Effects of Potassium Source and Secondary Nutrients on Potato Yield and Quality in Southcentral Alaska.

Calcium (Ca), magnesium (Mg), and sulfur (S) are required for the growth and development of all higher plants. They are commonly referred to as secondary nutrients because they are less often limiting to plant growth than the primary nutrients nitrogen (N), phosphorus (P), and potassium (K), although secondary nutrients are as critical for crop growth and development as the primary nutrients. There is limited information available concerning secondary nutrient requirements of potatoes grown in southcentral Alaska. Laughlin (1966) conducted studies between 1961 and 1963 comparing potassium chloride (KCl) and potassium sulfate (K2SO4) as potassium sources for Green Mountain potatoes, and determined the effects of varying rates of magnesium sulfate (MgSO4) and K2SO4 on Kennebec potatoes. Since these studies were conducted without irrigation and at production levels about one-half those obtained by top producers in the Matanuska Valley today, it was considered appropriate to expand upon the previous work using current production practices. Potassium was supplied as KCl and K2 SO4 to explore the need for additional S under local potato production conditions and to determine the effects of the chloride (Cl) and sulfate (SO4) anions on production and quality of potato tubers. In addition, Mg and Ca were added to determine whether the background levels of these nutrients were adequate for optimum production

Spectroscopic and microscopic analyses of Fe3O4/au nanoparticles obtained by laser ablation in water

Magneto-plasmonic nanoparticles constituted of gold and iron oxide were obtained in an aqueous environment by laser ablation of iron and gold targets in two successive steps. Gold nanoparticles are embedded in a mucilaginous matrix of iron oxide, which was identified as magnetite by both microscopic and spectroscopic analyses. The plasmonic properties of the obtained colloids, as well as their adsorption capability, were tested by surface-enhanced Raman scattering (SERS) spectroscopy using 2,2′-bipyridine as a probe molecule. DFT calculations allowed for obtaining information on the adsorption of the ligand molecules that strongly interact with positively charged surface active sites of the gold nanoparticles, thus providing efficient SERS enhancement. The presence of iron oxide gives the bimetallic colloid new possibilities of adsorption in addition to those inherent to gold nanoparticles, especially regarding organic pollutants and heavy metals, allowing to remove them from the aqueous environment by applying a magnetic field. Moreover, these nanoparticles, thanks to their low toxicity, are potentially useful not only in the field of sensors, but also for biomedical applications

A Green function method to study thin diffraction gratings

The anomalous features in diffraction patterns first observed by Wood over a century ago have been the subject of many investigations, both experimental and theoretical. The sharp, narrow structures - and the large resonances with which they are sometimes associated - arise in numerous studies in optics and photonics. In this paper we present an analytical method to study diffracted fields of optically thin gratings that highlights the nonanalyticities associated with the anomalies. Using this approach we can immediately derive diffracted fields for any polarization in a compact notation. While our equations are approximate, they fully respect energy conservation in the electromagnetic field, and describe the large exchanges of energy between incident and diffracted fields that can arise even for thin gratings.Comment: 19 pages, 8 figure

Descriptors for terpene esters from chromatographic and partition measurements: Estimation of human odor detection thresholds

We have used gas chromatographic retention data together with other data to obtain Abraham descriptors for 30 terpene esters. These include the air-water partition coefficient, as log Kw, for which no experimental values are available for any terpene ester. The other descriptors are the ester dipolarity, S, the hydrogen bond basicity, B, (the ester hydrogen bond acidity is zero for the esters studied), and L the logarithm of the air-hexadecane partition coefficient. Both S and B are larger than those for simple aliphatic esters, as expected from the terpene ester structures that include ring systems and ethylenic double bonds. These descriptors can then be used to obtain a large number of physicochemical and environmental properties of terpene esters. We have analyzed experimental results on human odor detection thresholds and have constructed another equation for the calculation of these thresholds, to go with a previous equation that we have reported. Then the descriptors for terpene esters can be used to estimate the important odor detection thresholds