Application of an atmospheric pressure sampling mass spectrometer to chlorination reactions

An atmospheric pressure mass spectrometric sampling system, based on a free jet expansion was used to study certain M-Cl-O reactions at high temperatures. The apparatus enables the volatile species from a 1-atm chemical process to be directly identified with a mass spectrometer which operates at approx. 10 to the minus 8th power torr. Studies for both pure metals and alloys are discussed. It is shown that this mass spectrometer system aids in identifying the volatile species, and provides fundamental information on the reaction mechanism

Set-partition tableaux and representations of diagram algebras

The partition algebra is an associative algebra with a basis of set-partition diagrams and multiplication given by diagram concatenation. It contains as subalgebras a large class of diagram algebras including the Brauer, planar partition, rook monoid, rook-Brauer, Temperley-Lieb, Motzkin, planar rook monoid, and symmetric group algebras. We give a construction of the irreducible modules of these algebras in two isomorphic ways: first, as the span of symmetric diagrams on which the algebra acts by conjugation twisted with an irreducible symmetric group representation and, second, on a basis indexed by set-partition tableaux such that diagrams in the algebra act combinatorially on tableaux. The first representation is analogous to the Gelfand model and the second is a generalization of Young's natural representation of the symmetric group on standard tableaux. The methods of this paper work uniformly for the partition algebra and its diagram subalgebras. As an application, we express the characters of each of these algebras as nonnegative integer combinations of symmetric group characters whose coefficients count fixed points under conjugation

Top Down Implementation Plan for system performance test software

The top down implementation plan used for the development of system performance test software during the Mark IV-A era is described. The plan is based upon the identification of the hierarchical relationship of the individual elements of the software design, the development of a sequence of functionally oriented demonstrable steps, the allocation of subroutines to the specific step where they are first required, and objective status reporting. The results are: determination of milestones, improved managerial visibility, better project control, and a successful software development

Mechanism of strength degradation for hot corrosion of alpha-SiC

Sintered alpha SiC was corroded by thin films of Na2SO4 and Na2CO3 molten salts at 1000%. This hot corrosion attack reduced room temperature strengths by as much as 50%. Strength degradation was porportional to the degree and uniformity of corrosion pitting attack as controlled by the chemistry of the molten salt. Extensive fractography identified corrosion pits as the most prevalent source of failure. A fracture mechanics treatment of the strength/pit depth relationship produced an average K sub IC equal to 2.6 MPa sub m 1/2, which is consistent with published values

Reaction of cobalt in SO2 atmospheric at elevated temperatures

The reaction rate of cobalt in SO2 argon environments was measured at 650 C, 700 C, 750 C and 800 C. Product scales consist primarily of an interconnected sulfide phase in an oxide matrix. At 700 C to 800 C a thin sulfide layer adjacent to the metal is also observed. At all temperatures, the rapid diffusion of cobalt outward through the interconnected sulfide appears to be important. At 650 C, the reaction rate slows dramatically after five minutes due to a change in the distribution of these sulfides. At 700 C and 750 C the reaction is primarily diffusion controlled values of diffusivity of cobalt (CoS) calculated from this work show favorable agreement with values of diffusivity of cobalt (CoS) calculated from previous sulfidation work. At 800 C, a surface step becomes rate limiting

Molten salt corrosion of SiC: Pitting mechanism

Thin films of Na2SO4 and Na2CO3 at 1000 C lead to severe pitting of sintered alpha-SiC. These pits are important as they cause a strength reduction in this material. The growth of product layers is related to pit formation for the Na2CO3 case. The early reaction stages involve repeated oxidation and dissolution to form sodium silicate. This results in severe grain boundary attack. After this a porous silica layer forms between the sodium silicate melt and the SiC. The pores in this layer appear to act as paths for the melt to reach the SiC and create larger pits

Innovation processes and industrial districts

In this survey, we examine the operations of innovation processes within industrial districts by exploring the ways in which differentiation, specialization, and integration affect the generation, diffusion, and use of new knowledge in such districts. We begin with an analysis of the importance of the division of labour and then investigate the effects of social embeddedness on innovation. We also consider the effect of forms of organization within industrial districts at various stages of product and process life, and we examine the negative aspects of embeddedness for innovation. We conclude with a discussion of the possible consequences of new information and communications technologies on innovation in industrial districts

Models of subjective response to in-flight motion data

Mathematical relationships between subjective comfort and environmental variables in an air transportation system are investigated. As a first step in model building, only the motion variables are incorporated and sensitivities are obtained using stepwise multiple regression analysis. The data for these models have been collected from commercial passenger flights. Two models are considered. In the first, subjective comfort is assumed to depend on rms values of the six-degrees-of-freedom accelerations. The second assumes a Rustenburg type human response function in obtaining frequency weighted rms accelerations, which are used in a linear model. The form of the human response function is examined and the results yield a human response weighting function for different degrees of freedom

Lattice Black Holes

We study the Hawking process on lattices falling into static black holes. The motivation is to understand how the outgoing modes and Hawking radiation can arise in a setting with a strict short distance cutoff in the free-fall frame. We employ two-dimensional free scalar field theory. For a falling lattice with a discrete time-translation symmetry we use analytical methods to establish that, for Killing frequency $\omega$ and surface gravity $\kappa$ satisfying $\kappa\ll\omega^{1/3}\ll 1$ in lattice units, the continuum Hawking spectrum is recovered. The low frequency outgoing modes arise from exotic ingoing modes with large proper wavevectors that "refract" off the horizon. In this model with time translation symmetry the proper lattice spacing goes to zero at spatial infinity. We also consider instead falling lattices whose proper lattice spacing is constant at infinity and therefore grows with time at any finite radius. This violation of time translation symmetry is visible only at wavelengths comparable to the lattice spacing, and it is responsible for transmuting ingoing high Killing frequency modes into low frequency outgoing modes.Comment: 26 pages, LaTeX, 2 figures included with psfig. Several improvements in the presentation. One figure added. Final version to appear in Phys.Rev.