acentric nanostructured assembly as a strategy for the design of organic electrooptic materials

The rational utilization of the paradigms of self-assembly and self-organization, essential requisites for the building up of the architectural complexity found in natural systems, is becoming an unavoidable strategy in the world of nanosciences. Recent developments in the field of organic materials for second-order nonlinear optics have focused in the recent past not only towards the optimization of the molecular engineering translating into ultrahigh molecular hyperpo- larizabilities, but also, and more fundamentally, towards the realization of acentric assemblies of such chromophores into nanomaterials with high electrooptic responses. Selected, recent examples dealing with these concepts are discussed

Synthesis of binaphthyl-based push-pull chromophores with supramolecularly polarizable acceptor ends

We report on the design and synthesis of new enantiopure binaphthyl derivatives in which electron-donating and electron-withdrawing substituents are placed in direct conjugation, to create push-pull dyes potentially active for NLO applications. The dyes, unprecedentedly, extend their π-bridge from the 3,3′ positions of the binaphthyl units and incorporate as acceptors 1,3-dicarbonyl and tetrafluorobenzene units, useful for further supramolecular polarization of the chiral dyes

Chiral Triptycenes in Supramolecular and Materials Chemistry

Triptycenes are an intriguing class of organic molecules with several unusual characteristics, such as a propeller-like shape, saddle-like cavities around a symmetrical scaffold, a rigid π-framework. They have been extensively studied and proposed as key synthons for a variety of applications in supramolecular chemistry and materials science. When decorated with an appropriate substitution pattern, triptycenes can be chiral, and, similarly to other popular chiral π-extended synthons, can express chirality robustly, efficiently, and with relevance to chiroptical spectroscopies. This minireview highlights and encompasses recent advances in the synthesis of chiral triptycenes and in their introduction as molecular scaffolds for the assembly of functional supramolecular materials

Direct Arylation Strategies in the Synthesis of π-Extended Monomers for Organic Polymeric Solar Cells

π-conjugated macromolecules for organic polymeric solar cells can be rationally engineered at the molecular level in order to tune the optical, electrochemical and solid-state morphology characteristics, and thus to address requirements for the efficient solid state device implementation. The synthetic accessibility of monomers and polymers required for the device is getting increasing attention. Direct arylation reactions for the production of the π-extended scaffolds are gaining importance, bearing clear advantages over traditional carbon-carbon forming methodologies. Although their use in the final polymerization step is already established, there is a need for improving synthetic accessibility to implement them also in the monomer synthesis. In this review, we discuss recent examples highlighting this useful strategy

Rotordynamic Forces on a Three Bladed Inducer under Forced Whirl Motion Operating at Different Conditions

The paper illustrates the main results of an experimental campaign conducted in the CPRTF (Cavitating Pump Rotordynamic Test Facility) at ALTA S.p.A., aimed at characterizing the rotordynamic forces acting on a whirling three-bladed, tapered-hub, variable-pitch inducer, named DAPROT3. The forces acting on the impeller have been measured by means of a rotating dynamometer mounted just behind the inducer. The roles of the imposed whirl motion of the rotor, flow coefficient, cavitation number and liquid temperature have been investigated. The results have been obtained by means of a recent experimental technique, consisting in measuring the continuous spectra of the rotordynamic forces as functions of the whirl excitation frequency. This technique allows for extrapolating valuable information from the experiments by more accurately and rapidly characterizing the spectral behavior of these forces than can be obtained from a limited number of point experiments conducted at constant whirl frequency. Therefore, it is useful to better capture the complexity of the rotordynamic forces and assess their consequences on the stability of axial inducers

Cavitating Pump Rotordynamic Test Facility at ALTA S.p.A.: Upgraded Capabilities of a Unique Test Rig

The paper illustrates the upgrades recently introduced in Alta’s Cavitating Pump Rotordynamic Test Facility in order to extend its experimental capabilities, with special reference to the addition of an auxiliary pump for testing of turbopump inducers over a wider range of flow coefficients, and the set-up of an original apparatus specifically designed for the characterization of the dynamic transfer matrices of cavitating inducers and turbopumps. Examples are presented of the improved capabilities of the facility

Crystal structure analyses facilitate understanding of synthesis protocols in the preparation of 6,6′-dibromo-substituted BINOL compounds

A combination of crystallographic and spectroscopic techniques has been used in order to address thorough purification protocols for a series of atropisomeric 1,1′-binaphthalene-2,2′-diol (BINOL) derivatives to be used as building blocks for chiral nanoscale constructs

Chiral nanostructuring of multivalent macrocycles in solution and on surfaces

We describe the design and synthesis of a novel functionality-rich, homochiral macrocycle, possessing the overall molecular D-2 symmetry, in which multivalency is introduced into the covalent framework by means of four suitably positioned pyridine moieties. The macrocycle synthesis is carried out with functionalized, enantiopure 1,1'-binaphthyl synthons as the source of chirality by means of a room temperature esterification reaction as the cyclization procedure. Upon addition of Pd2+, coordination of the pyridine moieties occurs both intra and intermolecularly, to afford chiral ordered mono and dimeric macrocycles or multimeric aggregates depending on the solvents and conditions used. The metal binding event takes place in combination with a significant macrocyclic conformational rearrangement detected by circular dichroism spectroscopy. When in combination with a third component (C-60), the macrocycle-Pd2+ hybrid undergoes surface-confined nanostructuring into chiral nanofibres

A Reduced Order Model for Optimal Centrifugal Pump Design

A reduced order model for preliminary design and noncavitating performance prediction of radial turbopumps has been illustrated in a previous paper presented by the same authors. The model expresses the 3D incompressible, inviscid, irrotational flow through helical blades with slow axial variations of the pitch and backsweep by superposing a 2D cross-sectional axial vorticity correction to a fully-guided flow with axisymmetric stagnation velocity in the meridional plane. Application of the relevant governing equations yields a set of constraints for the axial evolution of the blade pitch and backsweep that allows for the closed form definition of the impeller geometry and flowfield in terms of a reduced number of controlling parameters. In turn, mass and momentum conservation are used to account for the mixing of the flow leaving the impeller and its coupling with 2D reduced order models of the flow in the diffuser (if any) and the volute, thus generating the information necessary for completing the geometric definition of the machine and for determining its ideal noncavitating performance in accordance with the resulting flowfield. In the present paper, the above ideal flow model has been interfaced with the calculation of boundary layers inside the blade channels and other major forms of flow losses, with the aim of developing an effective tool for rapid parametric optimization of the machine geometry and performance under appropriate design constraints such as target values of the specific speed, flow coefficient and impeller blading solidity