Політичні стереотипи та стереотипізація мислення: роль та значення у системі іміджевих комунікацій

Всебічно розглянуто особливості стереотипізації мислення як важливого чинника у процесі сприйняття та аналізу особою або групою осіб суспільно-політичної дійсності. Досліджено природу, джерела та механізми формування політичних стереотипів та показано їх роль і значення у системі іміджевих комунікацій. Наголошено на необхід- ності аналізу існуючої системи стереотипів при створенні іміджу суб’єкта політики.There have been thoroughly examined peculiarities of stereotyping of thinking as an important factor in the process of perception and analysis of socio-political reality by a person or a group of people. There have been investigated the nature, sources and mechanism of political stereotypes formation and showed their role and meaning in the system if image communications. There has been put an emphasis on the necessity of analysis of the existing system of stereotypes while creating the image of a subject of policy

Understanding the unique biogeochemistry of the Mediterranean Sea: Insights from a coupled phosphorus and nitrogen model

The Mediterranean Sea (MS) is an oligotrophic basin whose offshore water column exhibits low dissolved inorganic phosphorus (P) and nitrogen (N) concentrations, unusually high nitrate (NO3) to phosphate (PO4) ratios, and distinct biogeochemical differences between the Western Mediterranean Sea (WMS) and Eastern Mediterranean Sea (EMS). A new mass balance model of P and N cycling in the WMS is coupled to a pre‐existing EMS model to understand these biogeochemical features. Estimated land‐derived inputs of reactive P and N to the WMS and EMS are similar per unit surface area, but marine inputs are 4 to 5 times greater for the WMS, which helps explain the approximately 3 times higher primary productivity of the WMS. The lateral inputs of marine sourced inorganic and organic P support significant fractions of new production in the WMS and EMS, similar to subtropical gyres. The mass balance calculations imply that the MS is net heterotrophic: dissolved organic P and N entering the WMS and EMS, primarily via the Straits of Gibraltar and Sicily, are mineralized to PO4 and NO3 and subsequently exported out of the basin by the prevailing anti‐estuarine circulation. The high deepwater (DW) molar NO3:PO4 ratios reflect the high reactive N:P ratio of inputs to the WMS and EMS, combined with low denitrification rates. The lower DW NO3:PO4 ratio of the WMS (21) compared to the EMS (28) reflects lower reactive N:P ratios of inputs to the WMS, including the relatively low N:P ratio of Atlantic surface water flowing into the WMS

Global Dam‐Driven Changes to Riverine N:P:Si Ratios Delivered to the Coastal Ocean

River damming alters nutrient fluxes along the land-ocean aquatic continuum as a result of biogeochemical processes in reservoirs. Both the changes in riverine nutrient fluxes and nutrient ratios impact ecosystem functioning of receiving water bodies. We utilize spatially distributed mechanistic models of nitrogen (N), phosphorus (P), and silicon (Si) cycling in reservoirs to quantify changes in nutrient stoichiometry of river discharge to coastal waters. The results demonstrate that the growing number of dams decouples the riverine fluxes of N, P, and Si. Worldwide, preferential removal of P over N in reservoirs increases N:P ratios delivered to the ocean, raising the potential for P limitation of coastal productivity. By midcentury, more than half of the rivers discharging to the coastal zone will experience a higher removal of reactive Si relative to reactive P and total N, in response to the rapid pace at which new hydroelectric dams are being built

Effects of pH and Dissolved Silicate on Phosphate Mineral-Water Partitioning with Goethite

Release of sorbed phosphate from ferric iron oxyhydroxides can contribute to excessive algal growth in surface water bodies. Dissolved silicate has been hypothesized to facilitate phosphate desorption by competing for mineral surface sites. Here, we conducted phosphate and silicate adsorption experiments with goethite under a wide pH range (3–11), both individually (P or Si) and simultaneously (P plus Si). The entire experimental data set was successfully reproduced by the charge distribution multisite surface complexation (CD-MUSIC) model. Phosphate adsorption was highest under acidic conditions and gradually decreased from near-neutral to alkaline pH conditions. Maximum silicate adsorption, in contrast, occurred under alkaline conditions, peaking around pH 10. The competitive effect of silicate on phosphate adsorption was negligible under acidic conditions, becoming more pronounced under alkaline conditions and elevated molar Si:P ratios (>4). In a subsequent experiment, desorption of phosphate with increasing pH was monitored, in the presence or absence of dissolved silicate. While, as expected, desorption of phosphate was observed during the transition from acidic to alkaline conditions, a fraction of phosphate remained irreversibly bound to goethite. Even at high Si:P ratios and alkaline pH, dissolved silicate did not affect phosphate desorption, implying that kinetic factors prevented silicate from displacing phosphate from goethite binding sites

Phosphorus retention and transformation in a dammed reservoir of the Thames River, Ontario: Impacts on phosphorus load and speciation

Extensive efforts are underway to reduce phosphorus (P) export from the Lake Erie watershed. On the Canadian side, the Thames River is the largest tributary source of P to Lake Erie’s western basin. However, the role of dams in retaining and modifying riverine P loading to the lake has not been comprehensively evaluated. We assessed whether Fanshawe Reservoir, the largest dam reservoir on the Thames River, acts as a source or sink of P, using year-round discharge and water chemistry data collected in 2018 and 2019. We also determined how in-reservoir processes alter P speciation by comparing the dissolved reactive P to total P ratio (DRP:TP) in upstream and downstream loads. Annually, Fanshawe Reservoir was a net sink for P, retaining 25% (36 tonnes) and 47% (91 tonnes) of TP in 2018 and 2019, respectively. Seasonally, the reservoir oscillated between a source and sink of P. Net P release occurred during the spring of 2018 and the summers of 2018 and 2019, driven by internal P loading and hypolimnetic discharge from the dam. The reservoir did not exert a strong influence on DRP:TP annually, but ratio increases occurred during both summers, concurrent with water column stratification. Our analysis demonstrates that Fanshawe Reservoir is not only an important P sink on the Thames River, but also modulates the timing and speciation of P loads. We therefore propose that the potential of using existing dam reservoirs to attenuate downstream P loads should be more thoroughly explored alongside source based P mitigation strategies.Canada-Ontario Agreement on Great Lakes Water Quality and Ecosystem Health || Canada First Research Excellence Fund through the Lake Futures project of the Global Water Futures

Transport of chloride and deuterated water in peat: The role of anion exclusion, diffusion, and anion adsorption in a dual porosity organic media

The final publication is available at Elsevier via https://doi.org/10.1016/j.jconhyd.2019.103497. © 2019. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/The dual-porosity structure of peat and the extremely high organic matter content give rise to a complex medium that typically generates prolonged tailing and early 50% concentration breakthrough in the breakthrough curves (BTCs) of chloride (Cl−) and other anions. Untangling whether these observations are due to rate-limited (physical) diffusion into inactive pores, (chemical) adsorption or anion exclusion remains a critical question in peat hydrogeochemistry. This study aimed to elucidate whether Cl− is truly conservative in peat, as usually assumed, and whether the prolonged tailing and early 50% concentration breakthrough of Cl− observed is due to diffusion, adsorption, anion exclusion or a combination of all three. The mobile-immobile (MiM) dual-porosity model was fit to BTCs of Cl− and deuterated water measured on undisturbed cores of the same peat soils, and equilibrium Cl− adsorption batch experiments were conducted. Adsorption of Cl− to undecomposed and decomposed peat samples in batch experiments followed Freundlich isotherms but did not exhibit any trends with the degree of peat decomposition and sorption became negligible below aqueous Cl− concentrations of ~310 mg L−1. The dispersivity determined by fitting the Cl− BTCs whether assuming adsorption or no adsorption were significantly different than determined by the deuterated water (p < .0001). However, no statistical differences in dispersivity (p = .27) or immobile water content (p = .97) was observed between deuterated water and Cl− when accounting for anion exclusion. A higher degree of decomposition significantly increased anion exclusion (p < .0001) but did not influence the diffusion of either tracer into the immobile porosity. Contrary to previous assumptions, Cl− is not truly conservative in peat due to anion exclusion, and adsorption at higher aqueous concentrations, but the overall effect of anion exclusion on transport is likely minimal.The authors acknowledge funding through the Canada Excellence Research Chair (CERC) program to PVC

Оценивание устойчивого развития окружающей среды на субнациональном уровне в Украине

Рассмотрены существующие методы оценивания устойчивого развития окружающей среды (самостоятельные индикаторы, а также их системы и индексы). Предложен индекс устойчивого развития окружающей среды для оценивания взаимоотношений с окружающей средой на уровне регионов Украины, учитывающий национальные приоритеты в экологической политике. По предложенному региональному индексу получены экологические профили и рейтинг областей Украины.Розглянуто існуючі методи оцінювання сталого розвитку довкілля (самостійні індикатори, а також їх системи та індекси). Запропоновано індекс сталого розвитку довкілля для оцінювання взаємовідносин із навколишнім середовищем на рівні регіонів України, який враховує національні пріоритети в екологічній політиці. За запропонованим регіональним індексом отримано екологічні профілі і рейтинг областей України.The existing methods for assessment of the environment sustainable development (independent indicators, their systems and indices) are considered. The environment sustainability index for assessment of relations with the environment at a regional level for Ukraine is proposed, which takes into account the national priorities in ecological policy. Ecological profiles and rating of the Ukrainian regions are obtained according to the proposed regional index

A very brief description of LOFAR - the Low Frequency Array

LOFAR (Low Frequency Array) is an innovative radio telescope optimized for the frequency range 30-240 MHz. The telescope is realized as a phased aperture array without any moving parts. Digital beam forming allows the telescope to point to any part of the sky within a second. Transient buffering makes retrospective imaging of explosive short-term events possible. The scientific focus of LOFAR will initially be on four key science projects (KSPs): 1) detection of the formation of the very first stars and galaxies in the universe during the so-called epoch of reionization by measuring the power spectrum of the neutral hydrogen 21-cm line (Shaver et al. 1999) on the ~5' scale; 2) low-frequency surveys of the sky with of order $10^8$ expected new sources; 3) all-sky monitoring and detection of transient radio sources such as gamma-ray bursts, x-ray binaries, and exo-planets (Farrell et al. 2004); and 4) radio detection of ultra-high energy cosmic rays and neutrinos (Falcke & Gorham 2003) allowing for the first time access to particles beyond 10^21 eV (Scholten et al. 2006). Apart from the KSPs open access for smaller projects is also planned. Here we give a brief description of the telescope.Comment: 2 pages, IAU GA 2006, Highlights of Astronomy, Volume 14, K.A. van der Hucht, e

Amplitude calibration of a digital radio antenna array for measuring cosmic ray air showers

Radio pulses are emitted during the development of air showers, where air showers are generated by ultra-high energy cosmic rays entering the Earth's atmosphere. These nanosecond short pulses are presently investigated by various experiments for the purpose of using them as a new detection technique for cosmic particles. For an array of 30 digital radio antennas (LOPES experiment) an absolute amplitude calibration of the radio antennas including the full electronic chain of the data acquisition system is performed, in order to estimate absolute values of the electric field strength for these short radio pulses. This is mandatory, because the measured radio signals in the MHz frequency range have to be compared with theoretical estimates and with predictions from Monte Carlo simulations to reconstruct features of the primary cosmic particle. A commercial reference radio emitter is used to estimate frequency dependent correction factors for each single antenna of the radio antenna array. The expected received power is related to the power recorded by the full electronic chain. Systematic uncertainties due to different environmental conditions and the described calibration procedure are of order 20%.Comment: Article accepted by Nuclear Instruments and Methods in Physics Research, A (NIM A