Latest Triassic climate humidification and kaolinite formation (Western Carpathians, Tatric Unit of the Tatra Mts.)

The Tomanová Formation, of Rhaetian age, overlying the Norian Carpathian Keuper in the Tatra Mts. is built of cyclic parasequences of mudstones and sandstones. Quartz (15 to 70 wt.%), kaolinite (13 to 46 wt.%) and 2:1 Al dioctahedral phyllosilicates (dioct 2:1: muscovite, illite, illite/smectite: 5 to 39 wt.%) represent the major mineral phase. The kaolinite/dioct 2:1 ratio decreases upwards in the section (from 4.3 to 0.5) and signals variability in weathering/erosion intensity and changing water salinity. Major and trace elements (LILE, HSFS, REE) indicate a uniform source – felsic rocks located probably in the Vindelician Highlands. The sedimentation rate (83 mm/ky) was controlled by climate. Alternation of dry and humid periods is refered by sedimentary textures and by maturity of quartz (aeolian vs. fluvial grains), and organic matter content and composition (Corg and d13Corg). Authigenic siderite or bethierine documents wet and reduced conditions in the upper part of the Tomanová Formation. The sedimention rate of the marine Dudzinec Formation attained 25 mm/ka and the character of cycles preserved in the sequence is similar as that of the Tomanová Formation (fining upwards parasequences). However, the different clay mineralogy, the recycled character of the silicates, the different d13Corg and elevated imput of carbonate detritus with specific C and O isotopic patterns document a discontinuity in the section. The transgressive character of the Dudzinec Fm. was deduced from the stratigraphic distribution and environmental characteristics of the benthic foraminifera present. Involutinids and spirillinids dominate in the lower part, endothyrinids govern the middle part, and in the upper part nodosariids and Ammodiscus-type microfauna occur. These age-diagnostic microfossils indicate a late Rhaetian age. Sea level rise in the Tatric Zone triggered by thermal expansion of the Central Atlantic Rift was gradual, being affected by input of terrestrial clastic sediment both by freshwater and by wind. The Tatric Triassic sequence in the Western Carpathians helps understanding of the development of sedimentation, palaeoclimate (kaolinite weathering), and palaeogeography of the northernmost Tethyan Domain

Double-exponential decay of orientational correlations in semiflexible polyelectrolytes

In this paper we revisited the problem of persistence length of polyelectrolytes. We performed a series of Molecular Dynamics simulations using the Debye-Hückel approximation for electrostatics to test several equations which go beyond the classical description of Odijk, Skolnick and Fixman (OSF). The data confirm earlier observations that in the limit of large contour separations the decay of orientational correlations can be described by a single-exponential function and the decay length can be described by the OSF relation. However, at short countour separations the behaviour is more complex. Recent equations which introduce more complicated expressions and an additional length scale could describe the results very well on both the short and the long length scale. The equation of Manghi and Netz when used without adjustable parameters could capture the qualitative trend but deviated in a quantitative comparison. Better quantitative agreement within the estimated error could be obtained using three equations with one adjustable parameter: 1) the equation of Manghi and Netz; 2) the equation proposed by us in this paper; 3) the equation proposed by Cannavacciuolo and Pedersen. Two characteristic length scales can be identified in the data: the intrinsic or bare persistence length and the electrostatic persistence length. All three equations use a single parameter to describe a smooth crossover from the short-range behaviour dominated by the intrinsic stiffness of the chain to the long-range OSF-like behaviour