Risikoanalyse durch eine wirkungsbezogenen Analytik mit der instrumentellen Hochleistungs-Dünnschichtchromatographie in der Lebensmittelüberwachung

Zusammenfassung.: Als wirkungsbezogene Analytik wird die Kopplung von biochemischen bzw. biologischen Testverfahren an chemisch/physikalische oder chromatographische Verfahren bezeichnet. So lassen sich mittels der Dünnschichtchromatographie die aufgetrennten Komponenten direkt auf dem Chromatogramm physikalisch-chemisch detektieren und quantifizieren. Durch die Kopplung von biochemischen (z.B. enzymatischen Hemmtests) oder biologischen Testverfahren können toxikologisch wirksame Substanzen in situ nachgewiesen werden. Mit diesen biologischen Testsystemen können - direkt auf dem Chromatogramm auf der Dünnschichtplatte - Fungizide, Antibiotika und Lumnineszenz-Hemmstoffen nachgewiesen werden; ein neues molekularbiologisches Testverfahren ermöglicht den qualitativen und quantitativen Nachweis von Hormonen. Mit biochemischen und biologischen Detektionsverfahren können Wirkstoffe in Lebensmittelproben sowie bei der Reinheitskontrolle und in der Metabolismusforschung von Chemikalien nachgewiesen werden. Außerdem können die detektierten Wirkstoffe durch ihre Migrationsstrecke und ihr UV-Spektrum charakterisiert oder auch identifiziert werden. Pflanzliche Lebensmittel wurden mit der wirkungsbezogenen Analytik auf die Gegenwart von Pestiziden hin untersucht. Biochemische und biologische Detektionsverfahren auf dem Dünnschichtchromatogramm sind sehr selektiv und sensitiv und schließen damit die Lücke zwischen biologischen in vitro-Testverfahren und instrumenteller Analytik. Die Detektion von Wirkungsäquivalenten ist als Screening-Verfahren zunächst unabhängig von Referenzsubstanzen. Neben verschiedenen Testverfahren wird ein Konzept zur Risikoanalyse und Risikobewertung vorgestellt, bei dem die wirkungsbezogene Analytik als Bindeglied zwischen Biotests und chemisch/physikalischen Analytik- und Identifizierungsverfahren fungier

Color Confinement and Massive Gluons

Color confinement is one of the central issues in QCD so that there are various interpretations of this feature. In this paper we have adopted the interpretation that colored particles are not subject to observation just because colored states are unphysical in the sense of Eq. (2.16). It is shown that there are two phases in QCD distinguished by different choices of the gauge parameter. In one phase, called the "confinement phase", color confinement is realized and gluons turn out to be massive. In the other phase, called the "deconfinement phase", color confinement is not realized, but the gluons remain massless.Comment: 14 page

Analytic Approach to Perturbative QCD

The two-loop invariant (running) coupling of QCD is written in terms of the Lambert W function. The analyticity structure of the coupling in the complex Q^2-plane is established. The corresponding analytic coupling is reconstructed via a dispersion relation. We also consider some other approximations to the QCD beta-function, when the corresponding couplings are solved in terms of the Lambert function. The Landau gauge gluon propagator has been considered in the renormalization group invariant analytic approach (IAA). It is shown that there is a nonperturbative ambiguity in determination of the anomalous dimension function of the gluon field. Several analytic solutions for the propagator at the one-loop order are constructed. Properties of the obtained analytical solutions are discussed.Comment: Latex-file, 19 pages, 2 tables, 51 references, to be published in Int. J. Mod. Phys.

Wilsonian Matching of Effective Field Theory with Underlying QCD

We propose a novel way of matching effective field theory with the underlying QCD in the sense of a Wilsonian renormalization group equation (RGE). We derive Wilsonian matching conditions between current correlators obtained by the operator product expansion in QCD and those by the hidden local symmetry (HLS) model. This determines without much ambiguity the bare parameters of the HLS at the cutoff scale in terms of the QCD parameters. Physical quantities for the pi and rho system are calculated by the Wilsonian RGE's from the bare parameters in remarkable agreement with the experiment.Comment: 13 pages, 4 figures, Minor corrections. This is the version to appear in Physical Review

Quarkonia in Hamiltonian Light-Front QCD

A constituent parton picture of hadrons with logarithmic confinement naturally arises in weak coupling light-front QCD. Confinement provides a mass gap that allows the constituent picture to emerge. The effective renormalized Hamiltonian is computed to ${\cal O}(g^2)$, and used to study charmonium and bottomonium. Radial and angular excitations can be used to fix the coupling $\alpha$, the quark mass $M$, and the cutoff $\Lambda$. The resultant hyperfine structure is very close to experiment.Comment: 9 pages, 1 latex figure included in the text. Published version (much more reader-friendly); corrected error in self-energ

On the infrared freezing of perturbative QCD in the Minkowskian region

The infrared freezing of observables is known to hold at fixed orders of perturbative QCD if the Minkowskian quantities are defined through the analytic continuation from the Euclidean region. In a recent paper [1] it is claimed that infrared freezing can be proved also for Borel resummed all-orders quantities in perturbative QCD. In the present paper we obtain the Minkowskian quantities by the analytic continuation of the all-orders Euclidean amplitudes expressed in terms of the inverse Mellin transform of the corresponding Borel functions [2]. Our result shows that if the principle of analytic continuation is preserved in Borel-type resummations, the Minkowskian quantities exhibit a divergent increase in the infrared regime, which contradicts the claim made in [1]. We discuss the arguments given in [1] and show that the special redefinition of Borel summation at low energies adopted there does not reproduce the lowest order result obtained by analytic continuation.Comment: 19 pages, 1 figur

Glueballs in a Hamiltonian Light-Front Approach to Pure-Glue QCD

We calculate a renormalized Hamiltonian for pure-glue QCD and diagonalize it. The renormalization procedure is designed to produce a Hamiltonian that will yield physical states that rapidly converge in an expansion in free-particle Fock-space sectors. To make this possible, we use light-front field theory to isolate vacuum effects, and we place a smooth cutoff on the Hamiltonian to force its free-state matrix elements to quickly decrease as the difference of the free masses of the states increases. The cutoff violates a number of physical principles of light-front pure-glue QCD, including Lorentz covariance and gauge covariance. This means that the operators in the Hamiltonian are not required to respect these physical principles. However, by requiring the Hamiltonian to produce cutoff-independent physical quantities and by requiring it to respect the unviolated physical principles of pure-glue QCD, we are able to derive recursion relations that define the Hamiltonian to all orders in perturbation theory in terms of the running coupling. We approximate all physical states as two-gluon states, and use our recursion relations to calculate to second order the part of the Hamiltonian that is required to compute the spectrum. We diagonalize the Hamiltonian using basis-function expansions for the gluons' color, spin, and momentum degrees of freedom. We examine the sensitivity of our results to the cutoff and use them to analyze the nonperturbative scale dependence of the coupling. We investigate the effect of the dynamical rotational symmetry of light-front field theory on the rotational degeneracies of the spectrum and compare the spectrum to recent lattice results. Finally, we examine our wave functions and analyze the various sources of error in our calculation.Comment: 75 pages, 17 figures, 1 tabl

Superlattice ultrasonic generation

We report the first experimental evidence for the resonant excitation of coherent high-frequency acoustic phonons in semiconducting doping superstructures by far-infrared laser radiation. After a grating-coupled delta-doped silicon doping superlattice is illuminated with ~1 kW/mm2 nanosecond-pulsed 246 GHz laser radiation, a delayed nanosecond pulse is detected by a superconducting bolometer at a time corresponding to the appropriate time-of-flight for ballistic longitudinal acoustic phonons across the (100) silicon substrate. The absorbed phonon power density in the microbolometer is observed to be ~10 μW/mm2, in agreement with theory. The phonon pulse duration also matches the laser pulse duration. The absence of any delayed transverse acoustic phonon signal by the superconducting bolometer is particularly striking and implies there is little or no incoherent phonon generation occurring in the process

Bulk fields with general brane kinetic terms

We analyse the effect of general brane kinetic terms for bulk scalars, fermions and gauge bosons in theories with extra dimensions, with and without supersymmetry. We find in particular a singular behaviour when these terms contain derivatives orthogonal to the brane. This is brought about by $\delta(0)$ divergences arising at second and higher order in perturbation theory. We argue that this behaviour can be smoothed down by classical renormalization.Comment: 31 pages, v2 few typos correcte

The anomalous threshold, confinement, and an essential singularity in the heavy-light form factor

The analytic behavior of the heavy-light meson form factor is investigated using several relativistic examples including unconfined, weakly confined, and strongly confined mesons. It is observed that confinement erases the anomalous threshold singularity and also induces an essential singularity at the normal annihilation threshold. In the weak confinement limit, the "would be" anomalous threshold contribution is identical to that of the real singularity on its space-like side.Comment: Latex 2.09 with epsf.sty. 24 pages of text and 8 postscript figures. Postscript version of complete paper will also be available soon at http://phenom.physics.wisc.edu/pub/preprints/1997/madph-97-983 or at ftp://phenom.physics.wisc.edu/pub/preprints/1997/madph-97-98