

A Merger Scenario for the Dynamics of Abell 665

We present new redshift measurements for 55 galaxies in the vicinity of the rich galaxy cluster Abell 665. When combined with results from the literature, we have good velocity measurements for a sample of 77 confirmed cluster members from which we derive the cluster's redshift z=0.1829 +/- 0.0005 and line-of-sight velocity dispersion of 1390 +/- 120 km/s. Our analysis of the kinematical and spatial data for the subset of galaxies located within the central 750 kpc reveals only subtle evidence for substructure and non-Gaussianity in the velocity distribution. We find that the brightest cluster member is not moving significantly relative to the other galaxies near the center of the cluster. On the other hand, our deep ROSAT high resolution image of A665 shows strong evidence for isophotal twisting and centroid variation, thereby confirming previous suggestions of significant substructure in the hot X-ray--emitting intracluster gas. In light of this evident substructure, we have compared the optical velocity data with N-body simulations of head-on cluster mergers. We find that a merger of two similar mass subclusters (mass ratios of 1:1 or 1:2) seen close to the time of core-crossing produces velocity distributions that are consistent with that observed.Comment: 30 pages and 7 figures. Accepted by the Astrophysical Journal Full resoultion figures 1 and 3 available in postscript at http://www.physics.rutgers.edu/~percy/A665paper.htm