Effect of alcoholic and nano-particles additives on tribological properties of diesel–palm–sesame–biodiesel blends

This study focused on evaluating the lubricity of diesel–biodiesel fuel with oxygenated alcoholic and nano-particle additives. Fuel injection system lubrication depended primarily on the fuel used in the diesel engine. Palm–sesame oil blend was used to produce biodiesel using the ultrasound-assisted technique. B30 fuel sample as a base fuel was blended with fuel additives in different proportions prior to tribological behavior analysis. The lubricity of fuel samples measured using HFRR in accordance with the standard method ASTM D6079. All tested fuels’ Tribological behavior examined through worn steel balls and plates using scanning electron microscopy (SEM) to assess wear scar diameter and surface morphology. During the test run, the friction coefficient was measured directly by the HFRR tribometer system. The results exhibited that B10 (diesel) had a very poor coefficient of friction and wear scar diameter, among other tested fuels. The addition of oxygenated alcohol (ethanol) as a fuel additive in the B30 fuel sample decreased the lubricity of fuel and increased the wear and friction coefficient, among other fuel additives. B30 with DMC showed the least wear scar diameter among all tested fuels. B30 with nanoparticle TiO2 exhibited the best results with the least wear scar diameter and lowest friction coefficient among all other fuel samples. B30+DMC demonstrated significant improvement in engine performance (BTE) and carbon emissions compared to different tested samples. B30+TiO2 also showed considerable improvement in engine characteristics

Effect of primary and secondary alcohols as oxygenated additives on the performance and emission characteristics of diesel engine

The demand for renewable energy sources is gradually escalating due to the spontaneously growing population and global economic development. The access to fossil fuels is gradually declining due to the limited available reserves. Hence, renewable energy resources, technology choice, and energy policy are always being revised due to the modernization of society. Meanwhile, the liquid energy sources such as methyl ester from locally produced vegetable oils are readily accepted by many countries globally, although it is currently being blended (up to 20%) with diesel. Oxides of nitrogen are the most substantial emissions from diesel engines produced due to high combustion temperature. The addition of alcohol in the fuel reduces the NOx formation since alcohols have high latent heat of evaporation. The present study's primary purpose is to investigate the effect of different alcohol types on engine performance and emission characteristics. For this purpose, seven test fuels and neat diesel were used. The test fuels P20 (20% palm biodiesel with 70% neat diesel and 10% alcohol on a volume basis), D70P20E10, D70P20Pr10, D70P20B10, D70P20Pe10, D70P20H10 were prepared and tested on a single-cylinder, 4-stroke, DI-diesel engine at different speeds at 100 % load. The P20E10 ternary fuel blend illustrated the most practical combination of all the bioethanol-based blends, which considerably improves the BTE, BSFC and reduces NOxformation at high speed compared to other types of alcoholic fuel blends. Also, the P20E10 fuel blend improved the cloud point of neat diesel

Critical review on sesame seed oil and its methyl ester on cold flow and oxidation stability

© 2019 The demand for renewable energy is steadily increasing due to rapid population growth and economic development worldwide. An additional reason is that fossil fuel reserves are limited, and this situation results in their non-uniform availability globally. Furthermore, the attitudes of the society, energy policies and technology choices are constantly changing. Thus, renewable energy resources are now considered good alternatives to fossil fuels. In the meantime, liquid energy, such as methyl ester from locally produced vegetable oils, is well accepted by many countries, even though it is currently being blended up to 20% with petroleum fuels. Recently, the industrialisation of biodiesel is a major problem because of its poor cold flow properties and oxidative stability. Vegetable oils are also being blended in an appropriate proportion before transesterification to obtain the desired properties in biodiesel. Similarly, poor cold flow properties and oxidative stability can be improved by choosing suitable vegetable oils for making blends. Amongst all available vegetable oils, sesame seed oil (SSO) has unique cold flow properties and oxidation stability, particularly because of naturally occurring antioxidants and preservatives, which enhance the stability of oil towards rancidity. Therefore, SSO can be used as a potential feedstock for blending with other vegetable oils to enhance the overall cold flow and oxidation stability properties. This overview summarises sesame cultivation, SSO production, the physicochemical properties of SSO and its potential as an alternative renewable fuel source. In this review, the physicochemical properties of sesame biodiesel are compared with those of biodiesel derived from other vegetable oils. Results show that blending SSO with palm oil before transesterification will successfully improve the cold flow properties and oxidation stability of palm methyl ester (biodiesel)

Critical review on sesame seed oil and its methyl ester on cold flow and oxidation stability

The demand for renewable energy is steadily increasing due to rapid population growth and economic development worldwide. An additional reason is that fossil fuel reserves are limited, and this situation results in their non-uniform availability globally. Furthermore, the attitudes of the society, energy policies and technology choices are constantly changing. Thus, renewable energy resources are now considered good alternatives to fossil fuels. In the meantime, liquid energy, such as methyl ester from locally produced vegetable oils, is well accepted by many countries, even though it is currently being blended up to 20% with petroleum fuels. Recently, the industrialisation of biodiesel is a major problem because of its poor cold flow properties and oxidative stability. Vegetable oils are also being blended in an appropriate proportion before transesterification to obtain the desired properties in biodiesel. Similarly, poor cold flow properties and oxidative stability can be improved by choosing suitable vegetable oils for making blends. Amongst all available vegetable oils, sesame seed oil (SSO) has unique cold flow properties and oxidation stability, particularly because of naturally occurring antioxidants and preservatives, which enhance the stability of oil towards rancidity. Therefore, SSO can be used as a potential feedstock for blending with other vegetable oils to enhance the overall cold flow and oxidation stability properties. This overview summarises sesame cultivation, SSO production, the physicochemical properties of SSO and its potential as an alternative renewable fuel source. In this review, the physicochemical properties of sesame biodiesel are compared with those of biodiesel derived from other vegetable oils. Results show that blending SSO with palm oil before transesterification will successfully improve the cold flow properties and oxidation stability of palm methyl ester (biodiesel)

Effect of primary and secondary alcohols as oxygenated additives on the performance and emission characteristics of diesel engine

Funding Information: This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) ( NRF-2019R1A2C1010557 ). The authors would also like to thank the University of Malaya for supporting Ph.D. student through research grant GPF046A-2018 . Publisher Copyright: © 2020 The Author(s)The demand for renewable energy sources is gradually escalating due to the spontaneously growing population and global economic development. The access to fossil fuels is gradually declining due to the limited available reserves. Hence, renewable energy resources, technology choice, and energy policy are always being revised due to the modernization of society. Meanwhile, the liquid energy sources such as methyl ester from locally produced vegetable oils are readily accepted by many countries globally, although it is currently being blended (up to 20%) with diesel. Oxides of nitrogen are the most substantial emissions from diesel engines produced due to high combustion temperature. The addition of alcohol in the fuel reduces the NOx formation since alcohols have high latent heat of evaporation. The present study's primary purpose is to investigate the effect of different alcohol types on engine performance and emission characteristics. For this purpose, seven test fuels and neat diesel were used. The test fuels P20 (20% palm biodiesel with 70% neat diesel and 10% alcohol on a volume basis), D70P20E10, D70P20Pr10, D70P20B10, D70P20Pe10, D70P20H10 were prepared and tested on a single-cylinder, 4-stroke, DI-diesel engine at different speeds at 100 % load. The P20E10 ternary fuel blend illustrated the most practical combination of all the bioethanol-based blends, which considerably improves the BTE, BSFC and reduces NOxformation at high speed compared to other types of alcoholic fuel blends. Also, the P20E10 fuel blend improved the cloud point of neat diesel.Peer reviewe

Highly Flexible, Proton-Conductive Silicate Glass Electrolytes for Medium-Temperature/Low-Humidity Proton Exchange Membrane Fuel Cells

We demonstrate highly flexible, proton-conductive silicate glass electrolytes integrated with polyimide (PI) nonwoven fabrics (referred to as "b-SS glass electrolytes") for potential use in medium-temperature/ low-humidity proton exchange membrane fuel cells (PEMFCs). The b-SS glass electrolytes are fabricated via in situ sol-gel synthesis of 3-trihydroxysilyl-1-propanesulfonic acid (THPSA)/3-glycidyloxypropyl trimethoxysilane (GPTMS) mixtures inside PI nonwoven substrates that serve as a porous reinforcing framework. Owing to this structural uniqueness, the b-SS glass electrolytes provide noticeable improvements in mechanical bendability and membrane thickness, in comparison to typical bulk silicate glass electrolytes that are thick and easily fragile. Another salient feature of the b-SS glass electrolytes is the excellent proton conductivity at harsh measurement conditions of medium temperature/low humidity, which is highly important for PEMFC-powered electric vehicle applications. This beneficial performance is attributed to the presence of a highly interconnected, proton-conductive (THPSA/GPTMS-based) silicate glass matrix in the PI reinforcing framework. Notably, the b-SS glass electrolyte synthesized from THPSA/GPTMS = 9/1 (mol/mol) exhibits a higher proton conductivity than water-swollen sulfonated polymer electrolyte membranes (here, sulfonated poly(arylene ether sulfone) and Nafion are chosen as control samples). This intriguing behavior in the proton conductivity of the b-SS glass electrolytes is discussed in great detail by considering its structural novelty and Grotthuss mechanism-driven proton migration that is strongly affected by ion exchange capacity (IEC) values and also state of water.close3