494 research outputs found
The millisecond pulsar mass distribution: Evidence for bimodality and constraints on the maximum neutron star mass
The mass function of neutron stars (NSs) contains information about the late
evolution of massive stars, the supernova explosion mechanism, and the
equation-of-state of cold, nuclear matter beyond the nuclear saturation
density. A number of recent NS mass measurements in binary millisecond pulsar
(MSP) systems increase the fraction of massive NSs (with M)
to of the observed population. In light of these results, we
employ a Bayesian framework to revisit the MSP mass distribution. We find that
a single Gaussian model does not sufficiently describe the observed population.
We test alternative empirical models and infer that the MSP mass distribution
is strongly asymmetric. The diversity in spin and orbital properties of
high-mass NSs suggests that this is most likely not a result of the recycling
process, but rather reflects differences in the NS birth masses. The asymmetry
is best accounted for by a bimodal distribution with a low mass component
centred at M and dispersed by
M, and a high-mass component with a mean of
and a dispersion of
M. We also establish a lower limit of M
at 98% C.L. for the maximum NS mass, from the absence of a high-mass truncation
in the observed masses. Using our inferred model, we find that the measurement
of 350 MSP masses, expected after the conclusion of pulsar surveys with the
Square-Kilometre Array, can result in a precise localization of a maximum mass
up to 2.15 M, with a 5% accuracy. Finally, we identify possible
massive NSs within the known pulsar population and discuss birth masses of
MSPs.Comment: submitted to ApJ; 21 pages in aastex6 two-column format, 12 figures,
5 tables. Comments are welcom
Surface hydrophobization of bacterial and vegetable cellulose fibers using ionic liquids as solvent media and catalysts
The surface hydrophobization through heterogeneous chemical modification of bacterial (and vegetable) cellulose fibers with several anhydrides (acetic, butyric, hexanoic and alkenyl succinic anhydrides) and hexanoyl chloride suspended in an ionic liquid, tetradecyltrihexylphosphonium bis(trifluoromethylsulfonyl) imide, [TDTHP][NTf(2)], was studied. Furthermore, in the reaction with hexanoyl chloride, another ionic liquid, N-hexyl-4-(dimethylamino)pyridinium bis(trifluoromethylsulfonyl) imide, [C(6)N(CH(3))(2)py][NTf(2)], was used instead of common organic bases as catalyst and to trap the released HCl. The analysis of the ensuing modified fibers by FTIR, XRD and SEM clearly showed that the esterification reactions occurred essentially at the fibers' outmost layers, not affecting their ultrastructure. The degree of substitution (DS) of the ensuing esterified fibers ranged from less than 0.002 to 0.41; and in all instances, the fibers' surface acquired a high hydrophobicity. This novel approach constitutes an important strategy in the preparation of modified fibers under greener conditions relaying in the use of non-volatile solvents.FCT - SFRH/BD/72830/2010SFRH/BPD/41781/2007PTDC/QUI/68472/2006PTDC/QUI/72903/200
Growth and dry matter production in sugarcane varieties grown under full irrigation
A análise de crescimento é considerada o método padrão para medir a produtividade biológica em espécies vegetais. Neste contexto objetivou-se avaliar, em onze variedades de cana-de-açúcar (SP79-1011, RB813804, RB863129, RB872552, RB943365, RB72454, RB763710, SP78-4764, SP81-3250, RB867515, RB92579) cultivadas sob irrigação plena, o crescimento e a produção de matéria seca no ciclo de cana planta. O experimento foi instalado em condições de campo no município de Carpina, PE. Utilizou-se o delineamento estatístico de blocos ao acaso, com quatro repetições. A análise de crescimento correspondeu à quantificação dos números de perfilhos e à, na mensuração da altura e diâmetro dos colmos, avaliados mensalmente em onze períodos de cultivo, os quais se estenderam dos 60 aos 360 dias após o plantio (DAP). A produção de matéria seca foi quantificada a partir dos 120 DAP, com intervalos de amostragem a cada dois meses. Observou-se que as variedades RB92579 e SP81-3250 apresentaram o maior perfilhamento e produção de matéria seca e as variedades RB813804 e RB72454 às maiores médias de altura, enquanto as variedades RB867515 e RB72454 obtiveram os maiores diâmetros do colmo.Growth analysis is considered as a standard method for measuring the biological productivity of plant species. The objective of this research was to evaluate the growth and dry matter production of eleven sugarcane varieties (SP79-1011, RB813804, RB863129, RB872552, RB943365, RB72454, RB763710, SP78-4764, SP81-3250, RB867515, RB92579), grown under full irrigation, in the planted cane cycle. The experiment was conducted in field conditions in the municipality of Carpina, PE. A randomized block design with four replications was used. The varieties' growth analysis was represented by the quantification of the tillers numbers, stalk height and diameter, measured monthly, in eleven periods of cultivation that extended from 60 to 360 days after planting (DAP). The dry matter production was measured from 120 DAP, with sampling intervals of every two months. It was observed that, at 360 DAP, the RB92579 and SP81-3250 varieties showed the highest tillering and dry matter production. The RB813804 and RB72454 varieties had the highest average for height, while the RB72454 and RB867515 varieties presented the largest stalk diameters
Avaliação de estruturas de pavimentos rodoviários através de pista e simulador de ensaios acelerados à escala real
Os ensaios acelerados de pavimentos rodoviários consistem na aplicação controlada de um carregamento vertical,
através de uma roda normalizada que circula a uma velocidade controlada, simulando as cargas reais introduzidas pelo
tráfego pesado. Em condições de temperatura e humidade controladas, os ensaios acelerados permitem simular num
período de tempo reduzido as ações a que um pavimento está sujeito ao longo da sua vida útil. No âmbito do Projeto
Tropical-PAV foi construída no LNEC uma pista de ensaios à escala real e instalado um Simulador de Ensaios
Acelerados sobre Pavimentos Rodoviários possibilitando o estudo e a validação de técnicas de construção e/ou
reabilitação de pavimentos rodoviários. No presente trabalho é feita uma apresentação geral dos ensaios acelerados
sobre pavimentos rodoviários e em particular do Projeto de I&D Tropical-PAV.Quadro de Referência Estratégica Nacional e à entidade financiadora Agência
Nacional da Inovação pelo financiamento ao projeto número 38915 Projeto de I&D Tropical-PA
Soluções de pavimentos rodoviários para países com climas tropicais – projeto de I&D tropical-PAV
Algumas empresas do setor da construção que integram a Plataforma Tecnológica Portuguesa da Construção (PTPC) decidiram promover a cooperação tecnológica entre si e com as entidades do Sistema Científico e Tecnológico Nacional (SCTN) para o desenvolvimento de novas soluções de pavimentação rodoviária para aplicação em países de clima tropical, nomeadamente ao nível das misturas betuminosas e das camadas de solocimento. O objetivo do projeto foi permitir a eventual criação de uma solução de pavimentação inovadora através do desenvolvimento de uma mistura betuminosa e de uma mistura de solo-cimento formuladas com base em ensaios empíricos e de desempenho, à escala laboratorial e, posteriormente, validando esse desempenho num ensaio à escala real recorrendo a uma Pista de Ensaios Acelerados de Pavimentos, onde foram aplicados carregamentos idênticos às solicitações que serão alvo ao longo do seu período de vida útil. Esta Pista de Ensaios Acelerados de Pavimentos construída no âmbito deste projeto integra um protótipo de um simulador de tráfego, que reproduz a simulação do tipo de solicitação a que um pavimento habitualmente está sujeito
Institutional assessment as an instrument of rationalization back to the school as a formal organisation
O papel central da avaliação, da avaliação institucional e dos
processos de garantia da qualidade de escolas e universidades
nas políticas educacionais é objeto de discussão, também
considerando a reforma do Estado. As teorias da nova gestão
pública e as perspectivas gestionárias são consideradas como
algumas das principais fontes de inspiração e de legitimação no
contexto dominante de uma educação contábil. Dados empíricos
preliminares resultantes do processo de avaliação externa de
escolas básicas e secundárias portuguesas são apresentados
e interpretados de acordo com os principais conceitos e
representações organizacionais de escola presentes nos relatórios
externos. Examinando algumas das imagens e dos significados de
escola, cultura de escola, autonomia, objetivos, liderança e eficácia
presentes nos relatórios de avaliação, o autor releva a importância
das imagens formais, racionais e burocráticas de escolas. Várias
questões de investigação são apresentadas tendo por base aquilo
a que o autor chama o processo da hiperburocratização das
organizações educativas. Algumas dimensões do conceito de
burocracia de Max Weber são revisitadas, em articulação com
perspectivas neocientíficas de garantia da qualidade e com as
tecnologias da informação e comunicação. O autor sugere que
maior relevância deve ser atribuída aos modelos formais e racionais
de interpretação das organizações educativas, pois os processos de
avaliação e de garantia da qualidade estão a contribuir para a
formalização de escolas e universidades e para a intensificação do
seu processo de racionalização, isto é, para a emergência de uma
imagem analítica das escolas como hiperburocracias.The central role of evaluation, institutional assessment and quality
assurance processes of schools and universities in education policy
is object of discussion also considering the reform of the state. New
Public Management theories and managerialist perspectives are
considered some of the main sources of inspiration and legitimation
in the dominant context of an audit education. Preliminary
empirical data from external assessment of Portuguese primary and
secondary schools are introduced and interpreted according to the
main concepts and organizational representations of school found
in external reports. Examining some of the central organizational
images and meanings of school, school culture, autonomy, goals,
leadership and effectiveness included in the external reviews, the
author stresses the importance of formal, rational and bureaucratic
images of schools. Several new research questions are presented
for further inquiry based on the hypothesis of what it is called by
the author the process of hyperbureaucratization of educational
organizations. Some of the main dimensions of the concept of
bureaucracy as presented by Max Weber are revisited in close
relation with neo-scientific approaches of quality assurance and
taking in consideration the use of information and communication
technologies. Accordingly the author suggests that much more
importance must be given to formal and rational models of
interpreting educational organizations because assessment and
quality assurance procedures are contributing to the formalization
of schools and universities and to the intensification of their process
of rationalization, i. e., to the emergence of an analytic image of
schools as hyperbureaucracies.(undefined
Direct enzymatic esterification of cotton and Avicel with wild-type and engineered cutinases
In this work, the surface of cellulose, either Avicel or cotton fabric, was modified using cutinases without any previous treatment to swell or to solubilise the polymer. Aiming further improvement of cutinase ester synthase activity on cellulose, an engineered cutinase was investigated. Wild-type cutinase from Fusarium solani and its fusion with the carbohydrate-binding module N1 from Cellulomonas fimi were able to esterify the hydroxyl groups of cellulose with distinct efficiencies depending on the acid substrate/solvent system used, as shown by titration and by ATR-FTIR. The carbonyl stretching peak area increased significantly after enzymatic treatment during 72 h at 30 °C. Cutinase treatment resulted in relative increases of 31 and 9 % when octanoic acid and vegetable oil were used as substrates, respectively. Cutinase-N1 treatment resulted in relative increases of 11 and 29 % in the peak area when octanoic acid and vegetable oil were used as substrates, respectively. The production and application of cutinase fused with the domain N1 as a cellulose ester synthase, here reported for the first time, is therefore an interesting strategy to pursuit.This work was co-funded by the European Social Fund through the management authority POPH and FCT, Postdoctoral fellowship reference: SFRH/BPD/47555/2008. The authors also want to thank Doctor Raul Machado for his valuable help on FTIR spectral data treatment
The Millisecond Pulsars in NGC 6760
We present the results of recent Arecibo and Green Bank observations of the
globular cluster NGC 6760. Using Arecibo, a phase-coherent timing solution has
been obtained for the previously known binary pulsar in this cluster, PSR
J1911+0102A. We have also discovered a new millisecond pulsar in NGC 6760, PSR
J1911+0101B, an isolated object with a rotational period of 5.38 ms and a
dispersion measure DM = 196.7 cm-3 pc. Both pulsars are located within 1.3 core
radii of the cluster center and have negative period derivatives. The resulting
lower limits for the accelerations of the pulsars are within the range expected
given a simple model of the cluster. A search for eclipses in the PSR
J1911+0102A binary system using both telescopes yielded negative results. The
corresponding limits on the extra gas column density at superior conjunction
are consistent with the hypothesis that the observational properties of
ultra-low-mass binary pulsars like PSR J1911+0102A are strongly affected by the
inclination of the orbital plane of the system. Among globular cluster pulsar
populations, that of NGC 6760 exhibits one of the largest known spreads in DM.
This quantity seems to be roughly proportional to a cluster's central DM; this
suggests that the observed spread is caused by a turbulent interstellar medium
at spatial scales of 1 pc.Comment: 10 pages in referee format, 4 figures, one table, re-submitted to the
Astrophysical Journa
PSR J2021+3651: A Young Radio Pulsar Coincident with an Unidentified EGRET Gamma-ray Source
We report on a deep search for radio pulsations toward five unidentified ASCA
X-ray sources coincident with EGRET gamma-ray sources. This search has led to
the discovery of a young and energetic pulsar using data obtained with the new
Wideband Arecibo Pulsar Processor. PSR J2021+3651 is likely associated with the
X-ray source AX J2021.1+3651, which in turn is likely associated with the COS B
high energy gamma-ray source 2CG 075+00, also known as GeV J2020+3658 or 3EG
J2021+3716. PSR J2021+3651 has a rotation period P = 104 ms and P_dot =
9.6x10^{-14}, implying a characteristic age ~17 kyr and a spin-down luminosity
E_dot ~ 3.4x10^{36}ergs/s. The dispersion measure DM ~ 371 pc cm^{-3} is by far
the highest of any observed pulsar in the Galactic longitude range 55 < l < 80.
This DM suggests a distance d > 10 kpc, and a high gamma-ray efficiency of
\~15%, but the true distance may be closer if there is a significant
contribution to the DM from excess gas in the Cygnus region. The implied
luminosity of the associated X-ray source suggests the X-ray emission is
dominated by a pulsar wind nebula unresolved by ASCA.Comment: 6 pages, 2 figures, submitted to ApJ
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