10 research outputs found
Groundwater resources assessment using numerical model : a case study in low-lying coastal area.
The impacts of climate change and human pressure in groundwater have been greatest threats facing small islands. This paper represents a case study of groundwater responses towards the climate change and human pressures in Manukan Island Malaysia. SEAWAT-2000 was used for the simulations of groundwater response in study area. Simulations of six scenarios representing climate change and human pressures showed changes in hydraulic heads and chloride concentrations. Reduction in pumping rate and an increase in recharge rate can alter the bad effects of overdrafts in Manukan Island. In general, reduction in pumping rate and an increase in recharge rate are capable to restore and protect the groundwater resources in Manukan Island. Thus, for groundwater management options in Manukan Island, scenario 2 is capable to lessen the seawater intrusion into the aquifer and sustain water resources on a long-term basis. The selection of scenario 6 is the preeminent option during wet season. The output of this study provides a foundation which can be used in other small islands of similar hydrogeological condition for the purpose of groundwater resources protection
Adsorption of textile dyes on raw and decanted Moroccan clays: Kinetics, equilibrium and thermodynamics
AbstractInexpensive and easily available Moroccan natural clays were investigated for the removal availability of textile dyes from aqueous solution. For this purpose, the adsorption of methylene blue (MB) as reference molecule, malachite green (MG) representative of cationic dyes and methyl orange (MO) representative of anionic dyes, was studied in batch mode under various parameters. The clays were characterized by means of XRD, cationic exchange capacity and BET surface area analysis. The experimental results show that, the adsorption was pH dependent with a high adsorption capacity of MB and MG in basic range and high adsorption of MO in acidic range. The pseudo-second-order kinetic model provided the best fit to the experimental data for the adsorption of MB and MG by the clays. However, the adsorption of MO was more suitable to be controlled by an intra-particle diffusion mechanism. The equilibrium adsorption data were analyzed by Langmuir, Freundlich and Dubinin–Radushkevich isotherm models. The adsorption process was found to be exothermic in nature in the case of MB and MO. However, the adsorption of MG was endothermic
Assessing the impacts of climate change on sustainable management of coastal aquifers
Water is a vital resource for the survival of not only human population, but also almost all ecosystems. Constituting 30 % of all freshwater, groundwater is the main source of available freshwater. Coastal aquifers, which serve as the major freshwater source for densely populated zones, are of vital importance and quite vulnerable to climate change. This paper examines the significant consequences of climate change, decreasing recharge rates, sea-level rise and increasing freshwater demand on the sustainable management of coastal aquifers, via a hypothetical case study. A 3-D numerical model is developed using SEAWAT, to simulate a circular island aquifer in the form of a freshwater lens surrounded by saltwater. Issues such as sloping land surface resulting in landward migration of the coastal boundary and transient response of the system due to pumping are considered through a set of predictive simulations. To assess the sensitivity of the model results to important parameters, a sensitivity analysis is performed. Results of this research, revealing the effects of mentioned pressures on the long-term sustainability of the freshwater resource, are evaluated on the basis of groundwater reserves and intrusion of the freshwater-saltwater interface in lateral and vertical directions. These outcomes are further used to determine the sustainable pumping rate of the system, considering both quantity and quality of the groundwater resources