Regional Control Over Compliance with the Requirements of the Legislation of the Russian Federation in the Field of Children’s Recreation and Health

This article discusses issues related to the emergence of a new type of control from January 1, 2017, namely, regional control over compliance with the requirements of the legislation of the Russian Federation in the field of organization of recreation and rehabilitation of children. The subjects of control are identified. It is noted that the lack of a clear wording of the subject of control impedes the effective implementation of the activities of its entities and creates the possibility of double control of children's recreation organizations and their recovery by officials of various public authorities. The author formulated a proposal to eliminate a gap in the legislation related to the absence of a Code of the Russian Federation on Administrative Offense, which provides for administrative liability for violation of the requirements of the legislation of the Russian Federation in the field of organization of recreation and recreation for children

Alkoxy compounds - XXIII. Synthesis, properties, PMR spectra, and stereochemistry of 2-alkyl-2-alkoxymethyl-1, 3-propanediols and 2, 2, 5-trialkyl-5-alkoxymethyl-1,3-dioxanes

The reduction of alkoxymethylalkylmalonic esters with lithium aluminum hydride has given previously unknown 2-alkyl-2-alkoxymethyl-1, 3-propanediols, and by the condensation of these with ketones six previously unreported 2, 2, 5-trialkyl-5-alkoxymethyl-1, 3-dioxanes have been synthesized. The PMR spectra of these compounds have been studied and the unsymmetrical boat conformation has been shown for the 2, 2, 5-trialkyl-5-alkoxymethyl-1, 3-dioxanes. The causes of the stereochemical features of the compounds mentioned are discussed. © 1971 Consultants Bureau

Alkoxy compounds - XXI. Synthesis, configuration, and conformation of some 5-alkoxymethyl-2,5-dialkyl-1,3-dioxanes

Twenty-six previously unreported 5-alkoxymethyl-2,5-dialkyl-1,3-dioxanes have been synthesized by the condensation of 2-alkoxymethyl-2-alkylpropane-1,3-diols with aldehydes. It has been shown by an analysis of the PMR spectra of these dioxanes that the 1,3-dioxanes considered are mixtures of two stereoisomers. In some cases these mixtures have been resolved into the individual isomers by vacuum fractionation in efficient columns. The configurations and conformations of the stereoisomeric 5-alkoxymethyl-2,5-dialkyl-1,3-dioxanes have been established by the NMR method; it has been shown that the lower-boiling isomers have the trans configuration and predominantly the chair conformation and the higherboiling isomers the cis configuration and predominantly an unsymmetrical boat conformation. © 1970 The Faraday Press, Inc

ЕФЕКТИВНІСТЬ ПЛАСТИНЧАТИХ ТЕПЛОУТИЛІЗАТОРІВ ТЕПЛОУТИЛІЗАЦІЙНИХ СИСТЕМ

The development and application of modern integrated methods for studying the efficiency of heat recovery systems and their individual elements enables ensuring their maximum efficiency. These methods are based on a combination of methods of exergic analysis with statistical methods of experiment planning, methods of the theory of linear systems, thermodynamics of irreversible processes, etc. A method is developed for calculating the losses of exergic power in heat conduction processes for a gas-air plate heat exchanger. Losses of exergic power occur when heat is transferred through the cross-section of the heat recovery plate. The methodology is based on a complex approach combining exergy methods with methods of thermodynamics of irreversible processes. The mathematical model of the investigated processes includes the exergy equation, the balance equation of exergy and entropy, the equation of continuity, the equation of phase motion, the energy equation, the balance equation for enthalpies, the Gibbs equation and the heat equation for boundary conditions of the third kind for an unbounded plate. A plate of a gas-air plate heat exchanger was modelled as an unlimited plate thickness. When obtaining formulas for calculating the losses of exergic power, the local differential equation of the exergy balance obtained earlier was used. In this equation, one of the terms determines the losses of exergy power, which are caused by the irreversibility of the processes. Such losses are related to thermal conductivity, phase viscosity, phase-to-phase heat transfer and friction between phases. On the basis of this equation and the solution of the heat equation under boundary conditions of the third kind, formulas are obtained for calculating the losses of exergy power. Calculations of total losses of exergic power in a gas-air plate heat exchanger and losses of exergic power in heat conduction processes under various operating conditions of the boiler are performed. It is established that losses of exergic power in heat conduction processes in a gas-air plate heat exchanger make up 8.6-11.6 % of the total losses of exergy power and depend on the operating mode of the boiler. Changing in the necessary direction the thermophysical characteristics of the gas-air plate heat exchanger, it is possible to reduce the loss of exergy power.Розроблено методику розрахунку втрат ексергетичної потужності у процесах теплопровідності під час передачі теплоти через поперечний переріз пластини газоповітряного пластинчастого теплоутилізатора за граничних умов третього роду. Методику засновано на комплексному підході, що поєднує ексергетичні методи з методами термодинаміки незворотних процесів. Математична модель досліджуваних процесів включає рівняння ексергії, рівняння балансу ексергії та ентропії, рівняння нерозривності трифазної термодинамічної системи при зміні концентрації однієї з фаз, рівняння руху фаз, рівняння енергій, рівняння балансу ентальпій, рівняння Гіббса і рівняння теплопровідності за граничних умов третього роду. Для отримання формул для розрахунку втрат ексергетичної потужності використано локальне диференціальне рівняння балансу ексергії. У цьому рівнянні одна зі складових визначає втрати ексергетичної потужності, зумовлені незворотністю процесів і пов'язані з теплопровідністю, в'язкістю фаз, міжфазним теплообміном і тертям між фазами. На підставі цього рівняння і рішення рівняння теплопровідності за граничних умов третього роду для необмеженої пластини, якою моделювалася пластина газоповітряного пластинчастого теплоутилізатора, отримано формули для розрахунку втрат ексергетичної потужності. Виконано розрахунки загальних втрат ексергетичної потужності в газоповітряному пластинчастому теплоутилізаторі за різних режимів роботи котла і втрат ексергетичної потужності у процесах теплопровідності. Встановлено, що втрати ексергетичної потужності у процесах теплопровідності в газоповітряному пластинчатому теплоутилізаторі становлять 8,6-11,6 % від загальних втрат ексергетичної потужності і залежать від режиму роботи котла

The Challenge of Machine Learning in Space Weather Nowcasting and Forecasting

The numerous recent breakthroughs in machine learning (ML) make imperative to carefully ponder how the scientific community can benefit from a technology that, although not necessarily new, is today living its golden age. This Grand Challenge review paper is focused on the present and future role of machine learning in space weather. The purpose is twofold. On one hand, we will discuss previous works that use ML for space weather forecasting, focusing in particular on the few areas that have seen most activity: the forecasting of geomagnetic indices, of relativistic electrons at geosynchronous orbits, of solar flares occurrence, of coronal mass ejection propagation time, and of solar wind speed. On the other hand, this paper serves as a gentle introduction to the field of machine learning tailored to the space weather community and as a pointer to a number of open challenges that we believe the community should undertake in the next decade. The recurring themes throughout the review are the need to shift our forecasting paradigm to a probabilistic approach focused on the reliable assessment of uncertainties, and the combination of physics-based and machine learning approaches, known as gray-box.Comment: under revie

THE RESEARCH OF POLETAEVSK FIELD KAOLIN FOR THE PRODUCTION OF FIRECLAY

The work was defined material, chemical and grain structure and properties of kaolin Poletaevsk field. Sinterability investigated different fractions of kaolin in pure form and its influence on the property of sintered kaolin various additives. The optimum temperature sintering kaolin fireclay on different brands.В работе определены вещественный, химический и зерновой состав и свойства каолина Полетаевского месторождения. Исследована спекаемость разных фракций каолина в чистом виде и влияние на свойства спеченного каолина различных добавок. Определены оптимальные температуры спекания каолина на шамот разных марок

Features of structural ordering and magnetic properties of the cobalt intercalates of titanium dichalcogenides

CoxTiS2 (x = 0.20, 0.30, 0.50, 0.75) compounds have a layered crystal structure with Ti atoms surrounded by the S octahedrons in the S-Ti-S layers and Co ions which could be surrounded both by the S octahedrons and tetrahedrons. The features of the crystal structure and magnetic properties of the polycrystalline CoxTiS2 samples were studied as a function of the cobalt concentration using X-ray diffraction and magnetization measurements. The disordered state of the Co atoms (x < 0.20) changes to the ordered one (x ≥ 0.20). The magnetic ordering arises at x = 0.20 with mostly antiferromagnetic interaction. For compound with x = 0.30 and 0.50 there is a weak ferromagnetic ordering. The ferromagnetic ordering is observed in Co0.75TiS2 below Tc = 375 K. © 2023, S.C. Virtual Company of Phisics S.R.L. All rights reserved.Russian Science Foundation, RSF: 22-72-00094The study was supported by the Russian Scientific Foundation (grant № 22-72-00094)

Development of the technology of obtaining highly pure powder AL2O3 on the basis of raw material of the Ural region

The process of granulation of kaolin of the Ural deposit was carried out in the work. Firing the resulting balls. Grinding after firing. Sulfuric acid leaching of raw materials at different concentrations of acid and time. Preparation of sediment.В работе был выполнен анализ процесса гранулирования каолина уральского месторождение. Также были исследованы технологии обжиг, помола полученных шариков. Рассмотрен процесс сернокислотного выщелачивания сырья при разных концентрациях кислоты и времени и получение осадка