604 research outputs found

    Genesis of an atypical Podzol in the Iberian Range: micromorphological characterization

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    A podzol has been described in the Iberian Range (Moncayo Natural Park), which may represent the southernmost example in Europe. The fact that it occurs at the podzol distribution limit makes its morphology atypical. The aim of this work is to identify the components and formation processes of the soil, and to determine if the processes are active or paleo-processes by a micromorphological approach. The study podzol is located in the top of a northern hillside (30% of slope), at 1600 m altitude on quartzitic sandstones, under Scots pine (Pinus sylvestris) with an udic moisture regime and a frigid temperature regime. We found opaque, orthic iron oxide nodules at the base of the profile (Bhs1), which is related to a current oxidation-reduction process; silt caps are also observed on the coarse elements, pedofeatures evidencing the cryoturbation process, probably also current processes. In the Bhs2 horizon, coatings and micro-laminated clay infillings are identified that are interspersed with fine silts in the holes. Many of these coatings are fragmented and mixed with the basal mass of the soil, indicating that they are paleofeature, possibly prior to the current podzolization. En el Sistema Ibérico (Parque Natural del Moncayo) han sido descritos Podzols, que se encuentran entre los más meridionales de Europa. El hecho de estar en su límite de distribución hace que su morfología sea atípica. El objetivo de este trabajo es identificar los componentes y procesos de formación del suelo, y determinar si los procesos son activos o paleo-procesos, mediante un enfoque micromorfológico. El Podzol de estudio está situado en la cima de una ladera septentrional (30% de pendiente), a 1600 m de altitud sobre areniscas cuarcíticas, bajo pino silvestre (Pinus sylvestris) con un régimen de humedad údico y un régimen de temperatura frígido. Se encuentran nódulos opacos, órticos, de óxidos de hierro en la base del perfil (horizonte Bhs1), lo que está relacionado con un proceso de óxido-reducción actual; también se observan casquetes o cappings de limo en los elementos gruesos, edaforrasgo que evidencia el proceso de crioturbación, probablemente también actual. En el horizonte Bhs2 se identifican revestimientos y rellenos de arcilla microlaminada que se intercalan con limos finos en los poros. Muchos de estos revestimientos están fragmentados y mezclados con la masa basal del suelo, lo que indica que son paleoprocesos, posiblemente anteriores a la podzolización actual

    Surface charging of thick porous water ice layers relevant for ion sputtering experiments

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    We use a laboratory facility to study the sputtering properties of centimeter-thick porous water ice subjected to the bombardment of ions and electrons to better understand the formation of exospheres of the icy moons of Jupiter. Our ice samples are as similar as possible to the expected moon surfaces but surface charging of the samples during ion irradiation may distort the experimental results. We therefore monitor the time scales for charging and dis- charging of the samples when subjected to a beam of ions. These experiments allow us to derive an electric conductivity of deep porous ice layers. The results imply that electron irradiation and sputtering play a non-negligible role for certain plasma conditions at the icy moons of Jupiter. The observed ion sputtering yields from our ice samples are similar to previous experiments where compact ice films were sputtered off a micro-balance.Comment: arXiv admin note: text overlap with arXiv:1509.0400

    A fast and easy approach to the simulation of binary mixtures sorption kinetics

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    Diffusivity of a component in a binary mixture is affected by the presence of a second component. The knowledge of the influence on each other component diffusivity is very useful for the prediction of sorption kinetics of binary mixtures. In this work kinetic studies of Cr(VI) and Cu(II) binary mixtures sorption onto exhausted coffee encapsulated in calcium alginate beads were carried out in both bench and pilot scale experiments. The spectroscopic analysis evidenced the complexity of the process since different mechanisms such as adsorption, redox reaction and ion exchange are involved. Experimental data were fitted to the Linear Adsorption Model (LAM). An empirical quadratic model was developed to estimate LAM parameters (De) and α = Cf/(Ci − Cf) as a function of the initial concentration of metals in the mixture. The empirical model developed enables to estimate the LAM parameters (De and α) of metal ions binary mixtures provided that the initial concentration of the metal ions is included in the range of concentrations studied. The estimated parameters introduced in LAM equation allow simulating the corresponding binary mixtures sorption kinetics. This study constitutes a fast and easy approach to the modelling of sorption kinetics of complex systems in which different processes take place simultaneously

    Estilo comportamental al inicio del segundo año de vida:estudio retrospectivo en escolares afectados de trastorno por deficit de atencion e hiperactividad

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    OBJECTIVES: To study the relationship between behavioural profile of children suffering from Attention Deficit Hyperactivity Disorder (ADHD) and the previous behavioural style of these patients as toddlers. SUBJECTS AND METHODS: We asked the parents of 50 schoolchildren with ADHD, and those of 30 controls, to fill in a Spanish version of the Toddler Behaviour Questionnaire (TBQ) from their retrospective perception of their children's behaviour as toddlers. TBQ items were grouped by factor analysis; t-Student between the scores of both groups and a multiple correlation analysis of TBQ and DSM-IV-ADHD-RS in each of the groups were used. RESULTS: Children in the ADHD group were reported by parents to have had a different toddler behavioural profile in comparison to that of control children (P<0.05). These differences were associated with adapting to new environments, mood, regularity and stability of play behaviour. A correlation was found between behavioural profile in DSM-IV-ADHD- RS and TBQ. CONCLUSIONS: The results of this study should be interpreted with caution. However, they suggest that in the fifth trimester of life a particular behavioural style as regards regularity, stability of play, and mood, could indicate a risk of developing ADHD in the future. This behavioural style should be taken into consideration in rearing and early education prospective studies

    Conservation of soil organic carbon, biodiversity and the provision of other ecosystem services along climatic gradients in West Africa

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    Terrestrial carbon resources are major drivers of development in West Africa. The distribution of these resources co-varies with ecosystem type and rainfall along a strong Northeast-Southwest climatic gradient. Soil organic carbon, a strong indicator of soil quality, has been severely depleted in some areas by human activities, which leads to issues of soil erosion and desertification, but this trend can be altered with appropriate management. There is significant potential to enhance existing soil carbon stores in West Africa, with benefits at the global and local scale, for atmospheric CO2 mitigation as well as supporting and provisioning ecosystem services. Three key factors impacting carbon stocks are addressed in this review: climate, biotic factors, and human activities. Climate risks must be considered in a framework of global change, especially in West Africa, where landscape managers have few resources available to adapt to climatic perturbations. Among biotic factors, biodiversity conservation paired with carbon conservation may provide a pathway to sustainable development, and biodiversity conservation is also a global priority with local benefits for ecosystem resilience, biomass productivity, and provisioning services such as foodstuffs. Finally, human management has largely been responsible for reduced carbon stocks, but this trend can be reversed through the implementation of appropriate carbon conservation strategies in the agricultural sector, as shown by multiple studies. Owing to the strong regional climatic gradient, country-level initiatives will need to consider carbon sequestration approaches for multiple ecosystem types. Given the diversity of environments, global policies must be adapted and strategies developed at the national or sub-national levels to improve carbon storage above and belowground. Initiatives of this sort must act locally at farmer scale, and focus on ecosystem services rather than on carbon sequestration solely

    Three-dimensional assessment of vascular cooling effects on hepatic microwave ablation in a standardized ex vivo model

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    The aim of this study was a three-dimensional analysis of vascular cooling effects on microwave ablation (MWA) in an ex vivo porcine model. A glass tube, placed in parallel to the microwave antenna at distances of 2.5, 5.0 and 10.0 mm (A-V distance), simulated a natural liver vessel. Seven flow rates (0, 1, 2, 5, 10, 100, 500 ml/min) were evaluated. Ablations were segmented into 2 mm slices for a 3D-reconstruction. A qualitative and quantitative analysis was performed. 126 experiments were carried out. Cooling effects occurred in all test series with flow rates >= 2 ml/min in the ablation periphery. These cooling effects had no impact on the total ablation volume (p > 0.05) but led to changes in ablation shape at A-V distances of 5.0 mm and 10.0 mm. Contrary, at a A-V distance of 2.5 mm only flow rates of >= 10 ml/min led to relevant cooling effects in the ablation centre. These cooling effects influenced the ablation shape, whereas the total ablation volume was reduced only at a maximal flow rate of 500 ml/min (p = 0.002). Relevant cooling effects exist in MWA. They mainly depend on the distance of the vessel to the ablation centre

    Spain's Budget Neglects Research

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    Letter.-- Carlos Fenollosa et al.Peer Reviewe

    Combination chemotherapy for choroidal melanoma: ex vivo sensitivity to treosulfan with gemcitabine or Cytosine arabinoside

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    Treatment of choroidal melanoma by chemotherapy is usually unsuccessful, with response rates of less than 1% reported for dacarbazine (DTIC)-containing regimens which show 20% or more response rates in skin melanoma. Recently, we reported the activity of several cytotoxic agents against primary choroidal melanoma in an ATP-based tumour chemosensitivity assay (ATP-TCA). In this study, we have used the same method to examine the sensitivity of choroidal melanoma to combinations suggested by our earlier study. Tumour material from 36 enucleated eyes was tested against a battery of single agents and combinations which showed some activity in the previous study. The combination of treosulfan with gemcitabine or cytosine arabinoside showed consistent activity in 70% and 86% of cases, respectively. Paclitaxel was also active, particularly in combination with treosulfan (47%) or mitoxantrone (33%). Addition of paclitaxel to the combination of treosulfan + cytosine analogue added little increased sensitivity. For treosulfan + cytosine arabinoside, further sequence and timing experiments showed that simultaneous administration gave the greatest suppression, with minor loss of inhibition if the cytosine analogue was given 24 h after the treosulfan. Administration of cytosine analogue 24 h before treosulfan produced considerably less inhibition at any concentration. While we have so far been unable to study metastatic tumour from choroidal melanoma patients, the combination of treosulfan with gemcitabine or cytosine arabinoside shows activity ex vivo against primary tumour tissue. Clinical trials are in progress. © 1999 Cancer Research Campaig
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