Ion-Transport across Vesicle Bilayers Mediated by an Artificial Channel Compound

Contains fulltext : 10570.pdf (publisher's version ) (Open Access

The biacetyl-azo dye system: A model system to investigate oxidative dye fading

Applied Science

An enhanced optical micro-fading device

This paper introduces a new set-up for the determination of colour change on cultural heritage objects, referred to herein as a stereo-microfading tester. The system uses high quality optics through the implementation of a stereo-microscope as its central element. This technology enables new developments such as incorporation of high quality imaging systems, and separation of fading and colour measurement processes. This paper describes this new micro-fading set-up and evaluates its performance against traditional devices based on the measurement of blue wool standards

An enhanced optical micro-fading device

This paper introduces a new set-up for the determination of colour change on cultural heritage objects, referred to herein as a stereo-microfading tester. The system uses high quality optics through the implementation of a stereo-microscope as its central element. This technology enables new developments such as incorporation of high quality imaging systems, and separation of fading and colour measurement processes. This paper describes this new micro-fading set-up and evaluates its performance against traditional devices based on the measurement of blue wool standards

Mössbauer spectrometry applied to the study of laboratory samples made of iron gall ink

Iron gall inks consist of a mixture of vitriol, gall nut extracts and gum arabic. The association of the iron(II) sulphate present in vitriols, and the carboxyphenolic acids present in gall nut extracts leads to the formation of dark coloured iron-based precipitates. In order to evaluate the percentage of iron used in the formation of these precipitates, transmission Mössbauer spectroscopy (MS) measurements were performed on laboratory made inks at room temperature. These were completed by X-ray diffraction (XRD), and Raman spectroscopy measurements. The samples consisted of several solutions of iron(II) sulphate, gallic acid and gum arabic. After evaporation, the residues were analysed. Up to eight different Mössbauer signatures were detected, most of them correlated to iron sulphates. The Mössbauer signature of the iron gall precipitate was also isolated. It is not distinctly defined and may overlap with the signatures of iron(III) hydroxy-sulphates, such as jarosite or copiapite. Raman spectrometry then proved to be a useful complementary technique for the identification of the precipitate