COMPARATIVE ADSORPTION STUDY ON RICE HUSK AND RICE HUSK ASH BY USING AMARANTHUS GANGETICUS PIGMENTS AS DYE

Low cost adsorbents such as Rice Husk (RH) and Rice Husk Ash (RHA) were used for removing dyes from aqueous medium and later Linear, Langmuir and Freundlich adsorption isotherms have been verified by using adsorption data. RH was activated by treating with nitric acid and RHA was prepared from RH by dolomite process. Natural dyes were extracted from the vegetable Amaranthus gangeticus by using a standard method. The removal efficiency of adsorbents was measured for the variation of parameters pH, contact time and adsorbents concentration. It has been noted that after changing time for same amount of adsorbent (1g/100ml) and dyes (10 ml) RH gave no efficiency trend but increased to 43.91% whereas for RHA efficiency was gradually increased to 59.62%. A reverse trend was noted when adsorption amounts were changed and others were put constant where RHA efficiency gradually increased to 99.30% but RH gave no trend with highest efficiency was close to 61.85%. The RH removal efficiency was good for pH 11 close to 62.86% and it was continuous from 3.95% at pH 2. Alternately, RHA gave 80.21% at pH 2 and later was decreased to 1.5% at pH 9 and again increased from pH 11. It is noted that RHA removal efficiency is better than RH and adsorptions are well fitted with isotherms

COMPARATIVE ADSORPTION STUDY ON RICE HUSK AND RICE HUSK ASH BY USING AMARANTHUS GANGETICUS PIGMENTS AS DYE

Low cost adsorbents such as Rice Husk (RH) and Rice Husk Ash (RHA) were used for removing dyes from aqueous medium and later Linear, Langmuir and Freundlich adsorption isotherms have been verified by using adsorption data. RH was activated by treating with nitric acid and RHA was prepared from RH by dolomite process. Natural dyes were extracted from the vegetable Amaranthus gangeticus by using a standard method. The removal efficiency of adsorbents was measured for the variation of parameters pH, contact time and adsorbents concentration. It has been noted that after changing time for same amount of adsorbent (1g/100ml) and dyes (10 ml) RH gave no efficiency trend but increased to 43.91% whereas for RHA efficiency was gradually increased to 59.62%. A reverse trend was noted when adsorption amounts were changed and others were put constant where RHA efficiency gradually increased to 99.30% but RH gave no trend with highest efficiency was close to 61.85%. The RH removal efficiency was good for pH 11 close to 62.86% and it was continuous from 3.95% at pH 2. Alternately, RHA gave 80.21% at pH 2 and later was decreased to 1.5% at pH 9 and again increased from pH 11. It is noted that RHA removal efficiency is better than RH and adsorptions are well fitted with isotherms

Green synthesis of zinc oxide nanoparticles using Cocos nucifera leaf extract: characterization, antimicrobial, antioxidant and photocatalytic activity

Zinc oxide nanoparticles (ZnO NPs) have been successfully prepared using Cocos nucifera leaf extract and their antimicrobial, antioxidant and photocatalytic activity investigated. The structural, compositional and morphological properties of the NPs were recorded and studied systematically to confirm the synthesis. The aqueous suspension of NPs showed an ultraviolet–visible (UV–Vis) absorption maxima of 370 nm, indicating primarily its formation. X-ray diffraction analysis identified the NPs with a hexagonal wurtzite structure and an average particle size of 16.6 nm. Fourier transform infrared analysis identified some biomolecules and functional groups in the leaf extract as responsible for the encapsulation and stabilization of ZnO NPs. Energy-dispersive X-ray analysis showed the desired elemental compositions in the material. A flower-shaped morphology of ZnO NPs was observed by scanning electron microscopy, with a grain size of around 15 nm. The optical properties of the NPs were studied by UV–Vis spectroscopy, and the band gap was calculated as 3.37 eV. The prepared ZnO NPs have demonstrated antimicrobial activity against T. harzianum and S. aureus, with a zone of inhibition of 14 and 10 mm, respectively. The photocatalytic behaviour of ZnO NPs showed absorbance degradation at around 640 nm and it discoloured methylene blue dye after 1 h, with a degradation maximum of 84.29%. Thus, the prepared ZnO NPs could potentially be used in antibiotic development and pharmaceutical industries, and as photocatalysts