906 research outputs found
Isotopic Anomalies in Primitive Solar System Matter: Spin-state Dependent Fractionation of Nitrogen and Deuterium in Interstellar Clouds
Organic material found in meteorites and interplanetary dust particles is
enriched in D and 15N. This is consistent with the idea that the functional
groups carrying these isotopic anomalies, nitriles and amines, were formed by
ion-molecule chemistry in the protosolar nebula. Theoretical models of
interstellar fractionation at low temperatures predict large enrichments in
both D and 15N and can account for the largest isotopic enrichments measured in
carbonaceous meteorites. However, more recent measurements have shown that, in
some primitive samples, a large 15N enrichment does not correlate with one in
D, and that some D-enriched primitive material displays little, if any, 15N
enrichment. By considering the spin-state dependence in ion-molecule reactions
involving the ortho and para forms of H2, we show that ammonia and related
molecules can exhibit such a wide range of fractionation for both 15N and D in
dense cloud cores. We also show that while the nitriles, HCN and HNC, contain
the greatest 15N enrichment, this is not expected to correlate with extreme D
enrichment. These calculations therefore support the view that Solar System 15N
and D isotopic anomalies have an interstellar heritage. We also compare our
results to existing astronomical observations and briefly discuss future tests
of this model.Comment: Submitted to ApJ
Observations of Isotope Fractionation in Prestellar Cores: Interstellar Origin of Meteoritic Hot Spot?
Isotopically fractionated material is found in many solar system objects, including meteorites and comets. It is thought, in some cases, to trace interstellar material that was incorporated into the solar system without undergoing significant processing. Here, we show the results of models and observations of the nitrogen and carbon fractionation in proto-stellar cores
Observations of Nitrogen Fractionation in Prestellar Cores: Nitriles Tracing Interstellar Chemistry
Primitive materials provide important clues on the processes that occurred during the formation and early evolution of the Solar System. Space-based and ground-based observations of cometary comae show that comets appear to contain a mixture of the products of both interstellar and nebular chemistries. Significant 15-nitrogen enrichments have been measured in CN and HCN towards a number of comets and may suggest an origin of interstellar chemical fractionation. Additionally, large N-15 enhancements are found in meteorites and has also led to to the view that the N-15 traces material formed in the interstellar medium (ISM), although multiple sources cannot be excluded. Here, we show the results of observations of the nitrogen and carbon fractionation in prestellar cores for various N-bearing species to decipher the origin of primitive material isotopic enrichments
Measuring molecular abundances in comet C/2014 Q2 (Lovejoy) using the APEX telescope
Comet composition provides critical information on the chemical and physical
processes that took place during the formation of the Solar system. We report
here on millimetre spectroscopic observations of the long-period bright comet
C/2014 Q2 (Lovejoy) using the Atacama Pathfinder Experiment (APEX) band 1
receiver between 2015 January UT 16.948 to 18.120, when the comet was at
heliocentric distance of 1.30 AU and geocentric distance of 0.53 AU. Bright
comets allow for sensitive observations of gaseous volatiles that sublimate in
their coma. These observations allowed us to detect HCN, CH3OH (multiple
transitions), H2CO and CO, and to measure precise molecular production rates.
Additionally, sensitive upper limits were derived on the complex molecules
acetaldehyde (CH3CHO) and formamide (NH2CHO) based on the average of the
strongest lines in the targeted spectral range to improve the signal-to-noise
ratio. Gas production rates are derived using a non-LTE molecular excitation
calculation involving collisions with H2O and radiative pumping that becomes
important in the outer coma due to solar radiation. We find a depletion of CO
in C/2014 Q2 (Lovejoy) with a production rate relative to water of 2 per cent,
and relatively low abundances of Q(HCN)/Q(H2O), 0.1 per cent, and
Q(H2CO)/Q(H2O), 0.2 per cent. In contrast the CH3OH relative abundance
Q(CH3OH)/Q(H2O), 2.2 per cent, is close to the mean value observed in other
comets. The measured production rates are consistent with values derived for
this object from other facilities at similar wavelengths taking into account
the difference in the fields of view. Based on the observed mixing ratios of
organic molecules in four bright comets including C/2014 Q2, we find some
support for atom addition reactions on cold dust being the origin of some of
the molecules.Comment: 10 pages, 7 figures, to be published in MNRA
Spin-State-Dependent Ion-Molecule Chemistry as the Origin of N-15 and D Isotopic Anomalies in Primitive Matter.
Many meteoritic and interplanetary dust particle (IDP) samples contain bulk enhancements and hotspots rich in N-15. Similarly low C(14)N/C(15)N ratios have been observed in numerous comets, An almost constant enrichment factor in comets from disti'nct formation zones in the nebular disk (i.e. both Jupiter Family and Oort Cloud comets), strongly suggests that this fractionation is primordial and was set in the protsolar cloud core. Deuterium enrichment is observed in both meteorites and IDP
Returning to Learning: Adults' Success in College Is Key to America's Future
Provides an overview of research on adult learners' characteristics, risk factors, and needs at four-year institutions and in for-credit and non-credit courses, and what changes institutions and governments can implement to help adult students succeed
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Randomized Controlled Trial of an Internet Application to Reduce HIV Transmission Behavior Among HIV Infected Men Who have Sex with Men.
We conducted a prospective, randomized controlled trial of an internet-based safer-sex intervention to reduce HIV transmission risk behaviors. HIV-infected men who have sex with men (n = 179) were randomized to receive a monthly internet survey alone or a monthly survey plus tailored risk reduction messages over 12 months. The primary outcome was the cumulative sexually transmitted infection (STI) incidence over 12 months. Secondary outcomes included self-reported unprotected sex with an at risk partner and disclosure of HIV status to partners. In a modified intent to treat analysis, there was no difference in 12-month STI incidence between the intervention and control arms (30 vs. 25 %, respectively; p = 0.5). Unprotected sex decreased and disclosure increased over time in both study arms. These improvements suggest that addition of the risk-reduction messages provided little benefit beyond the self-monitoring of risky behavior via regular self-report risk behavior assessments (as was done in both study arms)
Testing the Indirect Effect of Trait Mindfulness on Adolescent Cigarette Smoking Through Negative Affect and Perceived Stress Mediators
Mindfulness refers to an enhanced attention to and awareness of present moment experience. This study examined how trait mindfulness, as measured with six items from Mindfulness Attention Awareness Scale, might influence adolescent cigarette smoking frequency through its impact on depressive affect, anger affect and perceived stress mediators. Self-reported data from Chinese adolescents (N = 5287, mean age = 16.2 years, SD = 0.7; 48.8% females) were collected within 24 schools. The product of coefficients test was used to determine significant mediation paths. Results from baseline cross-sectional data indicated that trait mindfulness had a significant indirect effect on past 30-day smoking frequency through depressive affect, anger affect and perceived stress mediators. Results from 13-month longitudinal data indicated that these indirect effects remained significant for depressive affect and perceived stress but not for anger affect. Findings from this study may suggest that heightening mindfulness among adolescents may indirectly reduce cigarette smoking perhaps by improving affect regulation competencies
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