Interregional input-ouptut system for Ecuador, 2007: methodology and results

In this paper, we explore the structural characteristics of the interregional input-output system developed for Ecuador for the year 2007. As part of an ongoing project that aims to develop an interregional CGE model for the country, this database was developed under conditions of limited information. It provides the opportunity to better understand the spatial linkage structure associated with the national economy in the context of its 22 provinces, 15 sectors and 60 different products. This exploratory analysis is based on the description of structural coefficients and the use of traditional input-output techniques. Finally, we further explore the spatial linkage structure by looking at the regional decomposition of final demand. It is hoped that this exercise might result in a better appreciation of a broader set of dimensions that might improve our understanding of the integrated interregional economic system in Ecuador.Interregional input-output model; Ecuador; spatial linkages

Improving the functional properties of (K0.5Na0.5)NbO3 piezoceramics by acceptor doping

ZrO2 and TiO2 modified lead-free (K0.5Na0.5)NbO3 (KNN) piezoelectric ceramics are prepared by a conventional solid-state reaction. The effect of acceptor doping on structural and functional properties is investigated. A decrease in the Curie temperature and an increase in the dielectric constant values are observed when doping. More interestingly, an increase in the coercive field E-c and remanent polarization P-r is observed. The piezoelectric properties are greatly increased when doping with small concentrations dopants. ZrO2 doped ceramic exhibits good piezoelectric properties with piezoelectric coefficient d(33) = 134 pC/N and electromechanical coupling factor k(p) = 35%. It is verified that nonlinearity is significantly reduced. Thus, the creation of complex defects capable of pinning the domain wall motion is enhanced with doping, probably due to the formation of oxygen vacancies. These results strongly suggest that compositional engineering using low concentrations of acceptor doping is a good means of improving the functional properties of KNN lead-free piezoceramic system. (C) 2014 Elsevier Ltd. All rights reserved.Postprint (published version

Tuning the microstructure of flash sintered BZT-BCT ceramics to obtain enhanced and singular properties

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Low temperature dielectric relaxation in ordinary perovskite ferroelectrics: enlightenment from high-energy x-ray diffraction

Ordinary ferroelectrics exhibit a second order phase transition that is characterized by a sharp peak in the dielectric permittivity at a frequency-independent temperature. Furthermore, these materials show a low temperature dielectric relaxation that appears to be a common behavior of perovskite systems. Tetragonal lead zirconate titanate is used here as a model system in order to explore the origin of such an anomaly, since there is no consensus about the physical phenomenon involved in it. Crystallographic and domain structure studies are performed from temperature dependent synchrotron x-ray diffraction measurement. Results indicate that the dielectric relaxation cannot be associated with crystallographic or domain configuration changes. The relaxation process is then parameterized by using the Vogel–Fulcher–Tammann phenomenological equation. Results allow us to hypothesize that the observed phenomenon is due to changes in the dynamic behavior of the ferroelectric domains related to the fluctuation of the local polarization.Postprint (author's final draft

Preisach modelling of nonlinear response in electrically biased lead zirconate titanate-based piezoceramics

The alteration of the high-field electrical permittivity (nonlinear response) of PZT-based ceramics when an electrical bias field is applied is reported in this work. Large differences are observed between soft and hard PZT behaviours. While in soft PZT a bias field does not modify the nonlinear behaviour, a notable dependence is verified in hard PZT. The Preisach model is satisfactorily used to describe experimental results. A distribution function containing the first terms of the Maclaurin development series of a function composed by two Gaussian-like functions of different amplitudes is proposed. The model gives a satisfactory explanation for the fact that the permittivity depends not only on the amplitude of the applied electric field, but also on the bias field, both for soft and hard ceramics and for poled or unpoled samples.Postprint (published version

Elastic, dielectric and electromechanical properties of (Bi0.5Na0.5)TiO3-BaTiO3 piezoceramics at the morphotropic phase boundary region

A systematic study of the functional properties of the (1-x)(Bi0.5Na0.5)TiO3–xBaTiO3 (BNT-xBT) piezoceramic system for 0.05 = x = 0.07 is performed. The samples are obtained through the conventional solid-state route. The expected microstructure for these compounds, with no significant dependence on the composition, is verified by field-emission scanning electron microscopy. The morphotropic phase boundary (MPB) is detected for x = 0.06–0.07 by means of the Rietveld analysis of X-ray diffraction data. The dielectric spectra show a frequency-independent, completely diffuse phase transition with a composition-dependent diffusivity coefficient. The depolarization temperature is effectively evaluated from pyroelectric measurements, the value being strongly dependent on the composition. A significant contribution of the extrinsic effect to elastic, dielectric and electromechanical properties is revealed for MPB BNT-xBT. The Bi3+ substitution by Ba2+ leads to the formation of A-site vacancies, which give rise to the enhancement of domain wall motion, as occurs in other perovskite-type piezoelectrics. Good functional properties are achieved for x = 0.07 (d33 = 180 pC/N), which are similar or even better than those obtained by complex synthesis routes. This system exhibits a remarkable stability in the permittivity that has hitherto not been reported. This fact may open the way for BNT-BT compositions to be used in specific applications in which lead-free piezoceramics have previously been employed with little success, e.g. in high power devices.Postprint (author's final draft

High-precision time-of-flight determination algorithm for ultrasonic flow measurement

© 2019 IEEE. Personal use of this material is permitted. Permission from IEEE must be obtained for all other uses, in any current or future media, including reprinting/republishing this material for advertising or promotional purposes,creating new collective works, for resale or redistribution to servers or lists, or reuse of any copyrighted component of this work in other works.Commercial time-of-flight (TOF) ultrasonic flowme- ters are rapidly expanding in the general industry. Among the different techniques that can be applied to determine the TOF of ultrasonic waves, the cross-correlation method presents numerous advantages, such as robustness for weak signals and noise suppression. However, the selection of an appropriate reference wave is presumably a key element in the precise measurement of TOF. In the present paper, an algorithm to compute an accurate TOF is proposed. The form of the electric signal received by the transducer is obtained from an acoustically-forced underdamped oscillator model, and the analytical solution of the model is proposed as a reference wave. In order to validate the effectiveness of this procedure, an ultrasonic flowmeter system is designed and tested in a flowmeter calibration test rig. It is demonstrated that the use of the presented scheme overcome the average method limitations, and turns out to be a convenient solution in a wide range of conditions. Robust measurements of near-zero flow values are acquired, which allow the achievement of a high dynamic range. The error curve of the proposed system have been obtained, revealing that the absolute value of the relative errors are lower than 2% within all the spectrum of flow rates considered (from 0.2 to 150 m 3 /h). Results demonstrate that the algorithm provides high-precision measurements within a wide dynamic range. The algorithm is portable and versatile: it can be adapted to different types of transducers without the need of additional measurements, allowing to adjust parameters on-the-fly for an optimal performance of the ultrasonic flowmeter system.Peer ReviewedPostprint (author's final draft

Microstructure and Defect Formation in BaTiO3 Ceramics Obtained by Flash Sintering of Micro and Nanopowders

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Influence of extrinsic contribution on the macroscopic properties of hard and soft lead zirconate titanate ceramics

In this work, the contribution of the extrinsic effect to the macroscopic properties in soft and hard lead zirconate titanate ceramics is directly evaluated. Close to the room temperature, poled hard ceramics show an anomalous behavior, which is notably different from that of soft ceramics, not only in dielectric but also in piezoelectric and elastic responses. Hence, at room temperature their properties are thermally stable and the losses are unusually low. It is suggested that two mechanisms are present, with one mechanism inhibiting the other.Peer ReviewedPostprint (published version

Insight into the dynamics of low temperature dielectric relaxation of ordinary perovskite ferroelectrics

The temperature dependence of the dielectric response of ordinary ferroelectric materials exhibits a frequency-independent anomalous peak as a manifestation of the ferroelectric to paraelectric phase transition. A second anomaly in the permittivity has been reported in different ferroelectric perovskite-type systems at low temperatures, often at cryogenic temperatures. This anomaly manifests as a frequency-dependent local maximum, which exhibits similar characteristics to that observed in relaxor ferroelectrics around their phase transition. The origin of this unexpected behavior is still controversial. In order to clarify this phenomenon, a model-free route solution is developed in this work. Our findings reveal the same critical linear pattern/glass-like freezing behavior previously observed for glass-forming systems. Contrary to current thought, our results suggest that a critical-like dynamic parameterization could provide a more appropriate solution than the conventional Vogel–Fulcher–Tammann equation. The implemented methodology may open a new pathway for analyzing relaxation phenomena in other functional materials like relaxor ferroics.Postprint (published version