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Big Data and the Transformation of Operations Models: A Framework and A New Research Agenda
Big Data has been hailed as the ‘next big thing’ to drive business value, transform organisations and industries, and “reveal secrets to those with the humility, willingness and tools to listen” (Mayer-Schönberger and Cukier, 2013: 5). However, despite growing interest from organisations across industry sectors, Big Data applications appear to have concentrated on delivering incremental change and operational efficiency improvements, with little evidence on using Big Data to facilitate strategic, transformational change. In this paper, we explore how Big Data is actually being can be used across different sectors in leading organisations and examine the ways in which it is fostering change in the core operations models of organisations. A definition of ‘operations model’ is developed and the core components dimensions of an operations model are then examined, namely capacity, supply network, process and technology, and people development and organisation. Through a series of case studies, we examine the role of Big Data in affecting some, or all, of these components dimensions in order to generate value for the organisation by optimising, adapting or radically transforming the operations model. Following our analysis, we develop a tentative framework which can be used both for understanding how Big Data affects operations models, and for planning changes in operations models through Big Data. We set out a new research agenda to systematically understand the full potential of Big Data in transforming operations models
Tunable plasmonic resonance of gallium nanoparticles by thermal oxidation at low temperatures
This Accepted Manuscript is available for reuse under a CC BY-NC-ND 3.0 licence after the 12 month embargo period provided that all the terms of the licence are adhered toThe effect of the oxidation of gallium nanoparticles (Ga NPs) on their plasmonic properties is investigated. Discrete dipole approximation has been used to study the wavelength of the out-of-plane localized surface plasmon resonance in hemispherical Ga NPs, deposited on silicon substrates, with oxide shell (Ga2O3) of different thickness. Thermal oxidation treatments, varying temperature and time, were carried out in order to increase experimentally the Ga2O3 shell thickness in the NPs. The optical, structural and chemical properties of the oxidized NPs have been studied by spectroscopic ellipsometry, scanning electron microscopy, grazing incidence x-ray diffraction and x-ray photoelectron spectroscopy. A clear redshift of the peak wavelength is observed, barely affecting the intensity of the plasmon resonance. A controllable increase of the Ga2O3 thickness as a consequence of the thermal annealing is achieved. In addition, simulations together with ellipsometry results have been used to determine the oxidation rate, whose kinetics is governed by a logarithmic dependence. These results support the tunable properties of the plasmon resonance wavelength in Ga NPs by thermal oxidation at low temperatures without significant reduction of the plasmon resonance intensityThis research is supported by the MINECO (CTQ2014-53334-C2-2-R and MAT2016-80394-R) and Comunidad de Madrid (NANOAVANSENS ref. S2013/MIT-3029) projects. ARC acknowledges Ramón y Cajal program (under contract number RYC-2015-18047).
FN acknowledges support from Marie Sklodowska-Curie grant agreement No 641899 from the European Union’s Horizon 2020 research and innovation programm
The role of the oxide shell in the chemical functionalization of plasmonic gallium nanoparticles
S. Catalán-Gómez, M. Briones, A. Redondo-Cubero, F. J. Palomares, F. Nucciarelli, E. Lorenzo, J. L. Pau, "The role of the oxide shell in the chemical functionalization of plasmonic gallium nanoparticles", SPIE Optics + Optoelectronics Proc. SPIE 10231 (16 May 2017); doi: 10.1117/12.2265665; Copyright 2017 Society of Photo‑Optical Instrumentation Engineers. One print or electronic copy may be made for personal use only. Systematic reproduction and distribution, duplication of any material in this paper for a fee or for commercial purposes, or modification of the content of the paper are prohibited.Plasmonic Ga nanoparticles (NPs) were thermally oxidized at low temperature in order to increase the native Ga 2 O 3 shell thickness and to improve their stability during the chemical functionalization. The optical, structural and chemical properties of the oxidized NPs have been studied by spectroscopic ellipsometry, scanning electron microscopy, grazing incidence X-ray diffraction and X-ray photoelectron spectroscopy. A clear redshift of the peak wavelength is observed with the increasing annealing time due to the Ga 2 O 3 thickness increase, and barely affecting the intensity of the plasmon resonance. This oxide layer enhances the stability of the NPs upon immersion in ethanol or water. The surface sensitivity properties of the as-grown and oxidized NPs were investigated by linking a thiol group from 6-Mercapto-1-hexanol through immersion. Ellipsometric spectra at the reversal polarization handedness (RPH) condition are in agreement with the Langmuir absorption model, indicating the formation of a thiol monolayer on the NPs
Size-selective breaking of the core-shell structure of gallium nanoparticles
This Accepted Manuscript is available for reuse under a CC BY-NC-ND 3.0 licence after the 12 month embargo period provided that all the terms of the licence are adhered toCore-shell gallium nanoparticles (Ga NPs) have recently been proposed as an ultraviolet plasmonic material for different applications but only at room temperature. Here, the thermal stability as a function of the size of the NPs is reported over a wide range of temperatures. We analyze the chemical and structural properties of the oxide shell by x-ray photoelectron spectroscopy and atomic force microscopy. We demonstrate the inverse dependence of the shell breaking temperature with the size of the NPs. Spectroscopic ellipsometry is used for tracking the rupture and its mechanism is systematically investigated by scanning electron microscopy, grazing incidence x-ray diffraction and cathodoluminescence. Taking advantage of the thermal stability of the NPs, we perform complete oxidations that lead to homogenous gallium oxide NPs. Thus, this study set the physical limits of Ga NPs to last at high temperatures, and opens up the possibility to achieve totally oxidized NPs while keeping their sphericityThe research is supported by the MINECO (CTQ2014-53334-C2-2-R, CTQ2017-84309-C2-2-R, MAT2016-80394-R, MAT 2015-65274-R/FEDER and MAT2017-85089-C2-1-R) and Comunidad de Madrid (NANOAVANSENS ref. S2013/MIT-3029) projects. ARC acknowledges Ramón y Cajal program (under contract number RYC-2015-18047). FN
acknowledges support from Marie Sklodowska-Curie grant agreement No. 641899 from the European Union´s Horizon 2020 research and innovation programm
L3DAS21 Challenge: Machine Learning for 3D Audio Signal Processing
The L3DAS21 Challenge is aimed at encouraging and fostering collaborative
research on machine learning for 3D audio signal processing, with particular
focus on 3D speech enhancement (SE) and 3D sound localization and detection
(SELD). Alongside with the challenge, we release the L3DAS21 dataset, a 65
hours 3D audio corpus, accompanied with a Python API that facilitates the data
usage and results submission stage. Usually, machine learning approaches to 3D
audio tasks are based on single-perspective Ambisonics recordings or on arrays
of single-capsule microphones. We propose, instead, a novel multichannel audio
configuration based multiple-source and multiple-perspective Ambisonics
recordings, performed with an array of two first-order Ambisonics microphones.
To the best of our knowledge, it is the first time that a dual-mic Ambisonics
configuration is used for these tasks. We provide baseline models and results
for both tasks, obtained with state-of-the-art architectures: FaSNet for SE and
SELDNet for SELD. This report is aimed at providing all needed information to
participate in the L3DAS21 Challenge, illustrating the details of the L3DAS21
dataset, the challenge tasks and the baseline models.Comment: Documentation paper for the L3DAS21 Challenge for IEEE MLSP 2021.
Further information on www.l3das.com/mlsp202
Optical and radio behaviour of the BL Lacertae object 0716+714
Eight optical and four radio observatories have been intensively monitoring
the BL Lac object 0716+714 in the last years: 4854 data points have been
collected in the UBVRI bands since 1994, while radio light curves extend back
to 1978. Many of these data are presented here for the first time. The
long-term trend shown by the optical light curves seems to vary with a
characteristic time scale of about 3.3 years, while a longer period of 5.5-6
years seems to characterize the radio long-term variations. In general, optical
colour indices are only weakly correlated with brightness. The radio flux
behaviour at different frequencies is similar, but the flux variation amplitude
decreases with increasing wavelength. The radio spectral index varies with
brightness (harder when brighter), but the radio fluxes seem to be the sum of
two different-spectrum contributions: a steady base level and a harder-spectrum
variable component. Once the base level is removed, the radio variations appear
as essentially achromatic, similarly to the optical behaviour. Flux variations
at the higher radio frequencies lead the lower-frequency ones with week-month
time scales. The behaviour of the optical and radio light curves is quite
different, the broad radio outbursts not corresponding in time to the faster
optical ones and the cross-correlation analysis indicating only weak
correlation with long time lags. However, minor radio flux enhancements
simultaneous with the major optical flares can be recognized, which may imply
that the mechanism producing the strong flux increases in the optical band also
marginally affects the radio one.Comment: 18 pages, 15 Postscript figures, 5 JPEG figures, accepted for
publication in A&
The correlated optical and radio variability of BL Lacertae. WEBT data analysis 1994-2005
Since 1997, BL Lacertae has undergone a phase of high optical activity, with
the occurrence of several prominent outbursts. Starting from 1999, the Whole
Earth Blazar Telescope (WEBT) consortium has organized various multifrequency
campaigns on this blazar, collecting tens of thousands of data points. One of
the main issues in the study of this huge dataset has been the search for
correlations between the optical and radio flux variations, and for possible
periodicities in the light curves. The analysis of the data assembled during
the first four campaigns (comprising also archival data to cover the period
1968-2003) revealed a fair optical-radio correlation in 1994-2003, with a delay
of the hard radio events of ~100 days. Moreover, various statistical methods
suggested the existence of a radio periodicity of ~8 years. In 2004 the WEBT
started a new campaign to extend the dataset to the most recent observing
seasons, in order to possibly confirm and better understand the previous
results. In this campaign we have collected and assembled about 11000 new
optical observations from twenty telescopes, plus near-IR and radio data at
various frequencies. Here, we perform a correlation analysis on the long-term
R-band and radio light curves. In general, we confirm the ~100-day delay of the
hard radio events with respect to the optical ones, even if longer (~200-300
days) time lags are also found in particular periods. The radio
quasi-periodicity is confirmed too, but the "period" seems to progressively
lengthen from 7.4 to 9.3 years in the last three cycles. The optical and radio
behaviour in the last forty years suggests a scenario where geometric effects
play a major role. In particular, the alternation of enhanced and suppressed
optical activity (accompanied by hard and soft radio events, respectively) canComment: 6 pages, 4 figure
Multi-Epoch Multiwavelength Spectra and Models for Blazar 3C~279
Of the blazars detected by EGRET in GeV gamma rays, 3C 279 is not only the
best-observed by EGRET, but also one of the best-monitored at lower
frequencies. We have assembled eleven spectra, from GHz radio through GeV gamma
rays, from the time intervals of EGRET observations. Although some of the data
have appeared in previous publications, most are new, including data taken
during the high states in early 1999 and early 2000. All of the spectra show
substantial gamma-ray contribution to the total luminosity of the object; in a
high state, the gamma-ray luminosity dominates over that at all other
frequencies by a factor of more than 10. There is no clear pattern of time
correlation; different bands do not always rise and fall together, even in the
optical, X-ray, and gamma-ray bands.
The spectra are modeled using a leptonic jet, with combined synchrotron
self-Compton + external Compton gamma-ray production. Spectral variability of
3C 279 is consistent with variations of the bulk Lorentz factor of the jet,
accompanied by changes in the spectral shape of the electron distribution. Our
modeling results are consistent with the UV spectrum of 3C 279 being dominated
by accretion disk radiation during times of low gamma-ray intensity.Comment: 39 pages including 13 figures; data tables not included (see ApJ web
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