Rocking motion induced charging of C60 on h-BN/Ni(111)

One monolayer of C60 on one monolayer of hexagonal boron nitride on nickel is investigated by photoemission. Between 150 and 250 K the work function decreases and the binding energy of the highest occupied molecular orbital (HOMO) increases by approx. 100 meV. In parallel, the occupancy of the, in the cold state almost empty, lowest unoccupied molecular orbital (LUMO) changes by 0.4 electrons. This charge redistribution is triggered by onset of molecular rocking motion, i.e. by orientation dependent tunneling between the LUMO of C60 and the substrate. The magnitude of the charge transfer is large and cannot be explained within a single particle picture. It is proposed to involve electron-phonon coupling where C60- polaron formation leads to electron self-trapping.Comment: 15 pages, 4 figure

Remarks on some new models of interacting quantum fields with indefinite metric

We study quantum field models in indefinite metric. We introduce the modified Wightman axioms of Morchio and Strocchi as a general framework of indefinite metric quantum field theory (QFT) and present concrete interacting relativistic models obtained by analytical continuation from some stochastic processes with Euclidean invariance. As a first step towards scattering theory in indefinite metric QFT, we give a proof of the spectral condition on the translation group for the relativistic models.Comment: 13 page

Continuum Limit of 2D2D Spin Models with Continuous Symmetry and Conformal Quantum Field Theory

According to the standard classification of Conformal Quantum Field Theory (CQFT) in two dimensions, the massless continuum limit of the $O(2)$ model at the Kosterlitz-Thouless (KT) transition point should be given by the massless free scalar field; in particular the Noether current of the model should be proportional to (the dual of) the gradient of the massless free scalar field, reflecting a symmetry enhanced from $O(2)$ to $O(2)\times O(2)$. More generally, the massless continuum limit of a spin model with a symmetry given by a Lie group $G$ should have an enhanced symmetry $G\times G$. We point out that the arguments leading to this conclusion contain two serious gaps: i) the possibility of `nontrivial local cohomology' and ii) the possibility that the current is an ultralocal field. For the $2D$ $O(2)$ model we give analytic arguments which rule out the first possibility and use numerical methods to dispose of the second one. We conclude that the standard CQFT predictions appear to be borne out in the $O(2)$ model, but give an example where they would fail. We also point out that all our arguments apply equally well to any $G$ symmetric spin model, provided it has a critical point at a finite temperature.Comment: 19 page

Controlling the effective mass of quantum well states in Pb/Si(111) by interface engineering

The in-plane effective mass of quantum well states in thin Pb films on a Bi reconstructed Si(111) surface is studied by angle-resolved photoemission spectroscopy. It is found that this effective mass is a factor of three lower than the unusually high values reported for Pb films grown on a Pb reconstructed Si(111) surface. Through a quantitative low-energy electron diffraction analysis the change in effective mass as a function of coverage and for the different interfaces is linked to a change of around 2% in the in-plane lattice constant. To corroborate this correlation, density functional theory calculations were performed on freestanding Pb slabs with different in-plane lattice constants. These calculations show an anomalous dependence of the effective mass on the lattice constant including a change of sign for values close to the lattice constant of Si(111). This unexpected relation is due to a combination of reduced orbital overlap of the 6p_z states and altered hybridization between the 6p_z and 6p_xy derived quantum well states. Furthermore it is shown by core level spectroscopy that the Pb films are structurally and temporally stable at temperatures below 100 K.Comment: 7 pages, 6 figure

Tuning of the Rashba effect in Pb quantum well states via a variable Schottky barrier

Spin-orbit interaction (SOI) in low-dimensional systems results in the fascinating property of spin-momentum locking. In a Rashba system the inversion symmetry normal to the plane of a two-dimensional (2D) electron gas is broken, generating a Fermi surface spin texture reminiscent of spin vortices of different radii. This can be exploited in a spin-based field-effect transistor (spin- FET), where the Rashba system forms a 2D channel between ferromagnetic (FM) source and drain electrodes. The electron spin precesses when propagating through the Rashba channel and spin orientations (anti)parallel to the drain give (low) high conductivity. Crucial is the possibility to tune the momentum splitting, and consequently the precession angle, through an external parameter. Here we show that this can be achieved in Pb quantum well states through the doping dependence of the Schottky barrier, opening up the possibility of a terahertz spin-FET.Comment: 8 pages, 7 figure

Negative-Energy Spinors and the Fock Space of Lattice Fermions at Finite Chemical Potential

Recently it was suggested that the problem of species doubling with Kogut-Susskind lattice fermions entails, at finite chemical potential, a confusion of particles with antiparticles. What happens instead is that the familiar correspondence of positive-energy spinors to particles, and of negative-energy spinors to antiparticles, ceases to hold for the Kogut-Susskind time derivative. To show this we highlight the role of the spinorial ``energy'' in the Osterwalder-Schrader reconstruction of the Fock space of non-interacting lattice fermions at zero temperature and nonzero chemical potential. We consider Kogut-Susskind fermions and, for comparison, fermions with an asymmetric one-step time derivative.Comment: 14p

Complex Numbers, Quantum Mechanics and the Beginning of Time

A basic problem in quantizing a field in curved space is the decomposition of the classical modes in positive and negative frequency. The decomposition is equivalent to a choice of a complex structure in the space of classical solutions. In our construction the real tunneling geometries provide the link between the this complex structure and analytic properties of the classical solutions in a Riemannian section of space. This is related to the Osterwalder- Schrader approach to Euclidean field theory.Comment: 27 pages LATEX, UCSBTH-93-0

AdS/CFT correspondence in the Euclidean context

We study two possible prescriptions for AdS/CFT correspondence by means of functional integrals. The considerations are non-perturbative and reveal certain divergencies which turn out to be harmless, in the sense that reflection-positivity and conformal invariance are not destroyed.Comment: 20 pages, references and two remarks adde