235 research outputs found
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Normally-off GaN transistors for power applications
Normally-off high voltage GaN-HFETs for switching applications are presented. Normally-off operation with threshold voltages of 1 V and more and with 5 V gate swing has been obtained by using p-type GaN as gate. Different GaN-based buffer types using doping and backside potential barriers have been used to obtain blocking strengths up to 1000 V. The increase of the dynamic on-state resistance is analyzed for the different buffer types. The best trade-off between low dispersion and high blocking strength was obtained for a modified carbon-doped GaN-buffer that showed a 2.6x increase of the dynamic on-state resistance for 500 V switching as compared to switching from 20 V off-state drain bias. Device operation up to 200 °C ambient temperature without any threshold voltage shift is demonstrated
The metallic state in disordered quasi-one-dimensional conductors
The unusual metallic state in conjugated polymers and single-walled carbon
nanotubes is studied by dielectric spectroscopy (8--600 GHz). We have found an
intriguing correlation between scattering time and plasma frequency. This
relation excludes percolation models of the metallic state. Instead, the
carrier dynamics can be understood in terms of the low density of delocalized
states around the Fermi level, which arises from the competion between
disorder-induced localization and interchain-interactions-induced
delocalization.Comment: 4 pages including 4 figure
Convection in colloidal suspensions with particle-concentration-dependent viscosity
The onset of thermal convection in a horizontal layer of a colloidal
suspension is investigated in terms of a continuum model for binary-fluid
mixtures where the viscosity depends on the local concentration of colloidal
particles. With an increasing difference between the viscosity at the warmer
and the colder boundary the threshold of convection is reduced in the range of
positive values of the separation ratio psi with the onset of stationary
convection as well as in the range of negative values of psi with an
oscillatory Hopf bifurcation. Additionally the convection rolls are shifted
downwards with respect to the center of the horizontal layer for stationary
convection (psi>0) and upwards for the Hopf bifurcation (psi<0).Comment: 8 pages, 6 figures, submitted to European Physical Journal
Localized and Delocalized Charge Transport in Single-Wall Carbon-Nanotube Mats
We measured the complex dielectric constant in mats of single-wall
carbon-nanotubes between 2.7 K and 300 K up to 0.5 THz. The data are well
understood in a Drude approach with a negligible temperature dependence of the
plasma frequency (omega_p) and scattering time (tau) with an additional
contribution of localized charges. The dielectric properties resemble those of
the best ''metallic'' polypyrroles and polyanilines. The absence of metallic
islands makes the mats a relevant piece in the puzzle of the interpretation of
tau and omega_p in these polymers.Comment: 4 pages including 4 figure
Magnetic phases and reorientation transitions in antiferromagnetically coupled multilayers
In antiferromagnetically coupled superlattices grown on (001) faces of cubic
substrates, e.g. based on materials combinations as Co/Cu, Fe/Si, Co/Cr, or
Fe/Cr, the magnetic states evolve under competing influence of bilinear and
biquadratic exchange interactions, surface-enhanced four-fold in-plane
anisotropy, and specific finite-size effects. Using phenomenological
(micromagnetic) theory, a comprehensive survey of the magnetic states and
reorientation transitions has been carried out for multilayer systems with even
number of ferromagnetic sub-layers and magnetizations in the plane. In
two-layer systems (N=2) the phase diagrams in dependence on components of the
applied field in the plane include ``swallow-tail'' type regions of
(metastable) multistate co-existence and a number of continuous and
discontinuous reorientation transitions induced by radial and transversal
components of the applied field. In multilayers (N \ge 4) noncollinear states
are spatially inhomogeneous with magnetization varying across the multilayer
stack. For weak four-fold anisotropy the magnetic states under influence of an
applied field evolve by a complex continuous reorientation into the saturated
state. At higher anisotropy they transform into various inhomogeneous and
asymmetric structures. The discontinuous transitions between the magnetic
states in these two-layers and multilayers are characterized by broad ranges of
multi-phase coexistence of the (metastable) states and give rise to specific
transitional domain structures.Comment: Manuscript 34 pages, 14 figures; submitted for publicatio
On the move: New insights on the ecology and management of native and alien macrophytes
Globally, freshwater ecosystems are under threat. The main threats come from catchment land-use changes, altered water regimes, eutrophication, invasive species, climate change and combinations of these factors. We need scientific research to respond to these challenges by providing solutions to halt the deterioration and improve the condition of our valuable freshwaters. This requires a good understanding of aquatic ecosystems, and the nature and scale of changes occurring. Macrophytes play a fundamental role in aquatic systems. They are sensitive indicators of ecosystem health, as they are affected by run-off from agricultural, industrial or urban areas. On the other hand, alien macrophytes are increasingly invading aquatic systems all over the world. Improving our knowledge on the ecology and management of both native and alien plants is indispensable to address threats to freshwaters in order to protect and restore aquatic habitats. The International Aquatic Plants Group (IAPG) brings together scientists and practitioners based at universities, research and environmental organisations around the world. The main themes of the 15th symposium 2018 in New Zealand were biodiversity and conservation, management, invasive species, and ecosystem response and restoration. This Virtual Special Issue provides a comprehensive review from the symposium, addressing the ecology of native macrophytes, including those of conservation concern, and highly invasive alien macrophytes, and the implications of management interventions. In this editorial paper, we highlight insights and paradigms on the ecology and management of native and alien macrophytes gathered during the meeting
Generation of ribosome imprinted polymers for sensitive detection of translational responses
Whilst the profiling of the transcriptome and proteome even of single-cells becomes feasible, the analysis of the translatome, which refers to all messenger RNAs (mRNAs) engaged with ribosomes for protein synthesis, is still an elaborate procedure requiring millions of cells. Herein, we report the generation and use of “smart materials”, namely molecularly imprinted polymers (MIPs) to facilitate the isolation of ribosomes and translated mRNAs from merely 1,000 cells. In particular, we show that a hydrogel-based ribosome imprinted polymer could recover ribosomes and associated mRNAs from human, simian and mice cellular extracts, but did not selectively enrich yeast ribosomes, thereby demonstrating selectivity. Furthermore, ribosome imprinted polymers enabled the sensitive measurement of an mRNA translational regulatory event, requiring 1,000-fold less cells than current methodologies. These results provide first evidence for the suitability of MIPs to selectively recover ribonucleoprotein complexes such as ribosomes, founding a novel means for sensitive detection of gene regulation
Regioisomeric and substituent effects upon the outcome of the reaction of 1-borodienes with nitrosoarene compounds
A study of the reactivity of 1-borodienes with nitrosoarene compounds has been carried out showing an outcome that differs according to the hybridization state of the boron moiety. Using an sp2 boron substituent, a one-pot hetero-Diels–Alder/ring contraction cascade occurred to afford N-arylpyrroles with low to good yields depending on the electronic properties of the substituents on the borodiene, whereas an sp3 boron substituent led to the formation of stable boro-oxazines with high regioselectivity in most of the cases, in moderate to good yields. 1H and 11B NMR studies on two boro-oxazine regioisomers showed that selective deprotection can be performed. Formation of either the pyrrole or the furan derivative is pH- and regioisomer-structure-dependent. The results obtained, together with previous B3LYP calculations, support mechanistic proposals which suggest that pyrrole, or furan, formation proceeds via oxazine formation, followed by a boryl rearrangement and an intramolecular addition–elimination sequence
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