Characterization of cowpea to harvest rainwater for wheat in semiarid conditions

Aim of study: A field experiment was executed, under rainfed conditions from 2014-15 to 2017-18, to study the role of cowpea (Vigna unguiculata L.) in rainwater harvesting to enhance the wheat (Triticum aestivum L.) yield.Area of study: Rain-fed area of Pothwar region, Punjab, Pakistan.Material and methods: We designed three treatments (T1: control; T2: cowpea grown after conventional tillage and incorporated into soil to act as “green manure”; and T3: grown without any tillage practice, cut with sickle and spread as “mulch”). The effect of these treatments on soil moisture conservation was studied against conventional farmer’s practice, wherein no host crop is grown before wheat sowing.Main results: Available soil water remained highest in T2 during first three years when sufficient rainfall was received contrary to fourth year with low rainfall. The results revealed that cowpea biomass of 15.2 t/ha and 13.72 t/ha, from T2 and T3 respectively, were produced during 2015 corresponding to 213 mm rainfall. Whereas, these quantities increased to 25.69 t/ha and 24.29 t/ha during 2017 with 387 mm of rainfall. The study revealed that net income from wheat crop under T2 was Rs 13000 and Rs 9000 per hectare higher than that of control during the first two years respectively. Contrarily, net income from T2 was found negative and benefit-cost ratio reduced to 0.79 when very low rainfall was received during the last year.Research highlights: Use of cowpea as green manure gave maximum net return if sufficient rainfall is received during decomposition of cowpea and hence recommended for in-situ rainwater harvesting

The Changing Landscape for Stroke\ua0Prevention in AF: Findings From the GLORIA-AF Registry Phase 2

Background GLORIA-AF (Global Registry on Long-Term Oral Antithrombotic Treatment in Patients with Atrial Fibrillation) is a prospective, global registry program describing antithrombotic treatment patterns in patients with newly diagnosed nonvalvular atrial fibrillation at risk of stroke. Phase 2 began when dabigatran, the first non\u2013vitamin K antagonist oral anticoagulant (NOAC), became available. Objectives This study sought to describe phase 2 baseline data and compare these with the pre-NOAC era collected during phase 1. Methods During phase 2, 15,641 consenting patients were enrolled (November 2011 to December 2014); 15,092 were eligible. This pre-specified cross-sectional analysis describes eligible patients\u2019 baseline characteristics. Atrial fibrillation disease characteristics, medical outcomes, and concomitant diseases and medications were collected. Data were analyzed using descriptive statistics. Results Of the total patients, 45.5% were female; median age was 71 (interquartile range: 64, 78) years. Patients were from Europe (47.1%), North America (22.5%), Asia (20.3%), Latin America (6.0%), and the Middle East/Africa (4.0%). Most had high stroke risk (CHA2DS2-VASc [Congestive heart failure, Hypertension, Age  6575 years, Diabetes mellitus, previous Stroke, Vascular disease, Age 65 to 74 years, Sex category] score  652; 86.1%); 13.9% had moderate risk (CHA2DS2-VASc = 1). Overall, 79.9% received oral anticoagulants, of whom 47.6% received NOAC and 32.3% vitamin K antagonists (VKA); 12.1% received antiplatelet agents; 7.8% received no antithrombotic treatment. For comparison, the proportion of phase 1 patients (of N = 1,063 all eligible) prescribed VKA was 32.8%, acetylsalicylic acid 41.7%, and no therapy 20.2%. In Europe in phase 2, treatment with NOAC was more common than VKA (52.3% and 37.8%, respectively); 6.0% of patients received antiplatelet treatment; and 3.8% received no antithrombotic treatment. In North America, 52.1%, 26.2%, and 14.0% of patients received NOAC, VKA, and antiplatelet drugs, respectively; 7.5% received no antithrombotic treatment. NOAC use was less common in Asia (27.7%), where 27.5% of patients received VKA, 25.0% antiplatelet drugs, and 19.8% no antithrombotic treatment. Conclusions The baseline data from GLORIA-AF phase 2 demonstrate that in newly diagnosed nonvalvular atrial fibrillation patients, NOAC have been highly adopted into practice, becoming more frequently prescribed than VKA in Europe and North America. Worldwide, however, a large proportion of patients remain undertreated, particularly in Asia and North America. (Global Registry on Long-Term Oral Antithrombotic Treatment in Patients With Atrial Fibrillation [GLORIA-AF]; NCT01468701

Role of MOF surface defects on the microscopic structure of MOF/polymer interfaces: A computational study of the ZIF-8/PIMs systems

International audienceThe influence of defects at the metal-organic framework (MOF) surface on the microscopic structure of a MOF/polymer composite has been studied by a computational methodology that combines density functional theory calculations with force field-based molecular dynamics simulations. This has been applied to composites formed by ZIF-8 and two different polymers of intrinsic microporosity: PIM-1 and PIM-EA-TB. Analysis of the MOF/polymer interactions, surface coverage, polymer conformation/stiffness and a full characterization of the interfacial voids are provided. We found that, although the nature of the MOF/polymer interactions changes in the presence of defects, the coverage and conformation of the polymer, as well as the morphology of the "interfacial microvoids" remain practically unchanged from a microscopic point of view. These results suggest that there is no microscopic evidence that defective MOF surfaces drastically change the geometry of the MOF/polymer interface and the strength of the physisorption-type interactions in play. (C) 2017 Elsevier Inc. All rights reserved

Microscopic Model of the Metal-Organic Framework/Polymer Interface: A First Step toward Understanding the Compatibility in Mixed Matrix Membranes

International audienceAn innovative computational methodology integrating density functional theory calculations and force field-based molecular dynamics simulations was developed to provide a first microscopic model of the interactions at the metal-organic framework (MOF) surface/polymer interface. This was applied to the case of the composite formed by the polymer of intrinsic microporosity, PIM-1, and the zeolitic imidazolate framework, ZIF-8, as a model system. We found that the structure of the composite at the interface is the result of both the chemical affinity between PIM-1 and ZIF-8 and the rigidity of the polymer. Specifically, there is a preferential interaction between the -CN groups of PIM-1 and the NH terminal functions of the organic linker at the ZIF-8 surface. Additionally, the resulting conformation of the polymer gives rise to interfacial microvoids at the vicinity of the MOF surface. The porosity, rigidity, and density of the interfacial polymer were analyzed and compared to those for the bulk polymer. It was shown that the polymer still feels the impact of the MOF surface even at long distances above 15-20 Å. Further, both the polydispersity of the polymer and the flexibility of the MOF surface were revealed to only slightly affect the properties of the MOF/interface. This work, which delivers a microscopic picture of the MOF surface/polymer interactions at the interface, would lead, in turn, to the understanding of the compatibility in MOF-based mixed-matrix membrane

Optically functionalized hierarchical hematite assembled silica-titania nanocomposites for hydrocarbon detection: fiber optic chemical sensor

Mesoporous hematite nanoparticles (HNPs) encapsulated SiO2–TiO2 nanocomposites (STNC) are synthesized and heat-treated at low-temperature 50 °C for 1h (STNC/1h) and 2h (STNC/2h) by sol-gel process for hydrocarbons chemical sensing. Microscopic analysis revealed the thermally stable hierarchical structure of HNPs, which changed into aggregated porous spherical morphology after encapsulation in STNC and heat treatment. The low surface area of HNPs ~55 m2/g which is increased up to 289 m2/g for H-STNC/2h, is advantageous to enhance sensing device activity. Magnetic properties exhibited the superparamagnetic behavior of H-STNC/2h. The H-STNC/2h coated fiber optic chemical sensor revealed a linear response towards the higher carbon chains, sensitivity is calculated as 5.3 counts per unit variations in the carbon chain at 515 nm with R2 ~ 0.98. The proposed magnetic sensing device has good reversibility, stability, and validity without any leaching traces

Characterization of cowpea to harvest rainwater for wheat in semiarid conditions

Aim of study: A field experiment was executed, under rainfed conditions from 2014-15 to 2017-18, to study the role of cowpea (Vigna unguiculata L.) in rainwater harvesting to enhance the wheat (Triticum aestivum L.) yield.Area of study: Rain-fed area of Pothwar region, Punjab, Pakistan.Material and methods: We designed three treatments (T1: control; T2: cowpea grown after conventional tillage and incorporated into soil to act as “green manure”; and T3: grown without any tillage practice, cut with sickle and spread as “mulch”). The effect of these treatments on soil moisture conservation was studied against conventional farmer’s practice, wherein no host crop is grown before wheat sowing.Main results: Available soil water remained highest in T2 during first three years when sufficient rainfall was received contrary to fourth year with low rainfall. The results revealed that cowpea biomass of 15.2 t/ha and 13.72 t/ha, from T2 and T3 respectively, were produced during 2015 corresponding to 213 mm rainfall. Whereas, these quantities increased to 25.69 t/ha and 24.29 t/ha during 2017 with 387 mm of rainfall. The study revealed that net income from wheat crop under T2 was Rs 13000 and Rs 9000 per hectare higher than that of control during the first two years respectively. Contrarily, net income from T2 was found negative and benefit-cost ratio reduced to 0.79 when very low rainfall was received during the last year.Research highlights: Use of cowpea as green manure gave maximum net return if sufficient rainfall is received during decomposition of cowpea and hence recommended for in-situ rainwater harvesting