Bad weather absences and employer liability.

Discusses the liability of employers for disciplinary action taken against employees following absences relating to bad weathers, notably pursuant to government or police advice, or because attending the workplace is not physically practical

Further Hierarchies of Loss: Tracking Relationality in Pregnancy Loss Experiences

The article extends Robson and Walter’s concept of hierarchies of loss by describing further factors which afford differential social legitimacy to death-related losses. Drawing on our separate research with women in England who have experienced pre-viability pregnancy loss through different types of miscarriage and termination for foetal anomaly, we note that closeness of relationship to the object of loss does hierarchise pregnancy loss. However, other relational elements are also implicated, including ontological positions on what it was which was lost, in relation to other individually and socially experienced losses. Hierarchies are both imposed and agentially used by those who are implicated. This wider analysis extends the concept of hierarchies of loss so it can include experiences which do and do not involve grief and bereavement, and experiences of social recognition alongside those where loss is disenfranchised, marginalised, or ungrievable

Indian Earthquakes

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Mould or cold? Contrasting representations of unhealthy housing in Denmark and England and the relation to energy poverty

Both mould growth and underheating in housing are widely recognised as health concerns, but the problematisation and handling of these issues varies greatly in different nations. In this paper we compare Danish and English understandings of mould and cold in homes. Drawing on Bacchi's ‘What is the problem represented to be?’ framework, we ask how mould is understood in the two national contexts by analysing how it is problematised in key national policy documents, uncovering the effects of these contrasting problematisations on the way in which mould is managed in rental housing. Following Bacchi's approach, we find that contrasting problematisations of mould lead to highly divergent management approaches, in turn shaping public health consequences for those living with mould and cold. While in Denmark mould is central to rental housing management, and considered an important issue in its own right, in England mould is seen as a by-product of under-heating as a result of fuel poverty. In Denmark, a discourse of poverty is suppressed, since mould is framed as a building issue rather than related to income inequality, while in England mould in buildings is not adequately addressed due to a strong focus on access to warmth. By showing how policy problematisations shape housing management, our work suggests the value of a critical approach to housing and energy policy, which has salience to contexts beyond the UK and Denmark. We finish by identifying the risks of these narrow problematisations, suggesting the productive possibility of tackling both mould and cold together

A Portable MEMS Gravimeter for the Detection of the Earth Tides

Gravimeters are used for measuring the local gravitational acceleration. The use of current commercially available gravimeters, however, has been limited by their high cost and large size. In this study, a microelectromechanical system (MEMS) based relative gravimeter with an acceleration sensitivity of 8 μGall / √ (Hz) is demonstrated. The MEMS gravimeter, along with the custom interface electronics, is embedded on a battery powered portable platform. The portable platform enables continuous recording of the sensor response, while simultaneously measuring critical temperature and tilt parameters. To demonstrate the long-term stability of the system, the reported MEMS gravimeter platform was used to detect the Earth tides. In this paper, the first results from these measurements have been discussed

Joint Experimental and Computational 17O and 1H Solid State NMR Study of Ba2In2O4(OH)2 Structure and Dynamics.

A structural characterization of the hydrated form of the brownmillerite-type phase Ba2In2O5, Ba2In2O4(OH)2, is reported using experimental multinuclear NMR spectroscopy and density functional theory (DFT) energy and GIPAW NMR calculations. When the oxygen ions from H2O fill the inherent O vacancies of the brownmillerite structure, one of the water protons remains in the same layer (O3) while the second proton is located in the neighboring layer (O2) in sites with partial occupancies, as previously demonstrated by Jayaraman et al. (Solid State Ionics2004, 170, 25-32) using X-ray and neutron studies. Calculations of possible proton arrangements within the partially occupied layer of Ba2In2O4(OH)2 yield a set of low energy structures; GIPAW NMR calculations on these configurations yield 1H and 17O chemical shifts and peak intensity ratios, which are then used to help assign the experimental MAS NMR spectra. Three distinct 1H resonances in a 2:1:1 ratio are obtained experimentally, the most intense resonance being assigned to the proton in the O3 layer. The two weaker signals are due to O2 layer protons, one set hydrogen bonding to the O3 layer and the other hydrogen bonding alternately toward the O3 and O1 layers. 1H magnetization exchange experiments reveal that all three resonances originate from protons in the same crystallographic phase, the protons exchanging with each other above approximately 150 °C. Three distinct types of oxygen atoms are evident from the DFT GIPAW calculations bare oxygens (O), oxygens directly bonded to a proton (H-donor O), and oxygen ions that are hydrogen bonded to a proton (H-acceptor O). The 17O calculated shifts and quadrupolar parameters are used to assign the experimental spectra, the assignments being confirmed by 1H-17O double resonance experiments.This work was supported in part by Grants DMR050612 and CHE0714183 from the National Science Foundation and Grant DESC0001284 from the Department of Energy (supporting Y.- L.L. and D.M.), by an Advanced Fellowship from the EU-ERC (C.P.G.), and by the EPSRC (D.S.M.). F.B. thanks the EU Marie Curie actions FP7 for an International Incoming fellowship (Grant No. 275212) and Clare Hall, University of Cambridge, for a Research Fellowship.This is the final version of the article. It first appeared from ACS Publications via http://dx.doi.org/10.1021/acs.chemmater.5b0032

Joint Experimental and Computational O-17 and H-1 Solid State NMR Study of Ba2In2O4(OH)(2) Structure and Dynamics

This is the final version of the article. It first appeared from ACS Publications via http://dx.doi.org/10.1021/acs.chemmater.5b00328A structural characterization of the hydrated form of the brownmillerite-type phase Ba2In2O5, Ba2In2O4(OH)2, is reported using experimental multinuclear NMR spectroscopy and density functional theory (DFT) energy and GIPAW NMR calculations. When the oxygen ions from H2O fill the inherent O vacancies of the brownmillerite structure, one of the water protons remains in the same layer (O3) while the second proton is located in the neighboring layer (O2) in sites with partial occupancies, as previously demonstrated by Jayaraman et al. ( Solid State Ionics 2004, 170, 25?32) using X-ray and neutron studies. Calculations of possible proton arrangements within the partially occupied layer of Ba2In2O4(OH)2 yield a set of low energy structures; GIPAW NMR calculations on these configurations yield 1H and 17O chemical shifts and peak intensity ratios, which are then used to help assign the experimental MAS NMR spectra. Three distinct 1H resonances in a 2:1:1 ratio are obtained experimentally, the most intense resonance being assigned to the proton in the O3 layer. The two weaker signals are due to O2 layer protons, one set hydrogen bonding to the O3 layer and the other hydrogen bonding alternately toward the O3 and O1 layers. 1H magnetization exchange experiments reveal that all three resonances originate from protons in the same crystallographic phase, the protons exchanging with each other above approximately 150 ?C. Three distinct types of oxygen atoms are evident from the DFT GIPAW calculations bare oxygens (O), oxygens directly bonded to a proton (H-donor O), and oxygen ions that are hydrogen bonded to a proton (H-acceptor O). The 17O calculated shifts and quadrupolar parameters are used to assign the experimental spectra, the assignments being confirmed by 1H?17O double resonance experiments.This work was supported in part by Grants DMR050612 and CHE0714183 from the National Science Foundation and Grant DESC0001284 from the Department of Energy (supporting Y.- L.L. and D.M.), by an Advanced Fellowship from the EU-ERC (C.P.G.), and by the EPSRC (D.S.M.). F.B. thanks the EU Marie Curie actions FP7 for an International Incoming fellowship (Grant No. 275212) and Clare Hall, University of Cambridge, for a Research Fellowship

Isotopomeric polymorphism in a "doubly-polymorphic" multi-component molecular crystal

Isotopomeric polymorphism is observed in complexes of isonicotinamide with oxalic acid, highly unusual here in that each isotopic complex is itself polymorphic, a situation of “double polymorphism”. The four polymorphic forms exhibit different degrees of hydron transfer.</p

2H and 27Al Solid-State NMR Study of the Local Environments in Al-Doped 2-Line Ferrihydrite, Goethite, and Lepidocrocite.

Although substitution of aluminum into iron oxides and oxyhydroxides has been extensively studied, it is difficult to obtain accurate incorporation levels. Assessing the distribution of dopants within these materials has proven especially challenging because bulk analytical techniques cannot typically determine whether dopants are substituted directly into the bulk iron oxide or oxyhydroxide phase or if they form separate, minor phase impurities. These differences have important implications for the chemistry of these iron-containing materials, which are ubiquitous in the environment. In this work, 27Al and 2H NMR experiments are performed on series of Al-substituted goethite, lepidocrocite, and 2-line ferrihydrite in order to develop an NMR method to track Al substitution. The extent of Al substitution into the structural frameworks of each compound is quantified by comparing quantitative 27Al MAS NMR results with those from elemental analysis. Magnetic measurements are performed for the goethite series to compare with NMR measurements. Static 27Al spin-echo mapping experiments are used to probe the local environments around the Al substituents, providing clear evidence that they are incorporated into the bulk iron phases. Predictions of the 2H and 27Al NMR hyperfine contact shifts in Al-doped goethite and lepidocrocite, obtained from a combined first-principles and empirical magnetic scaling approach, give further insight into the distribution of the dopants within these phases.J.K., A.J.I., D.M. and N.P. were supported by an NSF grant collaborative research grant in chemistry CHE0714183. An allocation of time upon the NANO computer cluster at the Center for Functional Nanomaterials, Brookhaven National Laboratory, U.S.A., which is supported by the U.S. Department of Energy (DOE), Office of Basic Energy Sciences, under Contract No. DE-AC02-98CH10886 is also acknowledged. D.S.M. and C.P.G. thank the EPSRC and the EU-ERC for support.This is the final version of the article. It first appeared from the American Chemical Society via http://dx.doi.org/10.1021/acs.chemmater.5b0085