4,045 research outputs found
The scaling of the decoherence factor of a qubit coupled to a spin chain driven across quantum critical points
We study the scaling of the decoherence factor of a qubit (spin-1/2) using
the central spin model in which the central spin (qubit) is globally coupled to
a transverse XY spin chain. The aim here is to study the non-equilibrium
generation of decoherence when the spin chain is driven across (along) quantum
critical points (lines) and derive the scaling of the decoherence factor in
terms of the driving rate and some of the exponents associated with the quantum
critical points. Our studies show that the scaling of logarithm of decoherence
factor is identical to that of the defect density in the final state of the
spin chain following a quench across isolated quantum critical points for both
linear and non-linear variations of a parameter even if the defect density may
not satisfy the standard Kibble-Zurek scaling. However, one finds an
interesting deviation when the spin chain is driven along a critical line. Our
analytical predictions are in complete agreement with numerical results. Our
study, though limited to integrable two-level systems, points to the existence
of a universality in the scaling of the decoherence factor which is not
necessarily identical to the scaling of the defect density.Comment: 5 pages, 2 figures, Final and accepted versio
Anticandidal activity of some Zn(II) and Pb(II) complexes
The reactions of zinc and lead acetate with ligands HON=C(CH2)5, PhN=C(Ph)C(OH)Ph resulted in complexes of the type [M(ac)2L2] (M = Zn/Pb and L = corresponding ligand). Ligands were prepared by green methods. Complexes were characterized by proton-NMR, IR spectral studies and these spectra were compared with that of free ligands.Antifungal activity of the complexes demonstrated that the complexes [ZnII(ac)2{N(OH)=C(CH2)5}2], [PbII(ac)2{N(OH)=C(CH2)5}2] and [ZnII(ac)2{N(Ph)=C(Ph)C(OH)Ph}2] are active against Candida albicans
Reliability analysis of shallow foundations subjected to varied inclined loads
Risk and Reliability in Geotechnical Engineerin
Methyl 2-(N-Ethylamino)cyc1opentene-1- dithio-carboxylate Complexes of Pd(II), Pt(II) & Hg(II)
250-25
Ultra-narrow and widely tunable Mn^(2+) Emission from Single Nanocrystals of ZnS-CdS alloy
Extensively studied Mn-doped semiconductor nanocrystals have invariably
exhibited photoluminescence (PL) over a narrow energy window of width <= 149
meV in the orange-red region and a surprisingly large spectral width (>= 180
meV), contrary to its presumed atomic-like origin. Carrying out emission
measurements on individual single nanocrystals and supported by ab initio
calculations, we show that Mn PL emission, in fact, can (i) vary over a much
wider range (~ 370 meV) covering the deep green-deep red region and (ii)
exhibit widths substantially lower (~ 60-75 meV) than reported so far, opening
newer application possibilities and requiring a fundamental shift in our
perception of the emission from Mn-doped semiconductor nanocrystals.Comment: 5 pages, 5 figure
Effects of ion concentration on the hydrogen bonded structure of water in the vicinity of ions in aqueous NaCl solutions
Molecular dynamics simulations of dilute and concentrated aqueous NaCl solutions are carried out to investigate the changes of the hydrogen bonded structures in the vicinity of ions for different ion concentrations. An analysis of the hydrogen bond population in the first and second solvation shells of the ions and in the bulk water is done. Although essentially no effect of ions on the hydrogen bonding is observed beyond the first solvation shell of the ions for the dilute solutions, for the concentrated solutions a noticeable change in the average number of water-water hydrogen bonds is observed in the second solvation shells of the ions and even beyond. However, the changes in the average number of hydrogen bonds are found to be relatively less when both water-water and ion-water hydrogen bonds are counted. Thus, the changes in the total number of hydrogen bonds per water are not very dramatic beyond the first solvation shell even for concentrated solutions
- …