Application of Fourier Transform Infrared Spectroscopy (FTIR) for assessing biogenic silica sample purity in geochemical analyses and palaeoenvironmental research

The development of a rapid and non-destructive method to assess purity levels in samples of biogenic silica prior to geochemical/isotope analysis remains a key objective in improving both the quality and use of such data in environmental and palaeoclimatic research. Here a Fourier Transform Infrared Spectroscopy (FTIR) mass-balance method is demonstrated for calculating levels of contamination in cleaned sediment core diatom samples from Lake Baikal, Russia. Following the selection of end-members representative of diatoms and contaminants in the analysed samples, a mass-balance model is generated to simulate the expected FTIR spectra for a given level of contamination. By fitting the sample FTIR spectra to the modelled FTIR spectra and calculating the residual spectra, the optimum best-fit model and level of contamination is obtained. When compared to X-ray Fluorescence (XRF) the FTIR method portrays the main changes in sample contamination through the core sequence, permitting its use in instances where other, destructive, techniques are not appropriate. The ability to analyse samples of <1 mg enables, for the first time, routine analyses of small sized samples. Discrepancies between FTIR and XRF measurements can be attributed to FTIR end-members not fully representing all contaminants and problems in using XRF to detect organic matter external to the diatom frustule. By analysing samples with both FTIR and XRF, these limitations can be eliminated to accurately identify contaminated samples. Future, routine use of these techniques in palaeoenvironmental research will therefore significantly reduce the number of erroneous measurements and so improve the accuracy of biogenic silica/diatom based climate reconstructions

Impact of climate change on the characteristics of Indian summer monsoon onset

A high resolution regional climate modeling system, known as PRECIS (Providing REgional Climate for Impact Studies), developed by Hadley Centre for Climate Prediction and Research, UK, is applied for Indian subcontinent to assess the impact of climate change on the summer monsoon onset characteristics. The present day simulation (1961–1990) with PRECIS is evaluated for the characteristics of onset over Kerala, southernmost part of India, where the monsoon sets in over Indian landmass. The meteorological parameters like precipitation, outgoing long wave radiation (OLR), and low level winds are analysed to study the monsoon onset over Kerala. The model is able to capture the sudden and sharp increase of rainfall associated with the onset. The rapid built-up of convective activity over the southeastern Arabian Sea and Bay of Bengal is well represented by the model. PRECIS simulations, under scenarios of increasing greenhouse gas concentrations and sulphate aerosols, are analysed to study the likely changes in the onset characteristics in future, towards the end of present century (2071–2100). The analysis does not indicate significant difference in the mean onset dates in A2 and B2 scenarios. However, the variability of onset date is likely to be more towards the end of the 21st century especially in A2 scenario

Impact of global warming on cyclonic disturbances over south Asian region

A state-of-the-art regional climate modelling system, known as PRECIS (Providing REgional Climates for Impacts Studies) developed by the Hadley Centre for Climate Prediction and Research, UK is applied over the Indian domain to investigate the impact of global warming on the cyclonic disturbances such as depressions and storms. The PRECIS simulations at 50 × 50 km horizontal resolution are made for two time slices, present (1961–1990) and the future (2071–2100), for two socioeconomic scenarios A2 and B2. The model simulations under the scenarios of increasing greenhouse gas concentrations and sulphate aerosols are analysed to study the likely changes in the frequency, intensity and the tracks of cyclonic disturbances forming over north Indian Ocean (Bay of Bengal and Arabian Sea) and the Indian landmass during monsoon season. The model overestimates the frequency of cyclonic disturbances over the Indian subcontinent in baseline simulations (1961–1990). The change is evaluated towards the end of present century (2071–2100) with respect to the baseline climate. The present study indicates that the storm tracks simulated by the model are southwards as compared to the observed tracks during the monsoon season, especially for the two main monsoon months, viz., July and August. The analysis suggests that the frequency of cyclonic disturbances forming over north Indian Ocean is likely to reduce by 9% towards the end of the present century in response to the global warming. However, the intensity of cyclonic disturbances is likely to increase by about 11% compared to the present

Modelling the Encroachment of Farmhouse Culture on Private Village Pastures and Its Environmental Fall-Out in Northern Western Ghats, India

Tropical India harbours numerous pasturelands across small landholdings ranging up to few hectares which are covered with grass that is suitable as fodder. These grazing lands are commonly known as ‘Gairan’ in urbanised northern Western Ghats mountain tract in Western India). Such grasslands comprise about 20% of the total area of a village (Jodha, 1986), support livestock and supplement the agro-economy of the village. These pasturelands are being replaced by fenced ‘farmhouses’ of the urban elite, resulting in land use changes that caused drastic qualitative and quantitative changes in terms of area, fodder species composition and livestock they support (Patwardhan et al., 2003). The study area has faced large changes in the last few decades with increases in the area under settlement by 240%s as well as a decrease in the area of agriculture land and grasslands-scrub vegetation by 31 % and 39 % respectively (Nalavade, 2003). The present paper documents socio-cultural, economic and environmental changes in private village pastures across the Mumbai-Pune urban belt

Bioinspired Silica Offers a Novel, Green, and Biocompatible Alternative to Traditional Drug Delivery Systems

Development of drug delivery systems (DDS) is essential in many cases to remedy the limitations of free drug molecules. Silica has been of great interest as a DDS due to being more robust and versatile than other types of DDS (e.g., liposomes). Using ibuprofen as a model drug, we investigated bioinspired silica (BIS) as a new DDS and compared it to mesoporous silica (MS); the latter has received much attention for drug delivery applications. BIS is synthesized under benign conditions without the use of hazardous chemicals, which enables controllable in situ loading of drugs by carefully designing the DDS formulation conditions. Here, we systematically studied these conditions (e.g., chemistry, concentration, and pH) to understand BIS as a DDS and further achieve high loading and release of ibuprofen. Drug loading into BIS could be enhanced (up to 70%) by increasing the concentration of the bioinspired additive. Increasing the silicate concentration increased the release to 50%. Finally, acidic synthesis conditions could raise loading efficiency to 62% while also increasing the total mass of drug released. By identifying ideal formulation conditions for BIS, we produced a DDS that was able to release fivefold more drug per weight of silica when compared with MCM-41. Biocompatibility of BIS was also investigated, and it was found that, although ∼20% of BIS was able to pass through the gut wall into the bloodstream, it was nonhemolytic (∼2% hemolysis at 500 μg mL–1) when compared to MS (10% hemolysis at the same concentration). Overall, for DDS, it is clear that BIS has several advantages over MS (ease of synthesis, controllability, and lack of hazardous chemicals) as well as being less toxic, making BIS a real potentially viable green alternative to DDS

Evaluation of gas phase mass transfer at low reynolds numbers: a new model system

A new experimental system is presented which is suitable for studying gas side mass transfer coefficients in packed columns at Reynolds numbers even lower than 1.0. The system involves desorption of iodine from aqueous KI solutions. The reversible complex formation between iodine and iodine ions effectively slows down the concentration changes which otherwise would be too rapid for accurate experimentation

The role of charge-matching in nanoporous materials formation

Unravelling the molecular-level mechanisms that lead to the formation of mesoscale-ordered porous materials is a crucial step towards the goal of computational material design. For silica templated by alkylamine surfactants, a mechanism based on hydrogen-bond interactions between neutral amines and neutral silicates in solution has been widely accepted by the materials science community, despite the lack of conclusive evidence to support it. We demonstrate, through a combination of experimental measurements and multi-scale modelling, that the so-called “neutral templating route” does not represent a viable description of the synthesis mechanism of hexagonal mesoporous silica (HMS), the earliest example of amine-templated porous silica. Instead, the mesoscale structure of the material is defined by charge-matching of ionic interactions between amines and silicates. This has profound implications for the synthesis of a wide range of templated porous materials, and may shed new light on developing sustainable and economical routes to high value porous materials

Micro-Capsules in Shear Flow

This paper deals with flow-induced shape transitions of elastic capsules. The state of the art concerning both theory and experiments is briefly reviewed starting with dynamically induced small deformation of initially spherical capsules and the formation of wrinkles on polymerized membranes. Initially non-spherical capsules show tumbling and tank-treading motion in shear flow. Theoretical descriptions of the transition between these two types of motion assuming a fixed shape are at variance with the full capsule dynamics obtained numerically. To resolve the discrepancy, we expand the exact equations of motion for small deformations and find that shape changes play a dominant role. We classify the dynamical phase transitions and obtain numerical and analytical results for the phase boundaries as a function of viscosity contrast, shear and elongational flow rate. We conclude with perspectives on timedependent flow, on shear-induced unbinding from surfaces, on the role of thermal fluctuations, and on applying the concepts of stochastic thermodynamics to these systems.Comment: 34 pages, 15 figure

Simulated projections for summer monsoon climate over India by a high-resolution regional climate model (PRECIS)

Impact of global warming on the Indian monsoon climate is examined using Hadley Centre’s highresolution regional climate model, PRECIS (Providing REgional Climates for Impact Studies). Three simulations from a 17-member Perturbed Physics Ensemble generated using Hadley Center Coupled Model (HadCM3) for the Quantifying Uncertainty in Model Predictions (QUMP) project, are used to drive PRECIS. The PRECIS simulations corresponding to the IPCCSRES A1B emission scenario are carried out for a continuous period of 1961–2098. The model shows reasonable skill in simulating the monsoon climate over India. The climate projections are examined over three time slices, viz. short (2020s, i.e. 2011–2040), medium (2050s, i.e. 2041–2070) and long (2080s, i.e. 2071–2098). The model projections indicate significant warming over India towards the end of the 21st century. The summer monsoon precipitation over India is expected to be 9–16% more in 2080s compared to the baseline (1970s, i.e. 1961–1990) under global warming conditions. Also, the rainy days are projected to be less frequent and more intense over central India