Compleja historia de la formulación de la ley de Boyle

Los historiadoras da la ciencia, analizando los propios documentos da Boyle, han puesto de manifiesto como precedentes los trabajos da otros científicos, entra ellos: Evangelista Torricallí, Edmé Mariotte, Blaise Pascal, Henry Powar, Richard Townlay y Wiliam CroonaDli, que contribuyeron, a incluso predijeron, la formulación da la conocida ley da Boyle. Sin embargo, ninguno da ellos fue capaz de anticiparse a la publicación da la misma, manos aún con la precisión, meticulosidad experimental, detalle y exactitud que la conseguida por Boyle, quien adquirió desde entonces merecido prestigio como investigador científico y experimentador, constituyéndose en al más reputado "pneumático" da su época. Discípulo da Francis Bacon, aplicó con fidelidad la metodología inductiva da esta filósofo. Por otra parte, los experimentos descritos por Boyle en sus obras encierran un elevado valor didáctico en cuanto a la formulación del conocimiento científico

Global soil moisture bimodality in satellite observations and climate models

A new diagnostic metric based on soil moisture bimodality is developed in order to examine and compare soil moisture from satellite observations and Earth System Models. The methodology to derive this diagnostic is based on maximum likelihood estimator encoded into an iterative algorithm, which is applied to the soil moisture probability density function. This metric is applied to satellite data from the Advanced Microwave Scanning Radiometer for the Earth Observing System and global climate models data from the Coupled Model Intercomparison Project Phase 5 (CMIP5). Results show high soil moisture bimodality in transitional climate areas and high latitudes, potentially associated with land-atmosphere feedback processes. When comparing satellite versus climate models, a clear difference in their soil moisture bimodality is observed, with systematically higher values in the case of CMIP5 models. These differences appear related to areas where land-atmospheric feedback may be overestimated in current climate models

Relativistic r-modes and shear viscosity

We derive the relativistic equations for stellar perturbations, including in a consistent way shear viscosity in the stress-energy tensor, and we numerically integrate our equations in the case of large viscosity. We consider the slow rotation approximation, and we neglect the coupling between polar and axial perturbations. In our approach, the frequency and damping time of the emitted gravitational radiation are directly obtained. We find that, approaching the inviscid limit from the finite viscosity case, the continuous spectrum is regularized. Constant density stars, polytropic stars, and stars with realistic equations of state are considered. In the case of constant density stars and polytropic stars, our results for the viscous damping times agree, within a factor two, with the usual estimates obtained by using the eigenfunctions of the inviscid limit. For realistic neutron stars, our numerical results give viscous damping times with the same dependence on mass and radius as previously estimated, but systematically larger of about 60%.Comment: 8 pages, 7 figures, to appear in the Proceedings of the Albert Einstein Century International Conference, Paris, France, July 200

Two modes of peri-interaction between an aldehyde group and a carboxylate anion in naphthalaldehydate salts

Crystal structures of the salts of 1,8-naphthalaldehydic acid (8-formyl-1-naphthoic acid) show one of two types of interaction between the functional groups. In the more commonly observed case, a carboxylate oxygen lies close to the aldehyde carbonyl carbon atom (O⋯C: 2.445–2.630 Å) and makes an n–pi* interaction. However, in two other cases the carboxylate group has rotated so that the aldehyde now directs its hydrogen atom at the face of the carboxylate group and forms a surprisingly short contact with the carbon atom (H⋯C: 2.29 and 2.42 Å). This interaction is likely to be electrostatic in nature

Global-scale regionalization of hydrologic model parameters

Current state-of-the-art models typically applied at continental to global scales (hereafter called macroscale) tend to use a priori parameters, resulting in suboptimal streamflow (Q) simulation. For the first time, a scheme for regionalization of model parameters at the global scale was developed. We used data from a diverse set of 1787 small-to-medium sized catchments ( 10-10,000 km(2)) and the simple conceptual HBV model to set up and test the scheme. Each catchment was calibrated against observed daily Q, after which 674 catchments with high calibration and validation scores, and thus presumably good-quality observed Q and forcing data, were selected to serve as donor catchments. The calibrated parameter sets for the donors were subsequently transferred to 0.5 degrees grid cells with similar climatic and physiographic characteristics, resulting in parameter maps for HBV with global coverage. For each grid cell, we used the 10 most similar donor catchments, rather than the single most similar donor, and averaged the resulting simulated Q, which enhanced model performance. The 1113 catchments not used as donors were used to independently evaluate the scheme. The regionalized parameters outperformed spatially uniform (i.e., averaged calibrated) parameters for 79% of the evaluation catchments. Substantial improvements were evident for all major Koppen-Geiger climate types and even for evaluation catchments>5000 km distant from the donors. The median improvement was about half of the performance increase achieved through calibration. HBV with regionalized parameters outperformed nine state-of-the-art macroscale models, suggesting these might also benefit from the new regionalization scheme. The produced HBV parameter maps including ancillary data are available via

ESO Imaging survey: Optical Deep Public Survey

This paper presents new five passbands (UBVRI) optical wide-field imaging data accumulated as part of the DEEP Public Survey (DPS) carried out as a public survey by the ESO Imaging Survey (EIS) project. Out of the 3 square degrees originally proposed, the survey covers 2.75 square degrees, in at least one band (normally R), and 1.00 square degrees in five passbands. The median seeing, as measured in the final stacked images, is 0.97", ranging from 0.75" to 2.0". The median limiting magnitudes (AB system, 2" aperture, 5 sigma detection limit) are U_(AB)=25.65, B_(AB)=25.54, V_(AB)=25.18, R_(AB) = 24.8 and I_(AB)=24.12 mag, consistent with those proposed in the original survey design. The paper describes the observations and data reduction using the EIS Data Reduction System and its associated EIS/MVM library. The quality of the individual images were inspected, bad images discarded and the remaining used to produce final image stacks in each passband, from which sources have been extracted. Finally, the scientific quality of these final images and associated catalogs was assessed qualitatively by visual inspection and quantitatively by comparison of statistical measures derived from these data with those of other authors as well as model predictions, and from direct comparison with the results obtained from the reduction of the same dataset using an independent (hands-on) software system. Finally to illustrate one application of this survey, the results of a preliminary effort to identify sub-mJy radio sources are reported. To the limiting magnitude reached in the R and I passbands the success rate ranges from 66 to 81% (depending on the fields). These data are publicly available at CDS.Comment: 24 pages, 26 figures. Accepted for pubblication in A&

Revisión de los Gordiacea (Nematomorpha) de la colección de la Academia de Ciencias de California con descripción de una nueva especie

The Gordiacea of the California Academy of Sciences collection are studied. The specimens are included in the known species Gordius robustus Leidy, Pseudochordodes bedriagae (Camerano) and a new species, Neochordodes californensis n. sp. is proposed. Morphological, morphometric and geographical data are provided for these species.En este trabajo se estudian los Gordiacea de la colección de la California Academy of Sciences. Los ejemplares se incluyen en dos especies conocidas, Gordius robustus Leidy y Pseudochordodes bedriagae (Camerano), y una especie nueva: Neochordodes californensis n. sp. Se proporcionan datos morfológicos, morfométricos y geográficos para cada una de las especies