C ion-implanted TiO2 thin film for photocatalytic applications

Third-generation TiO2 photocatalysts were prepared by implantation of C+ ions into 110 nm thick TiO2 films. An accurate structural investigation was performed by Rutherford backscattering spectrometry, secondary ion mass spectrometry, X-ray diffraction, Raman-luminescence spectroscopy, and UV/VIS optical characterization. The C doping locally modified the TiO2 pure films, lowering the band-gap energy from 3.3 eV to a value of 1.8 eV, making the material sensitive to visible light. The synthesized materials are photocatalytically active in the degradation of organic compounds in water under both UV and visible light irradiation, without the help of any additional thermal treatment. These results increase the understanding of the C-doped titanium dioxide, helpful for future environmental applications. (C) 2015 AIP Publishing LLC

Low temperature deactivation of Ge heavily n-type doped by ion implantation and laser thermal annealing

International audienceHeavy doping of Ge is crucial for several advanced micro-and optoelectronic applications, but, at the same time, it still remains extremely challenging. Ge heavily n-type doped at a concentration of 1 X 10(20) cm(-3) by As ion implantation and melting laser thermal annealing (LTA) is shown here to be highly metastable. Upon post-LTA conventional thermal annealing As electrically deactivates already at 350 degrees C reaching an active concentration of similar to 4 x 10(19) cm(-3). No significant As diffusion is detected up to 450 degrees C, where the As activation decreases further to similar to 3 x 10(19) cm(-3). The reason for the observed detrimental deactivation was investigated by Atom Probe Tomography and in situ High Resolution X-Ray Diffraction measurements. In general, the thermal stability of heavily doped Ge layers needs to be carefully evaluated because, as shown here, deactivation might occur at very low temperatures, close to those required for low resistivity Ohmic contacting of n-type Ge

Heavily-doped Germanium on Silicon with Activated Doping Exceeding 1020 cm−3 as an Alternative to Gold for Mid-infrared Plasmonics

Ge-on-Si has been demonstrated as a platform for Si foundry compatible plasmonics. We use laser thermal annealing to demonstrate activated doping levels >1020 cm-3 which allows most of the 3 to 20 μm mid-infrared sensing window to be covered with enhancements comparable to gold plasmonics

Optical properties of highly n-doped germanium obtained by in situ doping and laser annealing

High n-type doping in germanium is essential for many electronic and optoelectronic applications especially for high performance Ohmic contacts, lasing and mid-infrared plasmonics. We report on the combination of in situ doping and excimer laser annealing to improve the activation of phosphorous in germanium. An activated n-doping concentration of 8.8  ×  1019 cm−3 has been achieved starting from an incorporated phosphorous concentration of 1.1  ×  1020 cm−3. Infrared reflectivity data fitted with a multi-layer Drude model indicate good uniformity over a 350 nm thick layer. Photoluminescence demonstrates clear bandgap narrowing and an increased ratio of direct to indirect bandgap emission confirming the high doping densities achieved

Fluorine effect on As diffusion in Ge

The enhanced diffusion of donor atoms, via a vacancy (V)-mechanism, severely affects the realization of ultrahigh doped regions in miniaturized germanium (Ge) based devices. In this work, we report a study about the effect of fluorine (F) on the diffusion of arsenic (As) in Ge and give insights on the physical mechanisms involved. With these aims we employed experiments in Ge co-implanted with F and As and density functional theory calculations. We demonstrate that the implantation of F enriches the Ge matrix in V, causing an enhanced diffusion of As within the layer amorphized by F and As implantation and subsequently regrown by solid phase epitaxy. Next to the end-of-range damaged region F forms complexes with Ge interstitials, that act as sinks for V and induce an abrupt suppression of As diffusion. The interaction of Ge interstitials with fluorine interstitials is confirmed by theoretical calculations. Finally, we prove that a possible F-As chemical interaction does not play any significant role on dopant diffusion. These results can be applied to realize abrupt ultra-shallow n-type doped regions in future generation of Ge-based devices

Nuclear expansion and symmetry energy of hot nuclei

The decrease in the symmetry energy of hot nuclei populated in $^{58}$Ni + $^{58}$Ni, $^{58}$Fe + $^{58}$Ni and $^{58}$Fe + $^{58}$Fe reactions at beam energies of 30, 40, and 47 MeV/nucleon, as a function of excitation energy is studied. It is observed that this decrease is mainly a consequence of increasing expansion or decreasing density rather than the increasing temperature. The results are in good agreement with the recently reported microscopic calculation based on the Thomas-Fermi approach. An empirical relation to study the symmetry energy of finite nuclei in various mass region is proposed.Comment: 10 pages, 2 figure

Signals of Bose Einstein condensation and Fermi quenching in the decay of hot nuclear systems

We report experimental signals of Bose-Einstein condensation in the decay of hot Ca projectile-like sources produced in mid-peripheral collisions at sub-Fermi energies. The experimental setup, constituted by the coupling of the INDRA 4$\pi$ detector array to the forward angle VAMOS magnetic spectrometer, allowed us to reconstruct the mass, charge and excitation energy of the decaying hot projectile-like sources. Furthermore, by means of quantum fluctuation analysis techniques, temperatures and mean volumes per particle "as seen by" bosons and fermions separately are correlated to the excitation energy of the reconstructed system. The obtained results are consistent with the production of dilute mixed (bosons/fermions) systems, where bosons experience a smaller volume as compared to the surrounding fermionic gas. Our findings recall similar phenomena observed in the study of boson condensates in atomic traps.Comment: Submitted to Phys. Rev. Lett. (december 2014

Production of α\alpha-particle condensate states in heavy-ion collisions

The fragmentation of quasi-projectiles from the nuclear reaction $^{40}Ca$ + $^{12}C$ at 25 MeV/nucleon was used to produce excited states candidates to $\alpha$-particle condensation. The experiment was performed at LNS-Catania using the CHIMERA multidetector. Accepting the emission simultaneity and equality among the $\alpha$-particle kinetic energies as experimental criteria for deciding in favor of the condensate nature of an excited state, we analyze the $0_2^+$ and $2_2^+$ states of $^{12}$C and the $0_6^+$ state of $^{16}$O. A sub-class of events corresponding to the direct 3-$\alpha$ decay of the Hoyle state is isolated.Comment: contribution to the 2nd Workshop on "State of the Art in Nuclear Cluster Physics" (SOTANCP2), Universite Libre de Bruxelles (Belgium), May 25-28, 2010, to be published in the International Journal of Modern Physics

Anomalous thermodynamics and phase transitions of neutron-star matter

In this letter we show that the presence of the long-range Coulomb force in dense stellar matter implies that the total charge cannot be associated with a chemical potential, even if it is a conserved quantity. As a further consequence, the analytical properties of the partition sum are modified, changing the order of the phase transitions and affecting the possible occurrence of critical behaviours. The peculiar thermodynamic properties of the system can be understood introducing a model hamiltonian in which each charge is independently neutralized by a uniform background of opposite charge.Comment: 4 pages - GANIL, LP

First Direct Measurement of the ^{17}O(p,\gamma)^{18}F Reaction Cross-Section at Gamow Energies for Classical Novae

Classical novae are important contributors to the abundances of key isotopes, such as the radioactive ^{18}F, whose observation by satellite missions could provide constraints on nucleosynthesis models in novae. The ^{17}O(p,\gamma)^{18}F reaction plays a critical role in the synthesis of both oxygen and fluorine isotopes but its reaction rate is not well determined because of the lack of experimental data at energies relevant to novae explosions. In this study, the reaction cross section has been measured directly for the first time in a wide energy range Ecm = 200 - 370 keV appropriate to hydrogen burning in classical novae. In addition, the E=183 keV resonance strength, \omega \gamma=1.67\pm0.12 \mueV, has been measured with the highest precision to date. The uncertainty on the ^{17}O(p,\gamma)^{18}F reaction rate has been reduced by a factor of 4, thus leading to firmer constraints on accurate models of novae nucleosynthesis.Comment: accepted by Phys. Rev. Let