3,704 research outputs found
Doping Evolution of Oxygen K-edge X-ray Absorption Spectra in Cuprate Superconductors
We study oxygen K-edge x-ray absorption spectroscopy (XAS) and investigate
the validity of the Zhang-Rice singlet (ZRS) picture in overdoped cuprate
superconductors. Using large-scale exact diagonalization of the three-orbital
Hubbard model, we observe the effect of strong correlations manifesting in a
dynamical spectral weight transfer from the upper Hubbard band to the ZRS band.
The quantitative agreement between theory and experiment highlights an
additional spectral weight reshuffling due to core-hole interaction. Our
results confirm the important correlated nature of the cuprates and elucidate
the changing orbital character of the low-energy quasi-particles, but also
demonstrate the continued relevance of the ZRS even in the overdoped region.Comment: Original: 5 pages, 4 figures. Replaced: 6 pages and 4 figures, with
updated title and conten
Topological Constraints at the Theta Point: Closed Loops at Two Loops
We map the problem of self-avoiding random walks in a Theta solvent with a
chemical potential for writhe to the three-dimensional symmetric
U(N)-Chern-Simons theory as N goes to 0. We find a new scaling regime of
topologically constrained polymers, with critical exponents that depend on the
chemical potential for writhe, which gives way to a fluctuation-induced
first-order transition.Comment: 5 pages, RevTeX, typo
Doping evolution of spin and charge excitations in the Hubbard model
To shed light on how electronic correlations vary across the phase diagram of
the cuprate superconductors, we examine the doping evolution of spin and charge
excitations in the single-band Hubbard model using determinant quantum Monte
Carlo (DQMC). In the single-particle response, we observe that the effects of
correlations weaken rapidly with doping, such that one may expect the random
phase approximation (RPA) to provide an adequate description of the
two-particle response. In contrast, when compared to RPA, we find that
significant residual correlations in the two-particle excitations persist up to
hole and electron doping (the range of dopings achieved in the
cuprates). These fundamental differences between the doping evolution of
single- and multi-particle renormalizations show that conclusions drawn from
single-particle processes cannot necessarily be applied to multi-particle
excitations. Eventually, the system smoothly transitions via a
momentum-dependent crossover into a weakly correlated metallic state where the
spin and charge excitation spectra exhibit similar behavior and where RPA
provides an adequate description.Comment: 5 pages, 4 figures, plus supplementary materia
Secure Vehicular Communication Systems: Implementation, Performance, and Research Challenges
Vehicular Communication (VC) systems are on the verge of practical
deployment. Nonetheless, their security and privacy protection is one of the
problems that have been addressed only recently. In order to show the
feasibility of secure VC, certain implementations are required. In [1] we
discuss the design of a VC security system that has emerged as a result of the
European SeVeCom project. In this second paper, we discuss various issues
related to the implementation and deployment aspects of secure VC systems.
Moreover, we provide an outlook on open security research issues that will
arise as VC systems develop from today's simple prototypes to full-fledged
systems
Activated O2 dissociation and formation of oxide islands on the Be(0001) surface: Another atomistic model for metal oxidation
By simulating the dissociation of O2 molecules on the Be(0001) surface using
the first-principles molecular dynamics approach, we propose a new atomistic
model for the surface oxidation of sp metals. In our model, only the
dissociation of the first oxygen molecule needs to overcome an energy barrier,
while the subsequent oxygen molecules dissociate barrierlessly around the
adsorption area. Consequently, oxide islands form on the metal surface, and
grow up in a lateral way. We also discover that the firstly dissociated oxygen
atoms are not so mobile on the Be(0001) surface, as on the Al(111) surface. Our
atomistic model enlarges the knowledge on metal surface oxidations by perfectly
explaining the initial stage during the surface oxidation of Be, and might be
applicable to some other sp metal surfaces.Comment: 5 pages, 4 figure
Hydrodynamics of polar liquid crystals
Starting from a microscopic definition of an alignment vector proportional to
the polarization, we discuss the hydrodynamics of polar liquid crystals with
local -symmetry. The free energy for polar liquid crystals
differs from that of nematic liquid crystals () in that it
contains terms violating the symmetry. First we show
that these -odd terms induce a general splay instability of a
uniform polarized state in a range of parameters. Next we use the general
Poisson-bracket formalism to derive the hydrodynamic equations of the system in
the polarized state. The structure of the linear hydrodynamic modes confirms
the existence of the splay instability.Comment: 9 pages, corrected typos, added references, revised content, to
appear in PR
Dependence of the flux creep activation energy on current density and magnetic field for MgB2 superconductor
Systematic ac susceptibility measurements have been performed on a MgB
bulk sample. We demonstrate that the flux creep activation energy is a
nonlinear function of the current density , indicating a
nonlogarithmic relaxation of the current density in this material. The
dependence of the activation energy on the magnetic field is determined to be a
power law , showing a steep decline in the activation
energy with the magnetic field, which accounts for the steep drop in the
critical current density with magnetic field that is observed in MgB. The
irreversibility field is also found to be rather low, therefore, the pinning
properties of this new material will need to be enhanced for practical
applications.Comment: 11 pages, 6 figures, Revtex forma
Ion Pairs for Transdermal and Dermal Drug Delivery: A Review
Ion pairing is a strategy used to increase the permeation of topically applied ionised drugs. Formation occurs when the electrostatic energy of attraction between oppositely charged ions exceeds their mean thermal energy, making it possible for them to draw together and attain a critical distance. These ions then behave as a neutral species, allowing them to partition more readily into a lipid environment. Partition coefficient studies may be used to determine the potential of ions to pair and partition into an organic phase but cannot be relied upon to predict flux. Early researchers indicated that temperature, size of ions and dielectric constant of the solvent system all contributed to the formation of ion pairs. While size is important, this may be outweighed by improved lipophilicity of the counter ion due to increased length of the carbon chain. Organic counter ions are more effective than inorganic moieties in forming ion pairs. In addition to being used to increase permeation, ion pairs have been used to control and even prevent permeation of the active ingredient. They have also been used to stabilise solid lipid nanoparticle formulations. Ion pairs have been used in conjunction with permeation enhancers, and permeation enhancers have been used as counter ions in ion pairing. This review attempts to show the various ways in which ion pairs have been used in drug delivery via the skin. It also endeavours to extract and consolidate common approaches in order to inform future formulations for topical and transdermal delivery
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