Study of the in-plane magnetic penetration depth in the cuprate superconductor Ca_2-xNa_xCuO_2Cl_2: role of the apical sites

A study of the in-plane magnetic penetration depth \lambda_ab in a series of the cuprate superconductors Ca_2-xNa_xCuO_2Cl_2 (Na-CCOC) with Na content x=0.11, 0.12, 0.15, 0.18, and 0.19 is reported. The zero temperature values of \lambda_ab(0) were obtained by means of the muon-spin rotation technique, as well as from measurements of the intrinsic susceptibility \chi^int(0) by using the procedure developed by Kanigel et al. [Phys.Rev.B 71, 224511 (2005)]. \lambda_ab at T=0K was found to increase with decreasing doping from \lambda_ab(0)=316(19)nm for the x=0.19 sample to \lambda_ab(0)=430(26)nm for the x=0.11 one. From a comparison of the present Na-CCOC data with those of Bi2201 and La214 cuprate superconductors it is concluded that substitution of the apical oxygen by chlorine decreases the coupling between the superconducting CuO_2 planes, leading to an enhancement of the two-dimensional properties of Na-CCOC.Comment: 8 pages, 7 figure

Exploring 2D Materials by High Pressure Synthesis: hBN, Mg-hBN, b-P, b-AsP, and GeAs

In materials science, selecting the right synthesis technique for specific compounds is one of the most important steps. High-pressure conditions have a significant effect on the crystal growth processes, leading to the creation of unique structures and properties that usually are not possible under normal conditions. The prime objective of this article is to illustrate the benefits of using high-pressure, high-temperature (HPHT) technique when developing two-dimensional (2D) materials. We could successfully grow bulk single crystals of hexagonal boron nitride (hBN) and magnesium doped hexagonal boron nitride (Mg-hBN) from Mg-B-N solvent. Further exploration of the Mg-B-N system could lead to the crystallization of isotopically 10B and 11B enriched hBN crystals, and other doped variants of it. Black phosphorus (b-P) and black phosphorus doped with arsenic (b-AsP) were obtained by directly converting its elements into melt and subsequently crystallizing them under HPHT. Germanium arsenide (GeAs) bulk single crystals were also obtained from the melt at a pressure of 1 GPa. Upon crystallization, all these compounds exhibit the anticipated layered structures, which makes them easy to exfoliate into 2D flakes, thus providing opportunities to modify their electrical behavior and create new useful devices

Normal state bottleneck and nematic fluctuations from femtosecond quasi-particle relaxation dynamics in Sm(Fe,Co)AsO

We investigate temperature and fluence dependent dynamics of the photoexcited quasi-particle relaxation and low-energy electronic structure in electron-doped 1111-structure Sm(Fe_{0.93}Co_{0.07})AsO single crystal. We find that the behavior is qualitatively identical to the 122-structure Ba(Fe,Co)_{2}As_{2} including the presence of a normal state pseudogap and a marked 2-fold symmetry breaking in the tetragonal phase that we relate to the electronic nematicity. The 2-fold symmetry breaking appears to be a general feature of the electron doped iron pnictides

Anharmonicity and self-energy effects of the E2g phonon in MgB2

We present a Raman scattering study of the E2g phonon anharmonicity and of superconductivity induced self-energy effects in MgB2 single crystals. We show that anharmonic two phonon decay is mainly responsible for the unusually large linewidth of the E2g mode. We observe ~ 2.5 % hardening of the E2g phonon frequency upon cooling into the superconducting state and estimate the electron-phonon coupling strength associated with this renormalization.Comment: 4 pages, 3 figures, accepted to PR

Nodal-to-nodeless superconducting order parameter in LaFeAs1−x_{1-x}Px_xO synthesized under high pressure

Similar to chemical doping, pressure produces and stabilizes new phases of known materials, whose properties may differ greatly from those of their standard counterparts. Here, by considering a series of LaFeAs$_{1-x}$P$_x$O iron-pnictides synthesized under high-pressure high-temperature conditions, we investigate the simultaneous effects of pressure and isoelectronic doping in the 1111 family. Results of numerous macro- and microscopic technique measurements, unambiguously show a radically different phase diagram for the pressure-grown materials, characterized by the lack of magnetic order and the persistence of superconductivity across the whole $0.3 \leq x \leq 0.7$ doping range. This unexpected scenario is accompanied by a branching in the electronic properties across $x = 0.5$, involving both the normal and superconducting phases. Most notably, the superconducting order parameter evolves from nodal (for $x < 0.5$) to nodeless (for $x \geq 0.5$), in clear contrast to other 1111 and 122 iron-based materials grown under ambient-pressure conditions.Comment: 9 pages, 7 figures, Suppl. materia